PRODUCING C5 OLEFINS FROM STEAM CRACKER C5 FEEDS

    公开(公告)号:US20180178187A1

    公开(公告)日:2018-06-28

    申请号:US15901415

    申请日:2018-02-21

    Abstract: Producing C5 olefins from steam cracker C5 reeds may include reacting a mixed hydrocarbon stream comprising cyclopentadiene, C5 olefins, and C6+ hydrocarbons in a dimerization reactor where cyclopentadiene is dimerized to dicyclopentadiene. The dimerization reactor effluent may be separated into a traction comprising the C6+ hydrocarbons and dicyclopentadiene and a second fraction comprising C5 olefins and C5 dienes. The second fraction, a saturated hydrocarbon diluent stream, and hydrogen may be fed to a catalytic distillation reactor system for concurrently separating linear C5 olefins from saturated hydrocarbon diluent, cyclic C5 olefins, and C5 dienes contained in the second fraction and selectively hydrogenating C5 dienes. An overhead distillate including the linear C5 olefins and a bottoms product including cyclic C5 olefins are recovered from the catalytic distillation reactor system. Other aspects of the C5 olefin systems and processes, including catalyst configurations and control schemes, are also described.

    Production of vinylidene olefins
    7.
    发明授权
    Production of vinylidene olefins 失效
    生产亚乙烯基烯烃

    公开(公告)号:US5625105A

    公开(公告)日:1997-04-29

    申请号:US596848

    申请日:1996-02-05

    CPC classification number: C07C2/30 C07C2531/14

    Abstract: Vinylidene olefin can be formed in good yield in much shorter reaction periods than found critical heretofore. The process involves dimerizing vinyl olefin with at least one trialkylaluminum compound as the sole catalyst component charged to the reaction vessel. These materials are charged to the reactor so that it contains in the range of 0.001 to 0.05 mol of trialkylaluminum per mol of the initial vinyl olefin. The reaction is performed at a temperature in the range of over 140.degree. C. and below 172.degree. C. for a period of time in the range of 1 to 24 hours sufficient to convert at least 10% by weight of the initial vinyl olefin to a different product with at least 80 wt % vinylidene dimer selectivity.

    Abstract translation: 亚乙烯基烯烃可以在比目前关键的短得多的反应时间内以良好的产率形成。 该方法包括将乙烯基烯烃与至少一种三烷基铝化合物二烯化,作为装入反应容器的唯一催化剂组分。 将这些材料装入反应器,使其每摩尔初始乙烯基烯烃含有0.001至0.05摩尔三烷基铝。 反应在超过140℃和低于172℃的温度下进行,持续1至24小时的时间足以将至少10重量%的初始乙烯基烯烃转化为 具有至少80重量%亚乙烯基二聚体选择性的不同产品。

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