公开(公告)号：US20230226604A1

公开(公告)日：2023-07-20

申请号：US17997879

申请日：2021-05-07

Applicant: SEOUL NATIONAL UNIVERSITY R&DB FOUNDATION ,  INSTITUTE FOR BASIC SCIENCE

Inventor： Taeghwan HYEON ,  Yung-Eun SUNG ,  Tae Yong YOO ,  Ji Mun YOO

IPC: B22F1/054 ,  B22F1/142 ,  B01J35/00 ,  B01J23/89 ,  B01J37/08 ,  B22F1/16 ,  B01J21/18 ,  B01J37/32

CPC classification number: B22F1/054 ,  B22F1/142 ,  B01J35/0013 ,  B01J23/8906 ,  B01J37/088 ,  B22F1/16 ,  B01J21/18 ,  B01J37/32 ,  B22F2301/35

Abstract: Alloy nanoparticles, and a method for forming the alloy nanoparticles, an alloy nanocatalyst comprising the alloy nanoparticles are provided. The alloy nanoparticles are formed by a method comprising mixing a first metal complex including a first metal and a second metal complex including a second metal to form a multimetal compound and heat-treating the multimetal compound to form an alloy compound. The first metal and the second metal comprise transition metal, the first metal complex comprises a pyridine-based ligand, and a carbon shell containing N is formed on the surface of the alloy compound by the heat treatment.

公开(公告)号：US11084027B2

公开(公告)日：2021-08-10

申请号：US16396607

申请日：2019-04-26

Applicant: SOOCHOW UNIVERSITY

Inventor： Jianmei Lu ,  Najun Li

IPC: B01J37/32 ,  B01J35/00 ,  B01J27/19 ,  B01J37/00 ,  B01J37/04 ,  B01J37/06 ,  B01J37/08 ,  C02F1/30 ,  C02F101/34

Abstract: A method of preparing a three-dimensional composite material includes the following steps: preparing polystyrene by soap-free emulsion polymerizing, obtaining polystyrene opal by a vertical deposition method, synthesizing MoP IO (molybdenum phosphide inverse opal), and compounding with quantum points CdS, so as to obtain a novel inorganic composite material, namely cadmium sulfide quantum dot-compounded MoP IO. The preparation method has the advantages that the MoP IO is prepared first, and the MoP IO is of a three-dimensional cyclic pore structure and has the photonic band gap feature, so that the MoP IO has better catalysis effect in light catalysis in comparison with that of common porous material; the MoP IO is compounded with the cadmium sulfide quantum dots, so that the light absorbing ability is enhanced, and the composite material capable of absorbing the visible light is obtained.

公开(公告)号：US11046587B2

公开(公告)日：2021-06-29

申请号：US16308928

申请日：2017-06-14

Applicant: BASF SE

Inventor： Stefan Marx ,  Stefanie Clade ,  Lena Arnold ,  Uwe Diehlmann ,  Ulrich Mueller

IPC: C01B39/02 ,  C01B39/48 ,  B01D53/94 ,  B01J29/06 ,  B01J29/70 ,  B01J29/76 ,  C01B39/04 ,  B01J29/072 ,  B01J19/00 ,  B01J19/18 ,  B01J37/32 ,  B01J37/00 ,  B01J29/86 ,  B01J29/87

Abstract: A continuous process for preparing a zeolitic material comprising (i) preparing a mixture comprising a source of YO2, optionally a source of X2O3, and a liquid solvent system; (ii) continuously feeding the mixture prepared in (i) into a continuous flow reactor at a liquid hourly space velocity in the range of from 0.3 to 20 h−1 for a duration of at least 1 h; and (iii) crystallizing the zeolitic material from the mixture in the continuous flow reactor, wherein the mixture is heated to a temperature in the range of from 100 to 300° C.; wherein the volume of the continuous flow reactor is in the range of from 150 cm3 to 75 m3, as well as to zeolitic materials which may be obtained according to the inventive process and to their use.

公开(公告)号：US09539563B2

公开(公告)日：2017-01-10

申请号：US14118748

申请日：2012-05-30

Applicant: Vincenzo Roberto Calderone ,  Nirappurackal Raveendran Shiju ,  Gad Rothenberg ,  Daniel Curulla-Ferre

Inventor： Vincenzo Roberto Calderone ,  Nirappurackal Raveendran Shiju ,  Gad Rothenberg ,  Daniel Curulla-Ferre

IPC: B01J23/00 ,  B01J23/75 ,  B01J35/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/06 ,  B01J37/32 ,  B01J35/08 ,  B01J37/18 ,  B01J37/00

CPC classification number: B01J23/75 ,  B01J23/745 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/008 ,  B01J35/08 ,  B01J37/0009 ,  B01J37/0072 ,  B01J37/0217 ,  B01J37/0221 ,  B01J37/0225 ,  B01J37/031 ,  B01J37/06 ,  B01J37/18 ,  B01J37/32 ,  C10G2/332

Abstract: The present invention pertains to novel core-shell particles comprising a core of iron oxide and a shell of cobalt oxide, characterized in that they are spherical with a number average diameter, as measured by TEM, of between 1 and 20 nm. This invention is also directed to their uses in the manufacture of a catalyst, and to the method for preparing these particles, by precipitating cobalt oxide onto magnetite or hematite particles which are themselves precipitated from Fe(III) and optionally Fe(II) salts.

Abstract translation: 本发明涉及包含氧化铁芯和氧化钴壳的新型核 - 壳颗粒，其特征在于它们是通过TEM测量的数均直径为1至20nm的球形。 本发明还涉及它们在制备催化剂中的用途，以及通过将氧化钴沉淀在本身从Fe（III）和任选的Fe（II）盐沉淀的磁铁矿或赤铁矿颗粒上制备这些颗粒的方法。

公开(公告)号：US09187339B2

公开(公告)日：2015-11-17

申请号：US12676626

申请日：2008-09-04

Applicant: Takayoshi Sasaki ,  Yasuo Ebina ,  Hirofumi Taniguchi ,  Yusuke Uesusuki

Inventor： Takayoshi Sasaki ,  Yasuo Ebina ,  Hirofumi Taniguchi ,  Yusuke Uesusuki

IPC: B32B15/08 ,  C09D5/00 ,  B05D3/06 ,  B05D1/36 ,  C08K3/22 ,  B01J31/02 ,  B32B15/04 ,  C01G23/04 ,  B01J35/00 ,  B82Y30/00 ,  C01G23/00 ,  C01G23/047 ,  C09C1/36 ,  C09D5/32 ,  C09D7/12 ,  C09D17/00 ,  G02B5/20 ,  B01J37/02 ,  B01J37/32

CPC classification number: C01G23/04 ,  B01J35/004 ,  B01J37/0215 ,  B01J37/0219 ,  B01J37/0244 ,  B01J37/32 ,  B82Y30/00 ,  C01G23/005 ,  C01G23/047 ,  C01P2002/84 ,  C01P2004/03 ,  C01P2004/04 ,  C01P2004/20 ,  C01P2004/22 ,  C01P2004/62 ,  C01P2004/64 ,  C01P2004/84 ,  C01P2006/60 ,  C08K3/22 ,  C09C1/3607 ,  C09D5/32 ,  C09D7/70 ,  C09D17/007 ,  G02B5/208

Abstract: Disclosed is an organic dispersion comprising a flaky titanium oxide particle having a high crystallinity and high light permeability contained in an organic solvent. The dispersion can be prepared by a method comprising preparing an aqueous dispersion of a flaky titanium oxide particle containing an organic cation, centrifuging the aqueous dispersion to produce a precipitate, and adding the precipitate to an organic solvent, or a method comprising lyophilizing the aqueous dispersion to produce a lyophilized material and mixing the lyophilized material to an organic solvent. When the organic dispersion is used, it becomes possible to form a film comprising a monolayer of a titanium oxide nanosheet densely arranged therein by such a simple manner that the dispersion is coated on a base material and drying the dispersion. The film thus produced has a photocatalytic activity and a super-hydrophilic property.

Abstract translation: 公开了一种有机分散体，其包含在有机溶剂中包含的具有高结晶度和高透光性的片状氧化钛颗粒。 分散体可以通过包括制备含有有机阳离子的片状氧化钛颗粒的水性分散体的方法制备，离心水分散体以产生沉淀物，并将沉淀物加入到有机溶剂中，或者包括冻干水分散体 以产生冻干材料并将冻干的材料混合到有机溶剂中。 当使用有机分散体时，可以通过这样一种简单的方式将分散体涂覆在基材上并干燥分散体形成包含其中密集布置的氧化钛纳米片的单层的薄膜。 由此制得的膜具有光催化活性和超亲水性。

公开(公告)号：US09149795B2

公开(公告)日：2015-10-06

申请号：US13115814

申请日：2011-05-25

Applicant: Ender Savrun ,  Stephanie J. Sawhill

Inventor： Ender Savrun ,  Stephanie J. Sawhill

IPC: B01J21/06 ,  B01J23/46 ,  F02K9/70 ,  F02K9/80 ,  F02C3/14 ,  B01J37/32 ,  B01J23/40 ,  B01J35/00 ,  B01J37/00 ,  B01J37/02

CPC classification number: B01J21/066 ,  B01J23/40 ,  B01J23/468 ,  B01J35/002 ,  B01J37/0018 ,  B01J37/0036 ,  B01J37/0201 ,  B01J37/32 ,  F02C3/14 ,  F02K9/70 ,  F02K9/80

Abstract: Ceramic catalyst carriers that are mechanically, thermally and chemically stable in a ionic salt monopropellant decomposition environment and high temperature catalysts for decomposition of liquid high-energy-density monopropellants are disclosed. The ceramic catalyst carrier has excellent thermal shock resistance, good compatibility with the active metal coating and metal coating deposition processes, melting point above 1800° C., chemical resistance to steam, nitrogen oxides and acids, resistance to sintering to prevent void formation, and the absence of phase transition associated with volumetric changes at temperatures up to and beyond 1800° C.

Abstract translation: 公开了在离子盐单推进剂分解环境中机械，热和化学稳定的陶瓷催化剂载体和用于分解液体高能密度单推进剂的高温催化剂。 陶瓷催化剂载体具有优异的耐热冲击性，与活性金属涂层和金属涂层沉积工艺的良好相容性，熔点高于1800℃，耐蒸汽，氮氧化物和酸的耐化学性，耐烧结以防止空隙形成，以及 在高于和超过1800°C的温度下，不存在与体积变化相关的相变。

公开(公告)号：US20050050994A1

公开(公告)日：2005-03-10

申请号：US10777482

申请日：2004-02-12

Applicant: Martin Devenney ,  Konstantinos Chondroudis ,  Alexander Gorer

Inventor： Martin Devenney ,  Konstantinos Chondroudis ,  Alexander Gorer

IPC: B01J19/00 ,  B01J37/18 ,  B01J37/32 ,  B22F9/18 ,  C40B30/08 ,  C40B40/18 ,  C40B60/14 ,  H01M4/88 ,  H01M4/92

CPC classification number: B01J37/18 ,  B01J19/0046 ,  B01J37/32 ,  B01J2219/00308 ,  B01J2219/00486 ,  B01J2219/00495 ,  B01J2219/00691 ,  B01J2219/00702 ,  B01J2219/00745 ,  B01J2219/00747 ,  B01J2219/00752 ,  C40B30/08 ,  C40B40/18 ,  C40B60/14 ,  H01M4/92

Abstract: The present invention is directed to a method for forming combinatorial libraries comprising arrays of materials prepared by depositing a metal species on a support for use as catalysts, such as electrocatalysts. The invention is also directed to combinatorial libraries comprising an array of such metal-containing supported catalysts. These catalyst-containing libraries are particularly well-suited for use in conducting combinatorial research investigations, in particular with respect to electrocatalysts for fuel cells.

Abstract translation: 本发明涉及一种用于形成组合文库的方法，其包括通过将金属物质沉积在用作催化剂如电催化剂的载体上制备的材料阵列。 本发明还涉及包含这种含金属的负载催化剂的阵列的组合文库。 这些含催化剂的文库特别适用于进行组合研究调查，特别是关于燃料电池的电催化剂。

公开(公告)号：US5055441A

公开(公告)日：1991-10-08

申请号：US473543

申请日：1990-02-01

Applicant: Eugene M. McCarron, III ,  John B. Parise

Inventor： Eugene M. McCarron, III ,  John B. Parise

IPC: B01J23/28 ,  B01J23/30 ,  B01J37/00 ,  B01J37/32 ,  C01G39/02 ,  C01G41/00

CPC classification number: C01G41/00 ,  B01J23/28 ,  B01J23/30 ,  B01J37/0045 ,  B01J37/0054 ,  B01J37/32 ,  C01G39/02 ,  C01P2002/54 ,  C01P2002/76 ,  C01P2002/77 ,  C01P2006/12

Abstract: A beta phase of molybdenum trioxide or the mixed metal oxides of molybdenum and tungsten is prepared by spray-freezing then freeze-drying, affording a powder which is then heated to a temperature of 275.degree. C. to 450.degree. C.

Abstract translation: 通过喷雾冷冻然后冷冻干燥制备三氧化钼或钼和钨的混合金属氧化物的β相，得到粉末，然后将其加热至275℃至450℃。

公开(公告)号：US3516784A

公开(公告)日：1970-06-23

申请号：US3516784D

申请日：1967-09-19

Applicant: SYLVANIA ELECTRIC PROD

Inventor： DODDS ROBERT E

IPC: B01J37/32 ,  C01G49/00 ,  C01G41/00

CPC classification number: C01G49/0009 ,  B01J37/32 ,  C01G49/0018 ,  C01P2002/76 ,  C01P2002/86

公开(公告)号：US20230286834A1

公开(公告)日：2023-09-14

申请号：US18117445

申请日：2023-03-05

Applicant: Beijing Normal University, Zhuhai

Inventor： Yi Yang ,  Lulu Bao ,  Huiqi Zhu ,  Xuhui Xu ,  Yinuo Wang ,  Yuxi Long ,  Ruikun Xu ,  Haowen Lin ,  Chenyang Zheng

IPC: C02F1/44 ,  B01J37/32 ,  B01J37/08 ,  B01D71/42 ,  B01D71/28 ,  B01D69/12 ,  B01J23/745

CPC classification number: C02F1/44 ,  B01J37/32 ,  B01J37/08 ,  B01D71/421 ,  B01D71/281 ,  B01D69/1213 ,  B01J23/745 ,  C02F2101/30

Abstract: A preparation method of a gradient long-effective catalytic membrane with high-strength and anti-deposition property is provided and includes: adding a nanometal oxide catalyst into an N, N-dimethylformamide solution of polyacrylonitrile or polystyrene, uniformly mixing, performing electrostatic spinning, keeping a receiver at −190° C. to −200° C. in the electrostatic spinning process, and performing freeze drying on a precursor membrane obtained after the electrostatic spinning is finished, so as to obtain the gradient long-effective catalytic membrane. According to the method, the gradient long-effective catalytic membrane with high-strength and anti-deposition property is obtained through a one-step method which adopts an ultralow-temperature-electrostatic spinning technology and combines with nanometal, the contradictory relation between the catalytic efficiency and the membrane stability in a traditional catalytic membrane is solved, the catalytic performance of the membrane is fully played, the organic polluted wastewater can be efficiently catalytically degraded, and the service life of the catalytic membrane is prolonged.