Abstract:
Hot melt adhesive including a polar group-containing olefin copolymer has: number average molecular weight (Mn) between 10 to 50 kg/mol, crystallinity (Xc) content below 30%, enthalpy (ΔH) between 5 to 65 J/g, polydispersity index (PDI) from 2 to 6, melting temperature (Tm) between 40 and 120° C., and including at least 80 mol % of a constituent unit of formula (1), optionally a constituent unit of formula (2), and between 0.1 to 1 mol %, of a constituent unit of formula (3):
wherein R1 is H or CH3; R2 is a hydrocarbyl group having 0 to 10 carbon atoms; R3 is a hydrocarbyl group having 2 to 10 carbon atoms, when X is hydroxyl functionality or a hydrocarbyl group having 0 to 10 carbon atoms, when X is polar organic group containing at least one carboxylic acid functionality and 0 to 6 carbon atoms.
Abstract:
A multilayer sheet includes: a substrate layer (A) that includes 40 to 99.9% by mass of a polyphenylene ether (a1), 0 to 59.9% by mass of a polystyrene (a2), and an amino group-containing polymer (a3); and an adhesive layer (B) that includes an acid-modified polyolefin.
Abstract:
An adhesive composition contains a modified polyolefin resin. The polyolefin resin is obtained by modifying a polyolefin resin with an unsaturated carboxylic acid and a radically reactive aromatic compound. The polyolefin resin has a heat of fusion of 10 J/g or less, which is measured in conformity with JIS K7122. A modified content of the unsaturated carboxylic acid content with respect to the modified polyolefin resin is more than 0.5% by mass and less than 5% by mass. A modified content of the radically reactive aromatic compound with respect to the modified polyolefin resin is 0.1% by mass or more and less than 3% by mass.
Abstract:
The present invention provides an adhesive composition and a hot-melt adhesive that are suitably used for bonding a polyolefin resin substrate and a polar material, and that are capable of low-temperature adhesion. The adhesive composition comprises an acid-modified polypropylene (A), an unfunctionalized polypropylene (B), and a polyethylene (C), and has a melting point of 70 to 140° C.
Abstract:
Disclosed is an adhesive for packaging materials being in a form of an aqueous dispersion including an acid-modified polyolefin resin containing a (meth)acrylic acid ester component, polyvinyl alcohol and an aqueous medium, wherein the content of polyvinyl alcohol is 0.1 to 10 parts by mass in relation to 100 parts by mass of the acid-modified polyolefin resin. Also disclosed is a packaging material using the adhesive wherein a barrier layer, an adhesive layer formed of a coating film obtained from the adhesive, and a sealant layer are laminated in this order.
Abstract:
A method for bonding a fabric to a polyolefin elastomer. The method comprises applying to the fabric: (a) from 10 to 90 wt % of an aqueous dispersion of a thermoplastic polymer; and (b) from 90 to 10 wt % of an aqueous dispersion of a rosin, wherein percentages are based on total dry weight of thermoplastic polymer and rosin.
Abstract:
The present invention provides a laminated polyester film which can be suitably used for extrusion lamination with polyolefins and comprises a coating layer having an excellent adhesion property to the polyolefins, in particular, a coating layer having a remarkably excellent adhesion property to polypropylene. The laminated polyester film of the present invention comprises a polyester film and a coating layer formed on a surface of the polyester film which is formed by applying a coating composition comprising (A) a modified polyolefin having two melting points, and at least one crosslinking agent, and then drying the coating composition applied.
Abstract:
Disclosed is an aqueous polyolefin resin dispersion including a polyolefin resin and an aqueous medium, wherein the polyolefin resin includes an olefin component and an unsaturated carboxylic acid component as copolymer components; the olefin component includes propylene (A) and an olefin(s) (B) other than propylene; the mass ratio (A/B) between the propylene (A) and the olefin(s) (B) other than propylene is 60/40 to 95/5; the content of the unsaturated carboxylic acid component as the copolymer component is 1 part by mass or more in relation to 100 parts by mass of the total mass of (A) and (B); and the content of the unsaturated carboxylic acid monomer in the dry residue of the aqueous dispersion is 10,000 ppm or less.
Abstract:
The present invention provides a hot melt adhesive being highly environmentally-friendly, and as well having sufficient pressure-sensitive adhesiveness, adhesion, thermal stability and the like. The present invention relates to a hot melt adhesive comprising (A) a polar functional group-modified polymer, (B) an aliphatic polyester-based resin, (C) a tackifier resin and (D) a thermoplastic elastomer.
Abstract:
The invention relates to hot-melt adhesive compositions having at least one thermoplastic poly-a-olefin that is solid at 25° C. and that contains silane groups, at least one soft resin having a melting point or softening point between −10 and 40° C., and at least one silane that is liquid at 25° C. The hot-melt adhesive compositions are characterized by an improved open time and reduced viscosity compared to the prior art that cannot be achieved by means of other low-molecular-weight components that are normally added to reduce the viscosity, because the components escape from the adhesive formulation over time. The hot-melt adhesives according to the invention are suitable in particular as laminating adhesives and have a desirable low viscosity during the application, while good cross-linking density can be achieved by the addition of silane that is liquid at room temperature. Despite the extended open time, the hot-melt adhesive compositions quickly build up an extremely high early strength and lead to a heat-stable adhesive bond.