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    Method of preparing pentafluoroethane, catalysts for fluorination and a preparation method thereof
    1.
    发明授权
    Method of preparing pentafluoroethane, catalysts for fluorination and a preparation method thereof 有权
    五氟乙烷制备方法，氟化催化剂及其制备方法

    公开(公告)号：US06503865B1

    公开(公告)日：2003-01-07

    申请号：US10172970

    申请日：2002-06-18

    申请人： Takashi Kanemura ,  Takashi Shibanuma

    发明人： Takashi Kanemura ,  Takashi Shibanuma

    IPC分类号： B01J2706

    CPC分类号： C07C17/206 ,  B01J23/26 ,  B01J23/864 ,  B01J23/866 ,  B01J35/002 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/0036 ,  B01J37/0072 ,  B01J37/031 ,  B01J37/26 ,  C07C17/21 ,  C07C19/08

    摘要： A method of preparing pentafluoroethane wherein chlorine-containing carbon compounds are fluorinated in the presence of chromium catalysts that are in an amorphous state and wherein the main component is chromium compounds with the addition of at least one metal element selected from the group composed of indium, gallium, cobalt, nickel, zinc and aluminum and the average valence of the chromium in said chromium compounds is not less than +3.5 but not more than +5.0. And said chromium catalysts and a preparation method thereof. A method of preparing pentafluoroethane wherein the total yield of chlorofluoroethane by-products can be decreased without significantly deteriorating the generation activity of the pentafluoroethane and compounds which can be recycled in the reaction system. And to provide catalysts for this fluorination and a preparation method thereof.

    摘要翻译： 一种制备五氟乙烷的方法，其中含铬碳化合物在铬催化剂存在下为氟化，其为非晶状态，其中主要成分为铬化合物，加入至少一种选自铟， 镓，钴，镍，锌和铝，并且所述铬化合物中的铬的平均化合价不小于+ 3.5且不大于+ 5.0。 所述铬催化剂及其制备方法。一种制备五氟乙烷的方法，其中可以降低氯氟乙烷副产物的总产率而不显着降低五氟乙烷的生成活性和可在反应体系中再循环的化合物。 并为该氟化提供催化剂及其制备方法。

    Process for activating halogenated catalysts, catalysts obtained by this process, and use of these catalysts in acid catalyst processes
    2.
    发明授权
    Process for activating halogenated catalysts, catalysts obtained by this process, and use of these catalysts in acid catalyst processes 失效
    用于活化卤代催化剂的方法，通过该方法获得的催化剂以及这些催化剂在酸催化剂方法中的用途

    公开(公告)号：US06194345B1

    公开(公告)日：2001-02-27

    申请号：US09319595

    申请日：1999-09-10

    申请人： Peter Mangnus ,  Alain Milan ,  Georges Szabo

    发明人： Peter Mangnus ,  Alain Milan ,  Georges Szabo

    IPC分类号： B01J2706

    CPC分类号： B01J29/76 ,  B01J29/7049 ,  B01J2229/26 ,  B01J2229/42

    摘要： The invention relates to a process of activating a supported acid catalyst, and consists in the conversion of Lewis acid-type acid sites which are deposited on a solid substrate into activated acid sites in a non-oxydizing acid medium. The catalyst is exposed to a phase of activation in a medium containing a holohydric acid or a halohydric acid precursor, in the presence of at least one preferably parafinic hydrocarbon or hydrocarbon derivative, at a temperature greater than 20° and preferably between 100° C. and 250° C., and at a pressure of between 105 and 50,106 Pa, for a length of time sufficient to ensure conversion into activated acid sites.

    摘要翻译： 本发明涉及一种活化负载的酸催化剂的方法，并且包括将沉积在固体基质上的路易斯酸型酸性位点转化成非氧化酸性介质中的活化酸性位点。 在含有全羟酸或卤代酸前体的介质中，在至少一种优选的parafinic烃或烃衍生物的存在下，在大于20℃，优选在100℃的温度下，将催化剂暴露于活化阶段。 和250℃，并且在105和50,106Pa之间的压力下，足以确保转化为活化酸性位点的时间长度。

    Isomerization catalyst with a specific pore size distribution
    3.
    发明授权
    Isomerization catalyst with a specific pore size distribution 有权
    具有特定孔径分布的异构化催化剂

    公开(公告)号：US06822130B2

    公开(公告)日：2004-11-23

    申请号：US10382671

    申请日：2003-03-06

    申请人： Pieter Jan Nat

    发明人： Pieter Jan Nat

    IPC分类号： B01J2706

    CPC分类号： B01J23/42 ,  B01J35/10 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  B01J37/24 ,  C10G45/62

    摘要： A catalyst composition comprising an alumina carrier, a Group VIII noble metal, and a halogen compound wherein the catalyst composition has total pore volume of more than 0.48 ml/g and wherein at least 50% of this total pore volume resides in pores with a diameter smaller than 12 nm. This catalyst composition has a higher activity in isomerization reactions, per gram of catalyst and per gram of Group VIII noble metal, than prior art catalyst compositions.

    摘要翻译： 一种催化剂组合物，其包含氧化铝载体，第Ⅷ族贵金属和卤素化合物，其中所述催化剂组合物的总孔体积大于0.48ml / g，并且其中所述总孔体积的至少50％位于具有直径 小于12nm。 与现有技术的催化剂组合物相比，该催化剂组合物在异构化反应中每克催化剂和每克第VIII族贵金属具有更高的活性。

    Photocatalyst and method of making
    4.
    发明授权
    Photocatalyst and method of making 失效
    光催化剂及其制备方法

    公开(公告)号：US06194346B1

    公开(公告)日：2001-02-27

    申请号：US09472832

    申请日：1999-12-28

    申请人： Hiroaki Tada ,  Koji Shimoda ,  Toshiya Ito ,  Akihiko Hattori

    发明人： Hiroaki Tada ,  Koji Shimoda ,  Toshiya Ito ,  Akihiko Hattori

    IPC分类号： B01J2706

    CPC分类号： C03C17/256 ,  B01D53/8687 ,  B01D53/885 ,  B01D2255/802 ,  B01J35/002 ,  B01J35/004 ,  C03C17/3417 ,  C03C2217/212 ,  C03C2217/241 ,  C03C2217/71 ,  C03C2218/10

    摘要： Fluorine contained within a photocatalyst layer containing titanium oxide and other metallic oxide semiconductors increases the metallic oxide's photocatalytic activity. The described photocatalyst may be in the form of either film, flake, particulate, or fiber. In addition, it can be used for coating the surface of a base material of various forms, such as sheet, film, flake, particulate, bar, or fiber. When using a base material that has an alkaline-containing glass composition, establishing a fluorine-containing layer, such as a layer of fluorine-containing silicon dioxide and other metallic oxide, between the photocatalyst film and the base material can prevent the deterioration of photocatalytic activity of the photocatalyst layer. The fluorine-containing layer functions as an alkaline barrier that controls the diffusion and migration of alkali metallic ions in the glass fibers, such as Na ions, into the photocatalyst layer. Inorganic fiber- and glass sheet-based photocatalyst bearing materials have an excellent capability to decompose rarefied harmful organic gases, and are suitable for use as interior wall and air filters in super clean enclosed spaces and conveyance spaces for semiconductor production, clean rooms for various other purposes, and office and residential buildings, and for other purposes including air cleaning, antibacterial action, anti-fouling action, and defogging of clear sheets (maintaining hydrophilicity).

    摘要翻译： 含有氧化钛和其它金属氧化物半导体的光催化剂层内的氟增加了金属氧化物的光催化活性。 所述的光催化剂可以是薄膜，薄片，颗粒或纤维的形式。 此外，它可以用于涂覆各种形式的基材的表面，例如片，薄膜，薄片，颗粒，棒或纤维。 当使用具有含碱性玻璃组合物的基材时，在光催化剂膜和基材之间建立诸如一层含氟二氧化硅和其它金属氧化物的含氟层可以防止光催化剂的劣化 光催化层的活性。 含氟层用作控制玻璃纤维（例如Na离子）中的碱金属离子在光催化剂层中的扩散和迁移的碱性屏障。 无机纤维和玻璃板基光催化剂轴承材料具有优异的分解稀有有害有机气体的能力，适用于超洁净封闭处所内壁和空气过滤器，半导体生产用输送空间，各种洁净室 用途，办公楼和住宅建筑物，以及用于其他用途，包括空气净化，抗菌作用，防污染作用和清除片材的除雾（保持亲水性）。

    Stable and selective dehydrogenation catalyst and a process for the preparation thereof
    5.
    发明授权
    Stable and selective dehydrogenation catalyst and a process for the preparation thereof 失效
    稳定和选择性脱氢催化剂及其制备方法

    公开(公告)号：US06635598B2

    公开(公告)日：2003-10-21

    申请号：US09832187

    申请日：2001-04-10

    申请人： Rajeswer Dongara ,  Krishnamurthy Konda Ramaswamy

    发明人： Rajeswer Dongara ,  Krishnamurthy Konda Ramaswamy

    IPC分类号： B01J2706

    CPC分类号： C07C5/417 ,  B01J23/8966 ,  B01J27/13 ,  C07C5/325 ,  C07C5/3337 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/14 ,  C07C2523/56 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2523/89 ,  C07C2527/06

    摘要： A novel catalyst for use in dehydrogenation of saturated hydrocarbons to unsaturated hydrocarbons and a method for its preparation is disclosed. Said catalyst comprises a composite incorporated within its spatial geometry on a percentage by weight basis, with a uniform concentration gradient, the following active elements: from 0.1 to 5.0% of a noble metal; from 0.1 to 5.0% of a metal of Group IV A; from 0.1 to 6.0% of a metal Group III A; from 0.1 to 10.0% of an alkali or alkaline earth metal element; from 0.01 to 10.0% of a halogen; and from 0.1 to 5.0% of a metal Group VIII selected from Fe, Co and Ni provided on a high surface area meso or macroporous support. The the high surface mesoporous support comprises a spheroidal gamma alumina support with a diameter of 1.4 to 2.0 mm, a surface area in the range of from 150 to 220 m2/g, with bimodal narrow pore size distribution, water adsorption capacity in the range of from 1.4 to 2.5 ml/g, gamma crystallinity in the range of 60 to 80% and a bulk density in the range of 0.25 to 0.4 g/ml.

    摘要翻译： 公开了一种用于将饱和烃脱氢成不饱和烃的新型催化剂及其制备方法。 所述催化剂包含在其空间几何形状内基于重量百分比掺入并具有均匀浓度梯度的复合材料，以下活性元素：0.1至5.0％的贵金属; 0.1至5.0％的IV族金属A ; 0.1〜6.0％的金属IIIA族; 0.1〜10.0％的碱金属或碱土金属元素; 0.01〜10.0％的卤素; 和0.1-5.0％的选自Fe，Co和Ni的金属组VIII，其设置在高表面积的中等或大孔载体上。 高表面介孔载体包括直径为1.4至2.0mm的球形γ氧化铝载体，表面积为150-220m2 / g，双峰窄孔径分布，水吸附容量范围为 从1.4至2.5ml / g，γ结晶度在60至80％范围内，堆积密度在0.25至0.4g / ml的范围内。

    Selective bifunctional multimetallic reforming catalyst
    7.
    发明授权
    Selective bifunctional multimetallic reforming catalyst 有权
    选择性双功能多金属重整催化剂

    公开(公告)号：US06495487B1

    公开(公告)日：2002-12-17

    申请号：US09435272

    申请日：1999-12-10

    申请人： Paula L. Bogdan

    发明人： Paula L. Bogdan

    IPC分类号： B01J2706

    CPC分类号： C10G35/09 ,  B01J23/626 ,  B01J23/63 ,  B01J27/13

    摘要： A novel catalyst and the use thereof in a reforming process is disclosed. The catalyst comprises a refractory inorganic oxide, platinum-group metal, Group IVA(IUPAC 14) metal, indium and lanthanide-series metal. Utilization of this catalyst in the conversion of hydrocarbons, especially in reforming, results in significantly improved selectivity to the desired gasoline or aromatics product.

    摘要翻译： 公开了一种新型催化剂及其在重整过程中的应用。 该催化剂包括耐火无机氧化物，铂族金属，IVA族（IUPAC 14）金属，铟和镧系金属。 这种催化剂在烃的转化中的应用，特别是在重整过程中，导致对所需汽油或芳烃产物的显着提高的选择性。