Catalysis
    2.
    发明授权
    Catalysis 失效
    催化

    公开(公告)号:US3909452A

    公开(公告)日:1975-09-30

    申请号:US26236372

    申请日:1972-06-13

    摘要: This invention relates to catalysts for use in the oxidation of organic compounds, for example methane, ethane, propylene and carbon monoxide, as well as for the production of methane by the steam reforming of naptha and naptha distillates. The catalyst includes an inert material on which there is applied an intermediate coating of at least one oxide selected from the group consisting of the oxides of titanium, zirconium, hafnium and thorium and a final or surface coating of a mixture or alloy of platinum, rhodium and optionally a base metal in which rhodium constitutes from 1-50 weight % and the base metal, if present, constitutes from 0.01 to 25 weight % of the total metal content.

    摘要翻译: 本发明涉及用于氧化有机化合物的催化剂,例如甲烷,乙烷,丙烯和一氧化碳,以及通过萘甲酸和萘甲酸馏分的蒸汽重整来生产甲烷。 催化剂包括惰性材料,在其上施加至少一种选自钛,锆,铪和钍的氧化物的至少一种氧化物的中间涂层,以及铂,铑的混合物或合金的最终或表面涂层 和任选的其中铑构成1-50重量%的贱金属,如果存在贱金属,则其占总金属含量的0.01至25重量%。

    Adsorbent for purifying vegetable oils from phosphorus containing compounds
    5.
    发明授权
    Adsorbent for purifying vegetable oils from phosphorus containing compounds 失效
    从含磷化合物中清除蔬菜油的吸附剂

    公开(公告)号:US3862054A

    公开(公告)日:1975-01-21

    申请号:US25740272

    申请日:1972-05-26

    CPC分类号: B01J20/2803 C11B3/10

    摘要: A granulated composition comprising 5 to 50 percent of a metal oxide of Group II or of Group III of the Periodic Table, or a mixture thereof, and 10 to 40 percent by weight of a cement which is heatresistant at 500*C and above, and 10 to 85 percent by weight of alumina or a clay free from iron oxides. The adsorbent is prepared by mixing an aqueous solution of a salt of said metals with an aqueous soda or alkali solution while simultaneously depositing, with stirring, the resulting carbonates or hydroxides of said metals onto the alumina or clay. The coated filler is separated to give a paste-like mass which is mixed, with stirring with the cement and water granulated, dried at 20* to 150*C and calcined at a temperature of from 300* to 500*C. The adsorbent may be regenerated quite easily and has a high mechanical strength up to 150 kg/cm2. The use of this adsorbent for the purification of vegetable oils makes it possible to reduce by 500 times the usual adsorbent consumption, eliminate separating oils from the adsorbent by filtration, and increase by 2 to 2.5 times the service life of catalysts employed in hydrogenation of oils.

    摘要翻译: 包含5至50%的元素周期表II或III族金属氧化物或其混合物的颗粒组合物和10至40重量%的在500℃及以上耐热的水泥,以及 10至85重量%的氧化铝或不含氧化铁的粘土。 通过将所述金属的盐的水溶液与苏打水或碱性溶液混合制备吸附剂,同时在搅拌下将所得金属的所得碳酸盐或氢氧化物同时沉积到氧化铝或粘土上。 将涂覆的填料分离,得到糊状物质,将其与水泥和水制粒搅拌混合,在20至150℃下干燥并在300至500℃的温度下煅烧。 可以很容易地再生,机械强度高达150 kg / cm2。 使用这种吸附剂来净化植物油使得可以减少常规吸附剂消耗的500倍,通过过滤消除吸附剂中的分离油,并增加油中氢化催化剂使用寿命的2〜2.5倍 。

    Hydrocracking catalyst
    6.
    发明授权
    Hydrocracking catalyst 失效
    水解催化剂

    公开(公告)号:US3860533A

    公开(公告)日:1975-01-14

    申请号:US33384873

    申请日:1973-02-20

    申请人: UNION OIL CO

    发明人: YOUNG DEAN ARTHUR

    CPC分类号: C10G47/20 B01J29/076

    摘要: Hydrocracking catalysts of improved activity comprising a Group VIB metal hydrogenation component and a crystalline aluminosilicate zeolite base are prepared by adding the Group VIB metal component to the zeolite in an aqueous acidic medium which maintains the Group VIB metal component in an essentially undissolved form. Catalysts prepared in this manner are found to display higher hydrocracking activity than conventional compositions wherein the Group VIB metal component is added to the zeolite by impregnation from an aqueous solution thereof.

    摘要翻译: 通过将VIB族金属组分添加到沸石中,将VIB族金属组分维持在基本上不溶形式的酸性介质中,制备包含VIB族金属氢化组分和结晶铝硅酸盐沸石基质的改进活性的加氢裂化催化剂。 发现以这种方式制备的催化剂显示比常规组合物更高的加氢裂化活性,其中通过从其水溶液中浸渍将VIB族金属组分加入到沸石中。

    Alumina catalyst support
    7.
    发明授权
    Alumina catalyst support 失效
    氧化铝催化剂支持

    公开(公告)号:US3856708A

    公开(公告)日:1974-12-24

    申请号:US24274872

    申请日:1972-04-10

    发明人: CARITHERS V

    摘要: In the manufacture of an alumina catalyst support, activated alumina is admixed with a binder such as cellulose ether and a filler material such as wood flour, with sufficient water to form a thick paste, which is extruded and cut into pellets, dried, rehydrated, and finally calcined. A catalyst support is provided having a high degree of macropore content, particularly as regards the proportion of total pore volume contributed by pores larger than 3,000 angstrom units.

    摘要翻译: 在氧化铝催化剂载体的制造中,活性氧化铝与纤维素醚等粘合剂和木粉等填充材料充分混合,形成厚糊状物,将其挤出并切成颗粒,干燥,再水合, 最后煅烧。 提供了具有高度大孔含量的催化剂载体,特别是关于由大于3,000埃单位的孔贡献的总孔体积的比例。

    Catalyst for use in purification of exhaust gas containing carbon monoxide
    10.
    发明授权
    Catalyst for use in purification of exhaust gas containing carbon monoxide 失效
    用于净化含有一氧化碳的废气的催化剂

    公开(公告)号:US3838069A

    公开(公告)日:1974-09-24

    申请号:US16655871

    申请日:1971-07-27

    摘要: A CATALYST CONSISTING OF MANGANESE OXIDES AND LEAD OXIDES OR ONE CONSISTING OF MANGANESE OXIDES AND BISMUTH OXIDES IN SUITABLE FOR THE OXIDATION AND PURIFICATION OF EXHAUST GAS CONTAINING CARBON MONOXIDE, AND ACARALYST CONSISTING OF THE MIXTURE OF MANGANESE OXIDES AND LEAD OXIDES TOGETHER WITH METALS OF SUCH TRANSITION ELEMENTS AS COPPER, IRON, COBALT, NICKEL, ECT, OR BISMUTH OXIDES OR THE LIKE ADDED THERETO AND A CATALYST CONSISTING OF THE MIXTURE OF MANGANESE OXIDES AND BIXMUTH OXIDES TOGETHER WITH OXIDES OF SUCH ALKALINE EARTH ELEMENTS AS MAGNESIUM, CALCIUM OR BARIUM, OXIDES OF SUCH RARE EARTH ELEMENTS AS YTTRIUM LANTHANUM, CERIUM OR NEODYMIUM, OXIDES OF ALUMINUM OR SILICON, OXIDE OR SUCH TRANSITION METALS AS COPPER, IRON, COBALT OR NICKEL, OR SOME TRANSITION METALS SUCH AS COPPER, IRON,, COBALT, NICKEL, ECT. ADDED THERETO ARE MORE SUITABLE FOR THE OXIDATION AND PURIFICATION OF EXHAUST GAS CONTAINING CARBON MONOXIDE.