公开(公告)号：US06635152B1

公开(公告)日：2003-10-21

申请号：US09589908

申请日：2000-06-07

申请人： Paul A. Cahill ,  Richard N. Steppel

发明人： Paul A. Cahill ,  Richard N. Steppel

IPC分类号： C07C600

CPC分类号： C07C5/31 ,  C07C2603/86

摘要： The present invention relates to a process for driving a non-polymerization solution-phase photochemical transformation. A sensitizer, such as a substituted diaminobenzophenone having a solubility in norbornadiene greater than that of Michler's Ketone, may be added to norbornadiene to form a solution, wherein the sensitizer decreases the induction period at the beginning of the reaction, increases the photon or quantum efficiency of conversion of norbornadiene to quadricyclane, and increases the rate of conversion at the end of the reaction. If the solution is irradiated with light from a metal halide-doped mercury arc lamp to photochemically transform the norbornadiene to quadricyclane, the conversion is more efficient than when other light sources are utilized. Furthermore, the addition of triethylamine to the solution tends to result in the formation of fewer by-products in the transformation reaction.

摘要翻译： 本发明涉及一种驱动非聚合溶液相光化学转化的方法。 可以向降冰片二烯中加入敏化剂，例如在降冰片二烯中的溶解度大于米ler酮的敏感剂形成溶液，其中敏化剂降低反应开始时的诱导期，增加光子或量子效率 降冰片二烯转化为四环素，并且增加反应结束时的转化率。 如果用来自金属卤化物掺杂的水银弧光灯的光照射该溶液以将降冰片二烯光学化学转化为四环体，那么转换比使用其它光源时更有效。 此外，向溶液中加入三乙胺倾向于导致在转化反应中形成更少的副产物。

公开(公告)号：US5041238A

公开(公告)日：1991-08-20

申请号：US236264

申请日：1988-08-22

申请人： Joel M. Kauffman ,  Charles J. Kelley ,  Richard N. Steppel

发明人： Joel M. Kauffman ,  Charles J. Kelley ,  Richard N. Steppel

IPC分类号： C07C13/567 ,  C07D209/86 ,  C07D307/91 ,  C09B57/00 ,  H01S3/213

CPC分类号： C07D307/91 ,  C07C13/567 ,  C07D209/86 ,  C09B57/00 ,  H01S3/213

摘要： Disclosed are organic laser dyes and more particularly o,o'-bridged oligophenylene laser dyes which when excited to lase emit radiation in various ranges and especially in the ultraviolet and violet ranges, that is, from about 300 nm to about 420 nm, of the light spectrum. An organic laser dye of this invention comprises an oligophenylene having at least one biphenyl moiety bridged between adjacent ortho positions via a single atom or a plural of atom substituents of various sizes. In one most preferred embodiment, the substituent bonded to the phenyl moieties forming the bridge is a carbon atom free of benzylic hydrogens. The bridging substituent can also be other atoms or groups free of reactive substituents. In another most preferred embodiment, the o,o'-bridged oligophenylene laser dyes are free of vinylene groups bonded directly to the phenyl moieties forming the oligophenylene chains. The o,o'-bridged oligophenylene laser dyes of the present invention are provided with relatively high power output and have relatively long photochemical lifetimes. Also disclosed are dye lasers and methods of lasing.

摘要翻译： 公开了有机激光染料，更特别的是O，O-桥接的低聚亚磷激光染料，当被激发以激发在各种范围内，特别是在紫外和紫色范围内发射辐射时，即约300nm至约420nm的 光谱。 本发明的有机激光染料包括通过单个原子或多个不同大小的原子取代基具有桥连在相邻邻位之间的至少一个联苯部分的低聚苯乙烯。 在一个最优选的实施方案中，键合到形成桥的苯基部分的取代基是不含苄基氢的碳原子。 桥接取代基也可以是没有反应性取代基的其它原子或基团。 在另一个最优选的实施方案中，邻氨基苯乙烯激光染料不含直接键合到形成低聚苯撑链的苯基部分的亚乙烯基。 本发明的邻苯二甲酰亚胺类激光染料具有较高的功率输出并具有较长的光化学寿命。 还公开了染料激光器和激光的方法。

公开(公告)号：US5037578A

公开(公告)日：1991-08-06

申请号：US504730

申请日：1990-04-02

申请人： Joel M. Kauffman ,  Charles J. Kelley ,  Richard N. Steppel

发明人： Joel M. Kauffman ,  Charles J. Kelley ,  Richard N. Steppel

IPC分类号： C07C13/567 ,  C07D209/86 ,  C07D307/91 ,  C09B57/00 ,  H01S3/213

CPC分类号： C07D307/91 ,  C07C13/567 ,  C07D209/86 ,  C09B57/00 ,  H01S3/213

摘要： Disclosed are organic laser dyes and more particularly o,o'-bridged oligophenylene laser dyes which when excited to lase emit radiation in various ranges and especially in the ultraviolet and violet ranges, that is, from about 300 nm to about 420 nm, of the light spectrum. An organic laser dye of this invention comprises an oligophenylene having at least one biphenyl moiety bridged between adjacent ortho positions via a single atom or a plural of atom substituents of various sizes. In one most preferred embodiment, the substituent bonded to the phenyl moieties forming the bridge is a carbon atom free of benzylic hydrogens. The bridging substituent can also be other atoms or groups free of reactive substituents. In another most preferred embodiment, the o,o'-bridged oligophenylene laser dyes are free of vinylene groups bonded directly to the phenyl moieties forming the oligophenylene chains. The o,o'-bridged oligophenylene laser dyes of the present invention are provided with relatively high power output and have relatively long photochemical lifetimes. Also disclosed are dye lasers and methods of lasing.

摘要翻译： 公开了有机激光染料，更特别的是O，O-桥接的低聚亚磷激光染料，当被激发以激发在各种范围内，特别是在紫外和紫色范围内发射辐射时，即约300nm至约420nm的 光谱。 本发明的有机激光染料包括通过单个原子或多个不同大小的原子取代基具有桥连在相邻邻位之间的至少一个联苯部分的低聚苯乙烯。 在一个最优选的实施方案中，键合到形成桥的苯基部分的取代基是不含苄基氢的碳原子。 桥接取代基也可以是没有反应性取代基的其它原子或基团。 在另一个最优选的实施方案中，邻氨基苯乙烯激光染料不含直接键合到形成低聚苯撑链的苯基部分的亚乙烯基。 本发明的邻苯二甲酰亚胺类激光染料具有较高的功率输出并具有较长的光化学寿命。 还公开了染料激光器和激光的方法。