摘要:
An electron injected APD with an embedded n electrode structure in which edge breakdown can be suppressed without controlling the doping profile of an n-type region of the embedded n electrode structure with high precision. The APD comprising a buffer layer with a low ionization rate is inserted between an n electrode connecting layer and an avalanche multiplication layer. Specifically, the APD is an electron injected APD in which an n electrode layer, the n electrode connecting layer, the buffer layer, the avalanche multiplication layer, an electric field control layer, a band gap gradient layer, a low-concentration light absorbing layer, a p-type light absorbing layer, and a p electrode layer are sequentially stacked, and a light absorbing portion that includes at least the low-concentration light absorbing layer and the p-type light absorbing layer forms a mesa shape.
摘要:
A wet-type flue gas desulfurization method and plant making use of a solid desulfurizing agent in which exhaust gas exhausted from a combustion apparatus such as a boiler is brought into contact with absorbing liquid to absorb sulfur oxide from the exhaust gas into the absorbing liquid followed by neutralization of the absorbing liquid containing the sulfur oxide thus absorbed. The solid desulfurizing agent is selectively retained in an absorbing liquid neutralizing zone and the absorbing liquid, containing water as a main constituent and solid products formed from the absorbed sulfur oxide, is selectively removed from the neutralizing zone. In the neutralizing zone the upward flow of the absorbing liquid, optionally augmented by an upward flow of air or water, forms a fluidized bed of limestone particles, thereby preventing coating of the limestone by gypsum and thereby retaining reactivity of limestone. According to the present invention, coexistence of Al and F in the absorbing liquid seldom deteriorates the desulfurizing performance. Further, it is possible to reduce power and cost required to grind limestone and to achieve a higher desulfurizing performance.
摘要:
A process for producing carbamic acid esters (N-phenyl carbamate) which comprises reacting an amino group-containing compound (aniline), oxygen, a nitro group-containing compound (nitrobenzene), a carbon monoxide-containing gas and a hydroxyl group-containing organic compound (ethyl alcohol) in the presence of a compound of a transition metal belonging to Pt group of VIII group (Pd) of the Periodic Table as catalyst, a non-metal halide (HCl) and water. ##STR1##
摘要:
A catalyst or a catalyst structure for removing nitrogen oxides contained in exhaust gases, having a small pressure loss and hard to cause ash deposition, and a process for producing the same are provided, which catalyst comprises a mixture of a catalyst composition of titanium oxide and at least one member of oxides of vanadium, molybdenum and tungsten, and inorganic fibers, the clearances of the inorganic fibers are filled with said catalyst composition; the ration by weight of said catalyst composition to said inorganic fibers is 3 or more; and the apparent density of said catalyst is 0.8 g/cm.sup.3 or more; and which process comprises providing a composition containing titanium oxide and at least one member of oxides of vanadium, molybdenum and tungsten, calcining said composition at 500.degree.-650.degree. C., crushing the calcined material so that powder of 20.mu. or less can occupy 90% by weight or more of the crushed material, adding water to the crushed material to form a slurry, impregnating an inorganic fiber sheet with the above slurry, placing the resulting sheet between porous molds, drying and molding it, and clacining the resulting molded material at 300.degree.-650.degree. C.
摘要:
Nitrogen oxides (NOx) are removed from combustion waste gases by injecting gas (NH.sub.3) into the combustion waste gases in the presence of a metallic catalyst to deoxidize the nitrogen oxides to nitrogen and water, within a reaction tower having the catalysts moving through the reaction tower, so that thereafter the dust may be separated from the catalysts and the catalysts may be regenerated continuously, so that the regenerated catalysts may be returned to the reaction tower. The catalyst moves in a substantially closed path, and preferable downwardly through the reaction tower, with the ammonia gas and combustion waste gases moving in cross current through the reaction tower, with mixing being enhanced by a plurality of angled baffle plates. Regeneration is accomplished by washing the catalysts, particularly ferrous catalysts with water to remove ferric sulfates, thereafter providing ferrous sulfates on the surface of the ferrous catalysts, and thereafter heating the catalysts with combustion gases separate from the ammonia gases, to dry the catalysts prior to their moving into the portion of the reaction tower having therein the mixed ammonia gas and combustion waste gases.
摘要:
A catalyst composition for reducing nitrogen oxides, which is characterized in that the same contains, as its chief ingredient,A. tin (Sn) as the component A, andB. at least one metal selected from the group consisting of molybdenum (Mo), tungsten (W), and iron (Fe), as the component (B).in the form of their oxides, and a process for reducing nitrogen oxides to nitrogen, which comprises contacting a gaseous mixture containing nitrogen oxides and molecular oxygen and a reducing gas with aforesaid catalyst composition at elevated temperatures.
摘要:
An electron injected APD with an embedded n electrode structure in which edge breakdown can be suppressed without controlling the doping profile of an n-type region of the embedded n electrode structure with high precision. The APD comprising a buffer layer with a low ionization rate is inserted between an n electrode connecting layer and an avalanche multiplication layer. Specifically, the APD is an electron injected APD in which an n electrode layer, the n electrode connecting layer, the buffer layer, the avalanche multiplication layer, an electric field control layer, a band gap gradient layer, a low-concentration light absorbing layer, a p-type light absorbing layer, and a p electrode layer are sequentially stacked, and a light absorbing portion that includes at least the low-concentration light absorbing layer and the p-type light absorbing layer forms a mesa shape.
摘要:
A wet-type flue gas desulfurization method and plant making use of a solid desulfurizing agent in which exhaust gas exhausted from a combustion apparatus such as a boiler is brought into contact with absorbing liquid to absorb sulfur oxide from the exhaust gas into the absorbing liquid followed by neutralization of the absorbing liquid containing the sulfur oxide thus absorbed. The solid desulfurizing agent is selectively retained in an absorbing liquid neutralizing zone and the absorbing liquid, containing water as a main constituent and solid products formed from the absorbed sulfur oxide, is selectively removed from the neutralizing zone. In the neutralizing zone the upward flow of the absorbing liquid, optionally augmented by an upward flow of air or water, forms a fluidized bed of limestone particles, thereby preventing coating of the limestone by gypsum and thereby retaining reactivity of limestone. According to the present invention, coexistence of Al and F in the absorbing liquid seldom deteriorates the desulfurizing performance. Further, it is possible to reduce power and cost required to grind limestone and to achieve a higher desulfurizing performance.
摘要:
Exhaust gas from combustion equipment such as a boiler is brought into contact with an absorbing liquid to absorb sulfur oxide from the exhaust gas into the absorbing liquid. Limestone particles having larger diameters are selectively retained in a zone wherein the absorbing liquid that has absorbed the sulfur oxide from the exhaust gas is neutralized. The absorbing liquid containing water and the gypsum thereby formed, as main constituents, are selectively drained from the neutralizing zone and recycled for renewed contact with the exhaust gas. Because of the possibility of a large decrease of desulfurizing performance due to a variation in the load on the boiler, etc., at least one of the following is monitored: pressure drop across the neutralizing zone, torque of a stirring device, solids concentration in the absorbing liquid, specific gravity of the absorbing liquid and viscosity of the absorbing liquid. Responsive to the monitored parameters outlet SO.sub.2 concentration is controlled within a predetermined range by regulation of at least one of the following: flow rate of the absorbing liquid circulated into contact with the exhaust gas, amount of the solid desulfurizing agent added to the absorbing liquid, particle diameter of the solid desulfurizing agent and speed of agitation of the solid desulfurizing agent in the neutralizing zone.
摘要:
The present invention relates to a method for sintering oxidized titanium powder and an active metallic component containing oxidized molybdenum as a binder for oxidized titanium granules. The active metallic component comprises one or more than one selected from a group consisting of V.sub.2 O.sub.3, Fe.sub.2 O.sub.3, WO.sub.3, Co.sub.2 O.sub.3, NiO, Cr.sub.2 O.sub.3, CeO.sub.2, SnO.sub.2, CuO, MoO.sub.3, Pt, Pd, Rh, Ru, Ir and Re.The method comprising the steps of:depositing vaporized oxidized molybdenum on the oxidized titanium powder in an atmosphere of molybdenum vapor at temperatures of 460.degree. to 650.degree. C.,forming a powdery mixture comprising the oxidized titanium powder with the deposited oxidized molybdenum and said active metallic component,adding water sufficient to make a viscous material of the powdery mixture,kneading the viscous material,shaping an article by using the viscous material, andcalcining the article to produce a product.
摘要翻译:本发明涉及氧化钛粉末和含有氧化钼作为氧化钛颗粒的粘合剂的活性金属成分的烧结方法。 活性金属组分包括选自V 2 O 3,Fe 2 O 3,WO 3,Co 2 O 3,NiO,Cr 2 O 3,CeO 2,SnO 2,CuO,MoO 3,Pt,Pd,Rh,Ru,Ir和Re中的一种或多种。 该方法包括以下步骤:在460℃至650℃的温度下,在钼蒸气气氛下,将氧化的氧化钼沉积在氧化的钛粉末上,形成包含氧化的钛粉末与沉积的氧化钼和所述活性物质的粉末混合物 金属组分,加入足以制备粉状混合物的粘性材料的水,捏合粘性物质,通过使用粘性物质成型物品,并煅烧制品以制备产品。