公开(公告)号：US20180021724A1

公开(公告)日：2018-01-25

申请号：US15694051

申请日：2017-09-01

申请人： Johnson Matthey Public Limited Company

发明人： Paul Joseph ANDERSEN ,  Maria BRANDMAIR ,  Silvia Alcove CLAVE ,  Rodney FOO ,  Bruce GOMERSALL ,  Michael NASH ,  Alison Mary WAGLAND

IPC分类号： B01D53/86 ,  B01D53/94 ,  B01J23/28 ,  B01J23/30 ,  B01J23/92 ,  B01J37/02 ,  B01J38/00 ,  B01J38/48 ,  B01J35/02 ,  B01D53/96 ,  B01J35/04 ,  B01J37/08 ,  B01D53/88

CPC分类号： B01D53/8628 ,  B01D53/88 ,  B01D53/9418 ,  B01D53/96 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/2092 ,  B01D2255/30 ,  B01D2255/40 ,  B01D2255/9202 ,  B01D2258/012 ,  B01D2258/0283 ,  B01J23/28 ,  B01J23/30 ,  B01J23/92 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0225 ,  B01J37/0232 ,  B01J37/0234 ,  B01J37/0244 ,  B01J37/08 ,  B01J38/00 ,  B01J38/485 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/31 ,  B01J2523/47 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

摘要： Articles comprising a catalyst film comprising VOx, MoO3 or WO3, and TiO2 deposited on a substrate are disclosed. The articles are useful for selective catalytic reduction (SCR) of NOx in exhaust gases. Methods for producing such articles deposit a catalyst film on the substrate to form a coated substrate, which is then calcined. When used in an SCR process, the coated articles have enhanced activity for NOx conversion, reduced activity for SOx conversion, or both. Light-weight, coated articles having high catalyst loads can be fabricated at the same or reduced dimensions when compared with laminated articles, and increased kNOx/kSOx ratios are available even from coated articles having relatively thin catalyst films. The articles should have particular value for power plant operations, where coal and high-sulfur fuels are commonly used and controlling sulfur trioxide generation is critical.

公开(公告)号：US20180280943A1

公开(公告)日：2018-10-04

申请号：US15937902

申请日：2018-03-28

申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY

发明人： Silvia ALCOVE CLAVE ,  Paul ANDERSEN ,  Maria BRANDMAIR ,  Manop HUBER ,  Michael NASH ,  David REPP

IPC分类号： B01J27/199 ,  B01D53/94 ,  B01D53/14

摘要： A catalyst for treating an exhaust gas comprising SO2, NOx and elemental mercury in the presence of a nitrogenous reductant comprises a composition containing oxides of: (i) Molybdenum (Mo) and optionally Tungsten (W); and (ii) Vanadium (V); and (iii) Titanium (Ti); and(iv) Phosphorus (P), wherein, with respect to the total metal atoms in the composition, the composition comprises: (i) Mo in an amount of less than 2 at. %, and optionally up to 9 at. % W; (ii) from 2.5 to 12 at. % V; (iii) from 85 to 96 at. % Ti, and wherein the composition comprises (iv) P in an atomic ratio to the sum of atoms of Mo, W and V of from 1:2 to 3:2. The values expressed must total 100%.

公开(公告)号：US20150343422A1

公开(公告)日：2015-12-03

申请号：US14726719

申请日：2015-06-01

申请人： Johnson Matthey Public Limited Company

发明人： Silvia Alcove CLAVE ,  Michael NASH ,  Paul Joseph ANDERSEN ,  Maria BRANDMAIR ,  Rodney FOO ,  Alison Mary WAGLAND ,  Bruce GOMERSALL

IPC分类号： B01J23/28 ,  B01J37/08 ,  B01J23/30 ,  B01J37/02 ,  B01J38/00 ,  B01D53/86

CPC分类号： B01D53/8628 ,  B01D53/88 ,  B01D53/9418 ,  B01D53/96 ,  B01D2251/2062 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/2092 ,  B01D2255/30 ,  B01D2255/40 ,  B01D2255/9202 ,  B01D2258/012 ,  B01D2258/0283 ,  B01J23/28 ,  B01J23/30 ,  B01J23/92 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0215 ,  B01J37/0225 ,  B01J37/0232 ,  B01J37/0234 ,  B01J37/0244 ,  B01J37/08 ,  B01J38/00 ,  B01J38/485 ,  B01J2523/00 ,  B01J2523/41 ,  B01J2523/31 ,  B01J2523/47 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69

摘要： Articles comprising a catalyst film comprising VOx, MoO3 or WO3, and TiO2 deposited on a substrate are disclosed. The articles are useful for selective catalytic reduction (SCR) of NOx in exhaust gases. Methods for producing such articles deposit a catalyst film on the substrate to form a coated substrate, which is then calcined. When used in an SCR process, the coated articles have enhanced activity for NOx conversion, reduced activity for SOx conversion, or both. Light-weight, coated articles having high catalyst loads can be fabricated at the same or reduced dimensions when compared with laminated articles, and increased kNOx/kSOx ratios are available even from coated articles having relatively thin catalyst films. The articles should have particular value for power plant operations, where coal and high-sulfur fuels are commonly used and controlling sulfur trioxide generation is critical.

摘要翻译： 公开了包含一种包含VO x，MoO 3或WO 3的催化剂膜和沉积在基板上的TiO 2的制品。 这些制品可用于废气中NOx的选择性催化还原（SCR）。 制造这种制品的方法在基材上沉积催化剂膜以形成涂覆的基材，然后将其煅烧。 当用于SCR工艺时，涂层制品具有增强的NOx转化活性，减少SOx转化的活性或两者。 与层压制品相比，可以以相同或较小的尺寸制造具有高催化剂载荷的轻质涂层制品，并且甚至可以使用具有相对薄的催化剂膜的涂布制品提高kNO x / k SO x比。 这些物品对于电厂运行具有特别的价值，其中通常使用煤和高硫燃料，并控制三氧化硫的生成至关重要。

公开(公告)号：US20180280946A1

公开(公告)日：2018-10-04

申请号：US15937896

申请日：2018-03-28

申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY

发明人： Silvia Alcove Clave ,  Paul ANDERSEN ,  Maria BRANDMAIR ,  Manop HUBER ,  Michael NASH ,  David REPP

IPC分类号： B01J29/78 ,  B01D53/94 ,  B01D53/14

摘要： A catalyst for treating an exhaust gas comprising SO2, NOx and elemental mercury in the presence of a nitrogenous reductant comprises a composition containing oxides of: (i) Molybdenum (Mo) and/or Tungsten (W); (ii) Vanadium (V); (iii) Titanium (Ti), and (iv) an MFI zeolite, wherein the composition comprises, based on the total weight of the composition: (i) 1 to 6 wt % of MoO3 and/or 1 to 10 wt % WO3; and (ii) 0.1 to 3 wt % V2O5, and (iii) 48.5 to 94.5 wt % TiO2; and (iv) 35 to 50 wt % MFI zeolite.