摘要:
H2 production, sulfuric acid and SO2 production process refers to an innovative process VIA the phenomena of the Sulfur-Iodine (S-I) thermochemical cycle. The process consist of the acid gas burner to burn all the acid gases with air, enriched air or oxygen and without using any fuel gas to produce SO2. The acid gases are normally processed in the prior arts of the sulfur recovery units. Iodine is used to produce the hydrogen. A portion or all of the acid gases are sent to the acid gas burner in accordance with the present invention. The present innovation not only produces hydrogen but also reduces the SO2 and CO2 emissions. The produced SO2 is sent to other units to produce other fertilizer products and the produced CO2 is sent to CO2 removal or CO2 Liquefaction process. The hydrogen is produced is used to supply the needs within the facility like hydrotreaters to reduce external import and to reduce the operating costs.
摘要:
A process where a gas, containing SO2 and O2 is brought in contact with a mixture of from 95% vol. to 50% vol. of activated carbon catalyst and from 5% vol. to 50% vol. of an inert filler material, where the SO2 is converted to H2SO4 on the activated carbon catalyst and is then washed from the activated carbon catalyst to obtain a H2SO4 solution.
摘要:
The present invention relates to a method for the catalytic removal of sulfur dioxide from waste gases in two reactors, wherein the first reactor is charged with an activated carbon catalyst. The method comprises: a. provision of a waste gas with a water content of less than 1 g H2O/Nm3 and an SO2 content of at least 5 ppm, b. introduction of the waste gases into a first reactor, c. catalytic conversion of the SO2 into gaseous SO3 in the first reactor by the activated carbon catalyst, wherein catalytic conversion on the activated carbon catalyst proceeds at a temperature of below 100° C., d. introduction of the prepurified waste gases from the first reactor into a second reactor, e. conversion of the SO3 with water into H2SO4 in the second reactor.
摘要:
Novel catalysts for the purification of gaseous effluents containing contaminating amounts of sulfur compounds include a catalytically active phase for the oxidation of such sulfur compounds into elemental sulfur, SO.sub.2 and/or SO.sub.3 and are shaped as to have a ratio between their external surface area and their volume of at least 2 mm.sup.-1 ; advantageously such catalysts have a concave multilobal configuration, preferably trilobal or quadrilobal.
摘要:
A method of preparing sulphur trioxide by the oxidation of sulphur dioxide contained in a reaction mixture in a stationary catalyst bed wherein the direction of the movement of the reaction mixture flow along the catalyst bed is reversed periodically each 10-200 minutes, or the temperature of said reaction mixture is changed in front of the catalyst bed from a temperature of 20.degree.-200.degree. C. to a temperature of 350.degree.-600.degree. C. each 10-200 minutes.
摘要:
A coal or petroleum combustion flue gas containing sulfur oxides and dust is treated by contacting the flue gas with a sulfur dioxide-oxidizing catalyst, thereby converting sulfur dioxide to sulfur trioxide, allowing the resulting sulfur trioxide to react with components of dust, absorbing the trioxide into the dust as a sulfate, and removing the dust. Catalytic oxidation of sulfur dioxide can be efficiently carried out at a low temperature and sulfur oxides can be efficiently removed from the flue gas.
摘要:
A catalyst suitable for use in oxidation and reduction reactions is provided. The catalyst includes an intermetallic compound of Ru, Pd, Ir or Pt and one or more base metals coated upon a substrate.
摘要:
A process for the oxidation of hydrogen sulfide to sulfur trioxide in the presence of elemental nitrogen with minimal oxidation thereof which comprises combining the hydrogen sulfide with a predetermined amount of oxygen containing gas to give at least 1% stoichiometric excess of oxygen for the oxidation of hydrogen sulfide to sulfur trioxide and passing the resulting mixture over a ceramic catalyst of the following empirical formula at a temperature between about 100.degree. C and about 700.degree. C.;w.sub.k X.sub.n J(1-k-n).sup.ZO (3.+-.m)whereinW is Zirconium, Tin or Thorium or mixtures thereof;X is an alkaline earth metal or mixture thereof;J is scandium, yttrium, a rare-earth element or mixture thereof;Z is a metal of the first transition series orA mixture thereof, at least 0.01% of said metalHaving an oxidation state other than +3;k is a number having a value between 0 and about 0.1;m is a number having a value of from 0 to 0.26; andn is a number having a value from 0 to about 0.51,Provided when n has a value of 0, k has a value between 0 and about 0.05.