公开(公告)号：US20230406701A1

公开(公告)日：2023-12-21

申请号：US18037416

申请日：2021-12-21

Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.

Inventor： Masashi Kiyosawa ,  Shigeru Nojima ,  Atsushi Tanaka ,  Kazuhiro Iwamoto ,  Takafumi Kubota

IPC: C01B3/30 ,  B01J23/745 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J23/94 ,  B01J38/00 ,  B01J8/18 ,  B01J8/26 ,  B01J8/00

CPC classification number: C01B3/30 ,  B01J23/745 ,  B01J35/006 ,  B01J35/026 ,  B01J35/023 ,  B01J35/0053 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1009 ,  B01J35/1014 ,  B01J23/94 ,  B01J38/00 ,  B01J8/1827 ,  B01J8/26 ,  B01J8/005 ,  C01B2203/0277 ,  C01B2203/0833 ,  C01B2203/1047 ,  C01B2203/1235

Abstract: A direct decomposition device for hydrocarbons for directly decomposing hydrocarbons into carbon and hydrogen includes a rector containing a catalyst including a plurality of metal particles with an iron purity of 86% or more. The reactor is configured to be supplied with a raw material gas containing hydrocarbons.

公开(公告)号：US20180214851A1

公开(公告)日：2018-08-02

申请号：US15884641

申请日：2018-01-31

Applicant: Auburn University

Inventor： Dongye ZHAO ,  Wen LIU

IPC: B01J23/10 ,  B01J20/20 ,  B01J20/28 ,  B01J20/34 ,  B01J21/06 ,  B01J23/02 ,  B01J21/18 ,  B01J35/00 ,  B01J37/02 ,  B01J37/08 ,  C02F1/28

CPC classification number: B01J23/10 ,  B01J20/20 ,  B01J20/28083 ,  B01J20/3416 ,  B01J20/3441 ,  B01J21/063 ,  B01J21/18 ,  B01J23/02 ,  B01J23/04 ,  B01J23/90 ,  B01J35/0013 ,  B01J35/004 ,  B01J35/0046 ,  B01J35/1061 ,  B01J37/0215 ,  B01J37/08 ,  B01J38/00 ,  C02F1/281 ,  C02F1/283 ,  C02F1/288 ,  C02F2101/20 ,  C02F2101/327 ,  C02F2103/02 ,  C02F2303/16 ,  C02F2305/08 ,  C02F2305/10

Abstract: A composite comprises a carbonaceous and a metallic nanotube conjugated with a carbonaceous support. The composite may be used to remove contaminants from water.

公开(公告)号：US20180169629A1

公开(公告)日：2018-06-21

申请号：US15738379

申请日：2016-05-25

Applicant: ZEON CORPORATION

Inventor： Akito NAKAI ,  Kazunori FURUKAWA

IPC: B01J23/96 ,  B01J23/44 ,  B01J38/48 ,  B01J20/10 ,  B01J20/22 ,  B01J20/28 ,  C08C19/02

CPC classification number: B01J23/96 ,  B01J20/10 ,  B01J20/22 ,  B01J20/28023 ,  B01J23/44 ,  B01J38/00 ,  B01J38/48 ,  C08C19/02 ,  C08F6/08

Abstract: A method for recovering a catalyst, wherein a solution containing a reaction mixture obtained by performing a hydrogenation reaction in a presence of a catalyst containing a platinum group metal is brought into contact with a fiber membrane having a group containing an amino group or a thiol group on a surface, thereby recovering the platinum group metal included in the solution is provided.

公开(公告)号：US09926253B2

公开(公告)日：2018-03-27

申请号：US15605915

申请日：2017-05-25

Applicant: ZHEJIANG UNIVERSITY OF TECHNOLOGY

Inventor： Yong Nie ,  Qinglong Xie ,  Ruchao Gong ,  Ying Duan ,  Shanshan Li ,  Yang Liu ,  Xiaojiang Liang ,  Zhenyu Wu ,  Meizhen Lu ,  Fengwen Yu ,  Jianbing Ji

IPC: C07C45/52 ,  B01J23/00 ,  B01J27/00 ,  C07C45/00 ,  B01J23/30 ,  B01J27/188 ,  B01J35/00

CPC classification number: B01J27/188 ,  B01J23/30 ,  B01J27/224 ,  B01J38/00 ,  C07C45/52 ,  C07C47/22

Abstract: A novel method for catalytic dehydration of glycerol to acrolein is provided. A fixed bed reactor is used, which is placed in a microwave unit. The feedstock is introduced into the fixed bed reactor after being preheated and gasified. Continuous glycerol dehydration occurs in the presence of a microwave-absorbing catalyst in the fixed bed reactor to form acrolein. The microwave-absorbing catalyst is composed of an active component loaded on a core-shell structure which consists of microwave absorbent coated by an oxide. The uniformity of microwave heating can reduce the formation of hot spot during the reaction and hence improve the catalyst stability. The process and operation is simple, and the unit can steadily run for a long time.

公开(公告)号：US20180021724A1

公开(公告)日：2018-01-25

申请号：US15694051

申请日：2017-09-01

Applicant: Johnson Matthey Public Limited Company

Inventor： Paul Joseph ANDERSEN ,  Maria BRANDMAIR ,  Silvia Alcove CLAVE ,  Rodney FOO ,  Bruce GOMERSALL ,  Michael NASH ,  Alison Mary WAGLAND

IPC: B01D53/86 ,  B01D53/94 ,  B01J23/28 ,  B01J23/30 ,  B01J23/92 ,  B01J37/02 ,  B01J38/00 ,  B01J38/48 ,  B01J35/02 ,  B01D53/96 ,  B01J35/04 ,  B01J37/08 ,  B01D53/88

CPC classification number: B01D53/8628 ,  B01D53/88 ,  B01D53/9418 ,  B01D53/96 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/2092 ,  B01D2255/30 ,  B01D2255/40 ,  B01D2255/9202 ,  B01D2258/012 ,  B01D2258/0283 ,  B01J23/28 ,  B01J23/30 ,  B01J23/92 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0225 ,  B01J37/0232 ,  B01J37/0234 ,  B01J37/0244 ,  B01J37/08 ,  B01J38/00 ,  B01J38/485 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/31 ,  B01J2523/47 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

Abstract: Articles comprising a catalyst film comprising VOx, MoO3 or WO3, and TiO2 deposited on a substrate are disclosed. The articles are useful for selective catalytic reduction (SCR) of NOx in exhaust gases. Methods for producing such articles deposit a catalyst film on the substrate to form a coated substrate, which is then calcined. When used in an SCR process, the coated articles have enhanced activity for NOx conversion, reduced activity for SOx conversion, or both. Light-weight, coated articles having high catalyst loads can be fabricated at the same or reduced dimensions when compared with laminated articles, and increased kNOx/kSOx ratios are available even from coated articles having relatively thin catalyst films. The articles should have particular value for power plant operations, where coal and high-sulfur fuels are commonly used and controlling sulfur trioxide generation is critical.

公开(公告)号：US09023286B2

公开(公告)日：2015-05-05

申请号：US13458592

申请日：2012-04-27

Applicant: Richard A. Johnson, II ,  Paolo Palmas

Inventor： Richard A. Johnson, II ,  Paolo Palmas

IPC: B01J8/12 ,  B01J38/26

CPC classification number: B01J8/125 ,  B01J8/08 ,  B01J38/00 ,  B01J38/26 ,  B01J2208/0084 ,  B01J2208/00884 ,  B01J2208/00938

Abstract: A process and device for the regeneration of catalyst is presented. The device includes a series of grids within a regeneration vessel, where each grid includes small openings for the passage of gas, and larger openings for the passage of catalyst. The grids span horizontally across the vessel, and are spaced vertically apart to create a flow of catalyst down through the regenerator.

Abstract translation: 提出了催化剂再生的方法和装置。 该装置包括再生容器内的一系列栅格，其中每个栅格包括用于气体通过的小开口和用于催化剂通过的较大开口。 栅格横跨容器横跨，并且垂直间隔开，从而通过再生器产生催化剂流。

公开(公告)号：US20120310021A1

公开(公告)日：2012-12-06

申请号：US13481121

申请日：2012-05-25

Applicant: Joshua Close ,  Haiyou Wang ,  Hsueh Sung Tung

Inventor： Joshua Close ,  Haiyou Wang ,  Hsueh Sung Tung

IPC: C07C17/275

CPC classification number: C07C17/275 ,  B01J23/745 ,  B01J23/94 ,  B01J31/0257 ,  B01J35/023 ,  B01J37/04 ,  B01J38/00 ,  B01J2231/32 ,  C07C17/278 ,  Y02P20/584 ,  C07C19/01

Abstract: Disclosed is a process for the manufacture of haloalkane compounds, and more particularly, an improved process for the manufacture of the compound 1,1,1,3,3-penta-chloropropane (HCC-240fa), which mitigates the formation of by-products from vinyl chloride (CH2═CHCl). The present invention is also useful in the manufacture of other haloalkane compounds such as HCC-250 and HCC-360. One embodiment of the invention comprises a method for mitigating 1,1,3,3,5,5-hexachloropentane and 1,1,1,3,5,5-hexachloropentane formation in the HCC-240fa manufacturing process, in which FeCl3, is introduced to a reactor only after the start-up phase has ended and a continuous operation has started. In a preferred embodiment, “pre-chelated” FeCl3, which is concentrated in a catalyst recovery column, is introduced to reactor after the continuous operation has started.

Abstract translation: 公开了一种制备卤代烷烃化合物的方法，更具体地说，涉及制备化合物1,1,1,3,3-五氯丙烷（HCC-240fa）的改进方法，其减少副产物的形成， 氯乙烯（CH 2 = CHCl）的产物。 本发明也可用于制备其它卤代烷烃化合物如HCC-250和HCC-360。 本发明的一个实施方案包括在HCC-240fa制造方法中减轻1,1,3,3,5,5-六氯戊烷和1,1,1,3,5,5-六氯戊烷形成的方法，其中FeCl 3， 仅在启动阶段结束并且连续运行已经开始之后被引入反应器。 在优选的实施方案中，将浓缩在催化剂回收塔中的预螯合的FeCl 3在连续操作开始之后引入反应器。

公开(公告)号：US20120071316A1

公开(公告)日：2012-03-22

申请号：US13266676

申请日：2010-04-26

Applicant: Hartwig Voss ,  Ekkehard Schwab ,  Bram Willem Hoffer ,  Till Gerlach

Inventor： Hartwig Voss ,  Ekkehard Schwab ,  Bram Willem Hoffer ,  Till Gerlach

IPC: B01J38/72

CPC classification number: B01D61/147 ,  B01D61/027 ,  B01D61/142 ,  B01D61/145 ,  B01D61/58 ,  B01D2315/16 ,  B01J21/18 ,  B01J23/38 ,  B01J23/44 ,  B01J25/02 ,  B01J38/00 ,  B01J38/48

Abstract: The present invention relates to a method of conditioning suspended catalysts, wherein at least part of the catalyst-comprising reaction medium is taken from one or more reactors and the suspended, at least partially inactivated catalysts are separated off and purified by means of at least one membrane filtration, with at least one of the membrane filtrations being carried out as a diafiltration.

Abstract translation: 本发明涉及一种调节悬浮催化剂的方法，其中至少部分含催化剂的反应介质取自一个或多个反应器，悬浮的，至少部分失活的催化剂被分离出并通过至少一种 膜过滤，其中至少一个膜过滤作为渗滤进行。

公开(公告)号：US07517446B2

公开(公告)日：2009-04-14

申请号：US11117203

申请日：2005-04-28

Applicant: Roger K. Lott ,  Lap-Keung Lee ,  Peter C. Quinn

Inventor： Roger K. Lott ,  Lap-Keung Lee ,  Peter C. Quinn

IPC: C10G45/00 ,  C10G47/00

CPC classification number: B01J27/047 ,  B01J27/051 ,  B01J35/0013 ,  B01J37/02 ,  B01J37/086 ,  B01J38/00 ,  B01J38/68 ,  C10G45/00 ,  C10G47/00 ,  C10G49/04 ,  C10G65/02 ,  C10G65/12

Abstract: A fixed bed hydroprocessing system, and also a method for upgrading a pre-existing fixed bed hydroprocessing system, involves preliminarily upgrading a heavy oil feedstock in one or more slurry phase reactors using a colloidal or molecular catalyst and then further hydroprocessing the upgraded feedstock within one or more fixed bed reactors using a porous supported catalyst. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor composition into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the precursor composition to form the colloidal or molecular catalyst in situ. Asphaltene or other hydrocarbon molecules otherwise too large to diffuse into the pores of the fixed bed catalyst can be upgraded by the colloidal or molecular catalyst. One or more slurry phase reactors may be built and positioned upstream from one or more fixed bed reactors of a pre-existing fixed bed system and/or converted from one or more pre-existing fixed bed reactors.

Abstract translation: 固定床加氢处理系统以及升级预先存在的固定床加氢处理系统的方法包括使用胶体或分子催化剂对一个或多个淤浆相反应器中的重油原料进行初步升级，然后在一个 或更多的固定床反应器。 胶体或分子催化剂通过将催化剂前体组合物紧密地混合到重油原料中并将原料的温度升高到高于前体组合物的分解温度以形成原位形成胶态或分子催化剂而形成。 否则通过胶体或分子催化剂可以提高沥青质或其它烃分子，否则太大而不能扩散到固定床催化剂的孔中。 一个或多个淤浆相反应器可以建立并定位在预先存在的固定床系统的一个或多个固定床反应器的上游和/或从一个或多个预先存在的固定床反应器转化。

公开(公告)号：US07410930B2

公开(公告)日：2008-08-12

申请号：US10527058

申请日：2004-03-09

Applicant: Hidenobu Wakita ,  Kiyoshi Taguchi ,  Seiji Fujihara ,  Kunihiro Ukai

Inventor： Hidenobu Wakita ,  Kiyoshi Taguchi ,  Seiji Fujihara ,  Kunihiro Ukai

IPC: C01B21/00

CPC classification number: C22B11/028 ,  B01J23/96 ,  B01J38/00 ,  C22B7/009 ,  C22B11/048 ,  Y02P10/214

Abstract: The present invention is a method for recovering a catalyst from a catalyst body comprising a carrier having a catalyst layer formed on at least a part of the surface thereof, which comprises (a) a step of forming an overcoat layer on the surface of the catalyst layer, and (b) a step of allowing the catalyst body having the overcoat layer formed thereon to stand under the condition to result in a difference in expansibility or contractility exhibited by the overcoat layer from that exhibited by the carrier, wherein exfoliation of the catalyst layer from the carrier is permitted by means of the resulting difference in expansibility or contractility under the condition.

Abstract translation: 本发明是一种从催化剂体中回收催化剂的方法，该催化剂体包含在其表面的至少一部分上形成有催化剂层的载体，其包括（a）在催化剂表面上形成外涂层的步骤 层，以及（b）使在其上形成有外涂层的催化剂体在由载体表现出的外涂层的扩展性或收缩性差异的状态下放置的步骤，其中催化剂的剥离 通过在条件下的可扩展性或收缩性的差异允许来自承运人的层。