知搜-全球专利检索

  1. Login
  2. Sign Up

Search Results

18 records (took 0.017 seconds)

    Process for activating halogenated catalysts, catalysts obtained by this process, and use of these catalysts in acid catalyst processes
    1.
    发明授权
    Process for activating halogenated catalysts, catalysts obtained by this process, and use of these catalysts in acid catalyst processes 失效
    用于活化卤代催化剂的方法，通过该方法获得的催化剂以及这些催化剂在酸催化剂方法中的用途

    公开(公告)号：US06194345B1

    公开(公告)日：2001-02-27

    申请号：US09319595

    申请日：1999-09-10

    Applicant: Peter Mangnus ,  Alain Milan ,  Georges Szabo

    Inventor： Peter Mangnus ,  Alain Milan ,  Georges Szabo

    IPC: B01J2706

    CPC classification number: B01J29/76 ,  B01J29/7049 ,  B01J2229/26 ,  B01J2229/42

    Abstract: The invention relates to a process of activating a supported acid catalyst, and consists in the conversion of Lewis acid-type acid sites which are deposited on a solid substrate into activated acid sites in a non-oxydizing acid medium. The catalyst is exposed to a phase of activation in a medium containing a holohydric acid or a halohydric acid precursor, in the presence of at least one preferably parafinic hydrocarbon or hydrocarbon derivative, at a temperature greater than 20° and preferably between 100° C. and 250° C., and at a pressure of between 105 and 50,106 Pa, for a length of time sufficient to ensure conversion into activated acid sites.

    Abstract translation: 本发明涉及一种活化负载的酸催化剂的方法，并且包括将沉积在固体基质上的路易斯酸型酸性位点转化成非氧化酸性介质中的活化酸性位点。 在含有全羟酸或卤代酸前体的介质中，在至少一种优选的parafinic烃或烃衍生物的存在下，在大于20℃，优选在100℃的温度下，将催化剂暴露于活化阶段。 和250℃，并且在105和50,106Pa之间的压力下，足以确保转化为活化酸性位点的时间长度。

    Acid catalyst with a sulfated zirconia base and its uses
    3.
    发明授权
    Acid catalyst with a sulfated zirconia base and its uses 失效
    具有硫酸化氧化锆基质的酸催化剂及其用途

    公开(公告)号：US06180555B2

    公开(公告)日：2001-01-30

    申请号：US09168920

    申请日：1998-10-09

    Applicant: Georges Szabo ,  Pedro Nascimento ,  Alain Milan ,  Sebsastien Decker

    Inventor： Georges Szabo ,  Pedro Nascimento ,  Alain Milan ,  Sebsastien Decker

    IPC: B01J27053

    CPC classification number: B01J21/066 ,  B01J27/053 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061

    Abstract: The invention relates to an acid catalyst containing a substantial quantity of supported or mass sulfated zirconia and at least one hydrogenating transition metal. This catalyst is characterized by the fact that the sulfated zirconia is in crystallized form and that it shows a specific surface area greater than or equal to 150 m2/g, a pore volume greater than or equal to 0.20 cm3/g and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m). The invention also relates to methods of making this catalyst and to the uses of this catalyst in hydrocarbon transformation chemical reactions requiring the use of an acid type catalyst, such as for example, isomerization, alkylation, oligomerization reactions or even light hydrocarbon dehydration reactions, and also heavier hydrocarbon hydrocracking and hydroisomerization reactions.

    Abstract translation: 本发明涉及含有大量负载或大量硫酸化氧化锆和至少一种氢化过渡金属的酸催化剂。 该催化剂的特征在于硫酸化氧化锆是结晶形式，并且其表现出大于或等于150m 2 / g的比表面积，大于或等于0.20cm 3 / g的孔体积和平均孔径 大于或等于20埃（20x10-10米）。 本发明还涉及制备该催化剂的方法以及该催化剂在需要使用酸型催化剂的烃转化化学反应中的用途，例如异构化，烷基化，低聚反应或甚至轻质烃脱水反应，以及 还有较重的烃类加氢裂化和加氢异构化反应。

    Acid catalyst with a sulfated zirconia base and its uses
    4.
    发明授权
    Acid catalyst with a sulfated zirconia base and its uses 失效
    具有硫酸化氧化锆基体的酸催化剂及其用途

    公开(公告)号：US06448198B1

    公开(公告)日：2002-09-10

    申请号：US09613585

    申请日：2000-07-10

    Applicant: Georges Szabo ,  Pedro Nascimento ,  Alain Milan ,  Sebastien Decker ,  Joeri Denayer ,  Jean-Pierre Dath

    Inventor： Georges Szabo ,  Pedro Nascimento ,  Alain Milan ,  Sebastien Decker ,  Joeri Denayer ,  Jean-Pierre Dath

    IPC: B01J27053

    CPC classification number: B01J21/066 ,  B01J27/053 ,  B01J37/0009

    Abstract: The invention relates to an acid catalyst containing a substantial quantity of supported or mass sulfated zirconia and at least one hydrogenating transition metal. This catalyst is characterized by the fact that the sulfated zirconia is in crystallized form and that it shows a specific surface area greater than or equal to 135 m2/g, a pore volume greater than or equal to 0.16 cm3/g and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m). The invention also relates to methods of making this catalyst and to the uses of this catalyst in hydrocarbon transformation chemical reactions requiring the use of an acid type catalyst, such as for example, isomerization, alkylation, oligomerization reactions or even light hydrocarbon dehydration reactions, and also heavier hydrocarbon hydrocracking and hydroisomerization reactions. In a preferred embodiment of the method of the present invention, a hydrated zirconia gel is washed with a soluble polar organic solvent (other than water). In accordance with the method including this washing step, a solid acid catalyst containing pure mass sulfated zirconia in a crystallized form has a surface area greater than or equal to 150 m2/g, a pore volume greater than or equal to 0.2 cm3/g, and more preferably greater than or equal to 0.25 cm3/g, and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m) and preferably greater than or equal to 30 Angstroms (30×10−10 m).

    Abstract translation: 本发明涉及含有大量负载或大量硫酸化氧化锆和至少一种氢化过渡金属的酸催化剂。 该催化剂的特征在于硫酸化氧化锆是结晶形式，并且其表现出大于或等于135m 2 / g的比表面积，大于或等于0.16cm 3 / g的孔体积和平均孔径 大于或等于20埃（20x10-10米）。 本发明还涉及制备该催化剂的方法以及该催化剂在需要使用酸型催化剂的烃转化化学反应中的用途，例如异构化，烷基化，低聚反应或甚至轻质烃脱水反应，以及 还有较重的烃加氢裂化和加氢异构化反应。 在本发明方法的优选实施方案中，用可溶性极性有机溶剂（水除外）洗涤水合氧化锆凝胶。 根据包括该洗涤步骤的方法，含有结晶形式的纯质量硫酸化氧化锆的固体酸催化剂具有大于或等于150m 2 / g的表面积，大于或等于0.2cm 3 / g的孔体积， 更优选大于或等于0.25cm 3 / g，平均孔径大于或等于20埃（20×10 -10 m），优选大于或等于30埃（30×10 -10 m）。

    Process for the activation of halogenated catalysts and catalysts obtained by said process for utilization in hydrocarbon conversion processes
    5.
    发明授权
    Process for the activation of halogenated catalysts and catalysts obtained by said process for utilization in hydrocarbon conversion processes 失效
    活化氢化催化剂和催化剂在石油转化过程中利用的方法

    公开(公告)号：US5151400A

    公开(公告)日：1992-09-29

    申请号：US554298

    申请日：1990-07-18

    Applicant: Georges Szabo ,  Egbertus F. P. Schasfoort ,  Alain Milan

    Inventor： Georges Szabo ,  Egbertus F. P. Schasfoort ,  Alain Milan

    IPC: B01J27/06 ,  B01J27/08 ,  B01J27/125 ,  B01J27/132 ,  B01J27/135 ,  B01J37/22 ,  C07B61/00 ,  C07C5/27 ,  C07C9/00 ,  C10G35/085 ,  C10G45/10

    CPC classification number: B01J27/132 ,  B01J27/135

    Abstract: The invention relates to a process for the preparation and activation of a catalyst, comprising a stage of fabricating a support consisting at least in part of at least one refractory oxide mineral, a stage of depositing on the support at least one metal from the platinum group, and a stage intended for forming on the support at least two metal halides of the Lewis acid type. Between the deposition of the metal halides of the Lewis acid type and the utilization of the catalyst in the reactor, the catalyst is subjected to an activation stage by being maintained in an acidic and nonoxidizing or reducing medium at a temperature between 300.degree. and 475.degree. C. so that its final content of a promoter metal of the zirconium, molybdenum tungsten or titanium type ranges from 0.15 to 1 percent, based on the weight of the support.

    Abstract translation: 本发明涉及一种制备和活化催化剂的方法，包括制备至少部分至少一种难熔氧化物矿物的载体的阶段，在载体上沉积至少一种来自铂族金属的金属 ，以及用于在载体上形成路易斯酸型至少两种金属卤化物的阶段。 在路易斯酸型的金属卤化物的沉积和反应器中的催化剂的利用之间，催化剂在300〜475℃的温度下保持在酸性和非氧化还原性介质中进行活化阶段 使得其基于载体重量的锆，钼钨或钛型促进剂金属的最终含量为0.15至1％。

    Hydrocarbon isomerization catalyst, process for its preparation, and use thereof
    9.
    发明授权
    Hydrocarbon isomerization catalyst, process for its preparation, and use thereof 失效
    烃异构化催化剂，其制备方法及其用途

    公开(公告)号：US4830998A

    公开(公告)日：1989-05-16

    申请号：US74009

    申请日：1987-07-16

    Applicant: Georges Szabo ,  Francois-Xavier Cormerais

    Inventor： Georges Szabo ,  Francois-Xavier Cormerais

    IPC: B01J29/12 ,  B01J29/22 ,  C07C1/00 ,  C07C5/27 ,  C07C9/12 ,  C07C9/16 ,  C07C67/00

    CPC classification number: B01J29/22 ,  B01J29/12 ,  C07C5/2791

    Abstract: Catalysts for the isomerization of hydrocarbons, particularly normal paraffins having from 4 to 7 carbon atoms, as well as a process for the preparation of the catalyst and a process for their use in the isomerization of such hydrocarbons are disclosed.The catalysts are composed of a zeolite support impregnated with a mixture of zirconium, a refractory metallic oxide and at least one platinum-group metal.The process for the preparation of the catalysts involves steps of depositing the zirconium, on the zeolite support, mixing (zeolite+Zr) with alumina, and depositing a platinum group metal on the mixture (zeolite+Zr)/alumina, accompanied by intermediate calcining and shaping steps, and followed by drying and final calcining steps. Alternative methods for depositing the zirconium and platinum group metals on the zeolite are disclosed.

    Abstract translation: 公开了用于异构化烃，特别是具有4至7个碳原子的正构链烷烃的催化剂，以及制备催化剂的方法及其用于异构化这些烃的方法。 催化剂由浸渍有锆，难熔金属氧化物和至少一种铂族金属的混合物的沸石载体组成。 制备催化剂的方法包括将锆沉积在沸石载体上，与氧化铝混合（沸石+ Zr）和将铂族金属沉积在混合物（沸石+ Zr）/氧化铝上的步骤，伴随着中间煅烧 和成型步骤，然后进行干燥和最终煅烧步骤。 公开了在沸石上沉积锆和铂族金属的替代方法。

Patent Agency Ranking