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    Polyesteramines with improved dye affinity and process for their production
    1.
    发明授权
    Polyesteramines with improved dye affinity and process for their production 失效
    具有改善染料亲和性的聚酯胺及其生产方法

    公开(公告)号：US3980620A

    公开(公告)日：1976-09-14

    申请号：US514784

    申请日：1974-10-15

    申请人： Yves Vaginay

    发明人： Yves Vaginay

    IPC分类号： C08G63/00 ,  C08G63/12 ,  C08G63/685 ,  C08G63/78 ,  D06P3/52 ,  C08G63/20 ,  C08G63/68

    CPC分类号： D06P3/521 ,  C08G63/6854 ,  Y10S8/922

    摘要： Polyesteramines with good dye affinity for anionic dyestuffs formed by reactingA. at least an aromatic dicarboxylic acid and possibly a small amount of an aliphatic diacid,B. at least a diol having at least 3 carbon atoms such as an aliphatic, a saturated alicyclic or a cycloaliphatic diol, andC. at least a compound of the formulaNR.sub.3where R, being the same or different, is alkyl, saturated alicyclic, cycloalkyl or arylaliphatic, or where two R groups form a cycle between them.The NR.sub.3 compound has 1, 2 or 3 R groups containing 0, 1, 2 or 3 ester generating groups with the total number of ester generating groups being 1 to 3. The NR.sub.3 compound has no more than two R groups being arylaliphatic or cycloaliphatic which have only one carbon atom between the cycle and the nitrogen atom or being saturated alicyclic and there are at least 3 or more carbon atoms between the ester generating groups and the nitrogen atom.The total amount of the NR.sub.3 compound is present so that the percentage of nitrogen fixed on the polymer is at least 0.03% by weight of the polymer.Yarns made from these polyesteramines are used in a variety of textile applications.

    摘要翻译： 对于通过反应A.形成的阴离子染料具有良好的染料亲和力的聚酯胺。至少有一种芳香二羧酸，并且可能是一种小量的二磷酸酯，B.至少具有至少3个碳原子的二醇，如脂肪酸，饱和脂肪酸 环己烷二醇和C.至少是式NR 3的化合物，其中R 1相同或不同，是烷基，饱和脂环族，环烷基或芳基脂族基，或者其中两个R基在它们之间形成一个循环。

    Phosphorous acid and ester catalyzed formation of aminediol modified polyesters
    2.
    发明授权
    Phosphorous acid and ester catalyzed formation of aminediol modified polyesters 失效
    磷酸酯和酯催化形成氨基改性聚酯

    公开(公告)号：US3835099A

    公开(公告)日：1974-09-10

    申请号：US37671573

    申请日：1973-07-05

    申请人： TOYO BOSEKI

    发明人： MUNAKATA H ,  WATANABE K ,  ARIMATSU Y ,  TANAKA M

    IPC分类号： C08L67/00 ,  C08G63/00 ,  C08G63/682 ,  C08G63/685 ,  C08G63/78 ,  C09J167/00 ,  D01F6/84 ,  D06P3/52 ,  C08G17/013

    CPC分类号： C08G63/6856 ,  D06P3/521

    摘要： IN WHICH R1 AND R2 ARE EACH AS DEFINED ABOVE AND P AND Q ARE EACH ZERO OR A POSITIVE INTEGER NOT MORE THAN 10, AN IMPROVED PROCESS WHICH IS CHARACTERIZED IN THAT THE REACTION IS CARRIED OUT IN THE PRESENCE OF AT LEAST ONE OF PHOSPHOROUS ACID COMPOUNDS AND HYPOPHOSPHOROUS ACID, WHEREBY (1) THE RATE OF POLYMERIZATION IS ELEVATED, (2) THE SUBLIMATION OF THE STARTING CARBOXYLIC ACID IS PREVENTED, (3) THE MOLECULAR WEIGHT OF THE POLYESTER IS INCREASED AND (4) THE POLYESTER OBTAINED IS COLORLESS AND TRANSPARENT.

    -CH2-N(-R1)-R2

    WHEREIN R1 AND R2 ARE EACH A LOWER ALKYL GROUP OR, WHEN TAKEN TOGETHER, THEY REPRESENT A LOWER ALKYLENE GROUP, R3 IS A LOWER ALKYL GROUP OR A GROUP OF THE FORMULA:

    CH2-O)Q-H

    H-(O-CH2-CH2)P-O-CH2-C(-R3)(-CH2-N(-R1)-R2)-CH2-O-(CH2-

    IN THE PRODUCTION OF A POLYESTER IMPROVED IN DYEABILITY WITH ACID DYES BY THE REACTION BETWEEN A CARBOXYLIC ACID AND A GLYCOL OF WHICH THE WHOLE OR PART IS THE ONE REPRESENTED BY THE FORMULA:

    METHODS OF TREATING TEXTILE FIBRES
    5.
    发明申请
    METHODS OF TREATING TEXTILE FIBRES 有权
    处理纺织纤维的方法

    公开(公告)号：US20140315022A1

    公开(公告)日：2014-10-23

    申请号：US13814177

    申请日：2011-08-02

    申请人： Warrick James David Allen ,  Andrea Duffy ,  Nicholas Horrocks

    发明人： Warrick James David Allen ,  James Leonard Rolfe ,  Andrea Duffy ,  Nicholas Horrocks

    IPC分类号： D06P1/52 ,  D06M15/59

    CPC分类号： D06P1/52 ,  C09D139/02 ,  D06M15/3562 ,  D06M15/3566 ,  D06M15/59 ,  D06P1/39 ,  D06P1/41 ,  D06P1/5242 ,  D06P1/525 ,  D06P3/241 ,  D06P3/242 ,  D06P3/521 ,  D06P3/522 ,  Y10T428/2969

    摘要： According to the invention there is provided a method of treating textile fibres including the steps of: providing a polymeric precursor which includes a group of sub-formula (I) where R2 and R3 are independently selected from (CR7R8)n, or a group CR9R10, CR7R8CR9R10 or CR9R10CR7R8 where n is 0, 1 or 2, R7 and R8 are independently selected from hydrogen, halo or hydrocarbyl, and either one of R9 or R10 is hydrogen and the other is an electron withdrawing group, or R9 and R10 together form an electron withdrawing group, and R4 and R5 are independently selected from CH or CR11 where R11 is an electron withdrawing group, the dotted lines indicate the presence or absence of a bond, X1 is a group CX2X3 where the dotted line bond to which it is attached is absent and a group CX2 where the dotted line bond to which it is attached is present, Y1 is a group CY2Y3 where the dotted line bond to which it is attached is absent and a group CY2 where the dotted line bond to which it is attached is present, and X2, X3, Y2 and Y3 are independently selected from hydrogen, fluorine or other substituents, R1 is selected from hydrogen, halo, nitro, hydrocarbyl, optionally substituted or interposed with functional groups, or —R3-R5≡Y1, and R13 is C(O) or S(0)2; coating the textile fibres with the polymeric precursor; and polymerising the polymeric precursor so as to produce a polymeric coating on the textile fibres.

    摘要翻译： 根据本发明，提供了一种处理纺织纤维的方法，包括以下步骤：提供聚合物前体，其包含其中R2和R3独立地选自（CR7R8）n，或CR9R10基团的一个子式（I） ，CR 7 R 8 CR 9 R 10或CR 9 R 10 CR 7 R 8，其中n为0,1或2，R 7和R 8独立地选自氢，卤素或烃基，R 9或R 10中的任一个为氢，另一个为吸电子​​基团，或者R 9和R 10一起形成 吸电子基团，R4和R5独立地选自CH或CR11，其中R11是吸电子基团，虚线表示存在或不存在键，X1是基团的虚线键 不存在，并且存在与其连接的虚线键的基团CX2，Y1是不存在与其连接的虚线键的基团CY2Y3，并且其中虚线键合的基团CY2 附属的是 并且X 2，X 3，Y 2和Y 3独立地选自氢，氟或其它取代基，R 1选自氢，卤素，硝基，烃基，任选取代或插入有官能团，或-R 3 -R 5 = Y 1，以及 R 13为C（O）或S（O）2; 用聚合物前体涂覆纺织纤维; 并聚合聚合物前体以便在纺织纤维上产生聚合物涂层。

    Process of dyeing articles made from polyesteramines
    6.
    发明授权
    Process of dyeing articles made from polyesteramines 失效
    染色由聚酯胺制成的制品的工艺

    公开(公告)号：US4025300A

    公开(公告)日：1977-05-24

    申请号：US541774

    申请日：1975-01-17

    申请人： Yves Vaginay

    发明人： Yves Vaginay

    IPC分类号： D06P5/00 ,  D06P3/52 ,  C08G63/20

    CPC分类号： D06P3/521

    摘要： Articles made from polyesteramines such as filaments, fibers and molded products are dyed by treating the article with an alkylating agent in the form of a solution or emulsion in an amount of at least 1.5% by weight based on the weight of the article and at a temperature higher than room temperature for at least 15 minutes. The article is then dyed with a conventional anionic dye and preferably these two steps are carried out simultaneously.

    摘要翻译： 用长丝，纤维和模制产品制成的制品通过用溶液或乳液形式的烷基化剂以基于制品的重量为至少1.5重量％的量处理制品而染色，并且在 温度高于室温至少15分钟。 然后将该制品用常规的阴离子染料染色，优选这两个步骤同时进行。

    Dye-bath treatment for polymeric articles
    7.
    发明授权
    Dye-bath treatment for polymeric articles 失效
    聚合物文章的阴道治疗

    公开(公告)号：US3502422A

    公开(公告)日：1970-03-24

    申请号：US3502422D

    申请日：1966-02-17

    申请人： UNIROYAL INC

    发明人： MILLER ROBERT ,  FARBER MILTON ,  SHICHMAN DANIEL

    IPC分类号： C08L23/02 ,  C08L67/02 ,  D06P1/642 ,  D06P1/651 ,  D06P1/653 ,  D06P1/673 ,  D06P3/52 ,  D06P3/79 ,  D06P3/82 ,  D06P3/02 ,  D06P5/00

    CPC分类号： C08L23/10 ,  C08K5/09 ,  C08L23/02 ,  C08L39/00 ,  C08L39/08 ,  C08L67/02 ,  C08L2203/12 ,  C08L2205/16 ,  D06P1/6422 ,  D06P1/65125 ,  D06P1/65156 ,  D06P1/653 ,  D06P1/67316 ,  D06P3/521 ,  D06P3/791 ,  C08L2666/02 ,  C08L2666/04

    摘要： 1,175,419. Dyeing modified polyolefins and polyesters. UNIROYAL Inc. 10 Feb., 1967 [17 Feb., 1966], No. 6481/67. Heading D1B Shaped articles of a minor proportion of a thermoplastic nitrogen containing basic dye receptor polymer and a major proportion of an inherently undyeable polyolefin or polyester are dyed by immersing the article in an aqueous dyebath containing an anionic dye and an acid, the amount of acid used being sufficient to cause at least a five-fold increase in dye uptake compared to when acid is absent and sufficient to obtain at least 55 % dyebath exhaustion, the acid being i) an aliphatic carboxylic acid having at least three carbon atoms, ii) an α-halo substituted aliphatic carboxylic acid, iii) a non-oxidising inorganic acid, iv) a compound which hydrolyses to an acid in water, v) acetic acid present in amounts of at least 400% o.w.f., vi) benzene sulphonic acid and vii) phenol. Preferably the article contains 0.5 to 10% of the thermoplastic nitrogen containing basic dye receptor polymer and the latter includes polyhexamethylene adipamide, polyhexamethylene sebacamide, polypyrrolidinone, polycaprolactam, polyenantholactam and copolymers of these, polyurethanes, polymer, polyvinylcarbazole, aniline-formaldehyde resins and polymers containing 2-vinylpyridine or 2- methyl-5-vinyl pyridine units. Polyolefins and polyesters used include polyethylene, polypropylene, poly(3-methyl-butene-1), poly(4- methyl-1-pentene) and their copolymers, polyethylene terephthalate, polyethylene terephthalate isophthalate, and poly(1,4-cyclohexylene-dimethylene terephthalate). Acid compounds used include nitrons, sulphurons, hydrochloric, propionic, hexanoic, glycolic, cyclohexylacttic, chloroacetic, dichloroacetic and α-bromopropionic acids and compounds which hydrolyse to give acids are aliphatic carboxylic acid alkyl esters, benzyl chloride, allyl bromide and p-nitrochlorobenzene.

    IMAGE FORMING METHOD AND IMAGE FORMING SYSTEM
    10.
    发明公开
    IMAGE FORMING METHOD AND IMAGE FORMING SYSTEM 审中-公开

    公开(公告)号：US20240253362A1

    公开(公告)日：2024-08-01

    申请号：US18425292

    申请日：2024-01-29

    申请人： BROTHER KOGYO KABUSHIKI KAISHA

    发明人： Takefumi KAWAKAMI

    IPC分类号： B41J2/21 ,  B41J3/407 ,  C09D11/32 ,  D06P3/52 ,  D06P5/30

    CPC分类号： B41J2/2117 ,  C09D11/32 ,  D06P5/30 ,  B41J3/4078 ,  D06P3/521

    摘要： An image forming method includes: applying a pretreatment liquid, which is an aqueous solution, to a cloth material, which is an absorbent base material; after applying the pretreatment liquid, applying an aqueous ink onto the cloth material to form an image on the cloth material by an ink jet method. Applying the pretreatment liquid includes applying the pretreatment liquid such that the cloth material includes, when applying the aqueous ink, the pretreatment liquid in an amount of 20 mg/cm2 to 150 mg/cm2 per unit area of the cloth material. The aqueous ink includes a white ink containing titanium oxide particles having an average particle diameter of 20 nm to 200 nm.