公开(公告)号：US11945898B2

公开(公告)日：2024-04-02

申请号：US17105846

申请日：2020-11-27

Applicant: SUSOS AG

Inventor： Angela Serrano ,  Stefan Zuercher ,  Samuele Tosatti

IPC: C08F8/32 ,  C08F8/40 ,  C08F8/44 ,  C08F22/18 ,  C08F120/22 ,  C08F120/24 ,  C08G63/00 ,  C08G63/91 ,  C08G65/00 ,  C08G65/329 ,  C08G69/00 ,  C08G69/48 ,  C08G81/02 ,  C08L71/02 ,  C09D5/16 ,  C09D133/14 ,  C09D133/16 ,  C09D133/26 ,  C09D171/02 ,  C09D201/02 ,  C08F220/60

CPC classification number: C08F8/32 ,  C08F8/40 ,  C08F8/44 ,  C08F22/18 ,  C08F120/22 ,  C08F120/24 ,  C08G63/00 ,  C08G63/91 ,  C08G65/00 ,  C08G65/329 ,  C08G69/00 ,  C08G69/48 ,  C08G81/025 ,  C08L71/02 ,  C09D5/16 ,  C09D5/1656 ,  C09D133/14 ,  C09D133/16 ,  C09D133/26 ,  C09D171/02 ,  C09D201/02 ,  C08F220/603 ,  C08F220/606 ,  C08F2438/03 ,  C08G2650/50 ,  C08F8/40 ,  C08F220/06 ,  C08F8/44 ,  C08F220/06

Abstract: A functional polymer including at least two different types of side chains, having the general formula (1),




wherein A is an at least monosubstituted alkylene or arylene group; B is an amide, ester or ether group and n is 0 or 1; F is selected from: an ester, secondary amine, amide, ether, thio ether, thio ester, and may be the same or different for the different side chains; D is a side chain intended to reversible bind to a substrate or has a coating function; E is a side chain intended to irreversible bind to a substrate, the side chain E and polymer includes 1 to 10 different side chains D and 1 to 10 different side chains E, but at least one of each, and includes a plurality of each type, whereby the different types of side chains are randomly or regularly distributed in the polymer.

公开(公告)号：US06649719B2

公开(公告)日：2003-11-18

申请号：US09931215

申请日：2001-08-16

Applicant: George G. I. Moore ,  Michael A. Yandrasits ,  Jay F. Schulz ,  Richard M. Flynn

Inventor： George G. I. Moore ,  Michael A. Yandrasits ,  Jay F. Schulz ,  Richard M. Flynn

IPC: C08F1418

CPC classification number: C09D133/16 ,  C07C69/63 ,  C08F20/24 ,  C08F120/24

Abstract: Described is a compound having at least one acrylate monomer, said monomer including at least one pendant group of the structure —O—CH(Rf)(Rf′), wherein Rf is a straight chain or branched perfluoroalkyl group with five or less carbon atoms, and Rf′ is a branched perfluoroalkyl group with three to five carbon atoms; and a method of reducing the surface tension of a liquid by adding a compound of the invention to the liquid. Also described is a composition that includes a compound of the invention in an aqueous solution or dispersion; a method of treating a substrate to render it oil- and/or water-repellent that includes treating a substrate with a composition of the invention; a method of coating an electrical device that includes applying a composition of the invention; a method of coating optical fibers that includes applying a composition of the invention; and an article that includes a substrate treated with a composition of the invention.

Abstract translation: 描述了具有至少一种丙烯酸酯单体的化合物，所述单体包括至少一个-O-CH（Rf）（Rf'）结构的侧基，其中Rf是具有五个或更少碳原子的直链或支链全氟烷基 ，Rf'为3〜5个碳原子的支链全氟烷基; 以及通过将本发明的化合物加入到液体中来降低液体的表面张力的方法。 还描述了在水溶液或分散体中包含本发明化合物的组合物; 处理基材以使其具有油和/或防水性的方法，其包括用本发明的组合物处理基材; 包括施用本发明的组合物的电气装置的涂覆方法; 涂布光纤的方法，其包括施加本发明的组合物; 以及包含用本发明的组合物处理的基材的制品。

公开(公告)号：US20170066864A1

公开(公告)日：2017-03-09

申请号：US15357413

申请日：2016-11-21

Applicant: Henkel IP & Holding GmbH

Inventor： Tianzhi Zhang ,  Matthew P. Burdzy ,  Dingsong Feng ,  Yonghui Zhang

IPC: C08F220/18 ,  C07C271/20 ,  C07C271/14 ,  C07F7/08

CPC classification number: C08F220/18 ,  C07C265/08 ,  C07C271/12 ,  C07C271/14 ,  C07C271/20 ,  C07F7/025 ,  C07F7/0836 ,  C07F7/1804 ,  C08F120/24 ,  C08F126/02 ,  C08G18/02 ,  C08G77/24 ,  C09D133/16

Abstract: Novel fluorinated compounds, their method of preparation and use are disclosed, as well as the incorporation of new and old fluorinated compounds in controlled radical polymerization processes to efficiently produce polymer compositions with unique and enhanced properties. Various cure mechanisms and types of end-uses are disclosed.

Abstract translation: 公开了新的氟化化合物及其制备和使用方法，以及将新的和旧的含氟化合物引入受控的自由基聚合方法中以有效地制备具有独特和增强的性能的聚合物组合物。 公开了各种固化机理和最终用途的类型。

公开(公告)号：US20090312517A1

公开(公告)日：2009-12-17

申请号：US12519649

申请日：2007-12-27

Applicant: Yu Yang ,  George G.I. Moore

Inventor： Yu Yang ,  George G.I. Moore

IPC: C08G63/00 ,  C08G61/00 ,  C08G75/00

CPC classification number: C08F2/38 ,  C07C17/275 ,  C07C19/14 ,  C07C19/16 ,  C07C43/126 ,  C07C69/63 ,  C07C309/82 ,  C07C311/09 ,  C08F8/10 ,  C08F8/12 ,  C08F8/14 ,  C08F120/24 ,  C08F120/36 ,  C08F220/24 ,  C08G18/2885 ,  C09D175/04 ,  D06M15/256 ,  Y10T428/3154 ,  C08F110/02

Abstract: A process comprises combining in a batchwise, semi-continuous, or continuous manner, or a combination thereof, in the presence of at least one free radical initiator, and at a temperature sufficient to cause the initiator to fragment to form free radicals, (a) at least one telogen selected from (1) fluoroalkyl halides that comprise at least one halomethylene moiety (—CHX—) and, optionally, at least one non-fluorine heteroatom, and (2) perfluoroalkyl halides that comprise at least one halofluoromethylene moiety (—CFX—) and at least one non-halogen heteroatom, the halides being selected from iodides and bromides; and (b) ethylene; the telogen and the ethylene being combined in total amounts such that the number of moles of ethylene per mole of telogen is at least about 4.

Abstract translation: 一种方法包括在分批，半连续或连续方式或其组合中，在至少一种自由基引发剂存在下，和足以引发引发剂片段形成自由基的温度下（ ）至少一个选自（1）包含至少一个卤代亚甲基部分（-CHX-）和任选的至少一个非氟杂原子的氟代烷基卤化物的起始物，和（2）包含至少一个卤氟亚甲基部分的全氟烷基卤化物 -CFX-）和至少一个非卤素杂原子，所述卤化物选自碘化物和溴化物; 和（b）乙烯; 季戊四醇和乙烯的总量相结合，使得每摩尔环糊精的乙烯摩尔数至少约为4。

公开(公告)号：US20020042470A1

公开(公告)日：2002-04-11

申请号：US09931215

申请日：2001-08-16

Inventor： George G.I. Moore ,  Michael A. Yandrasits ,  Jay F. Schulz ,  Richard M. Flynn

IPC: C08F118/00 ,  B05D005/12 ,  B05D001/02 ,  B05D001/28 ,  B05D001/18

CPC classification number: C09D133/16 ,  C07C69/63 ,  C08F20/24 ,  C08F120/24

Abstract: Described is a compound having at least one acrylate monomer, said monomer including at least one pendant group of the structure nullOnullCH(Rf)(Rfnull), wherein Rf is a straight chain or branched perfluoroalkyl group with five or less carbon atoms, and Rfnull is a branched perfluoroalkyl group with three to five carbon atoms; and a method of reducing the surface tension of a liquid by adding a compound of the invention to the liquid. Also described is a composition that includes a compound of the invention in an aqueous solution or dispersion; a method of treating a substrate to render it oil-and/or water-repellent that includes treating a substrate with a composition of the invention; a method of coating an electrical device that includes applying a composition of the invention; a method of coating optical fibers that includes applying a composition of the invention; and an article that includes a substrate treated with a composition of the invention.

Abstract translation: 描述了具有至少一种丙烯酸酯单体的化合物，所述单体包括至少一个-O-CH（Rf）（Rf'）结构的侧基，其中Rf是具有五个或更少碳原子的直链或支链全氟烷基 ，Rf'为3〜5个碳原子的支链全氟烷基; 以及通过将本发明的化合物加入到液体中来降低液体的表面张力的方法。 还描述了在水溶液或分散体中包含本发明化合物的组合物; 处理基材以使其具有油和/或拒水性的方法，其包括用本发明的组合物处理基材; 包括施用本发明的组合物的电气装置的涂覆方法; 涂布光纤的方法，其包括施加本发明的组合物; 以及包含用本发明的组合物处理的基材的制品。

公开(公告)号：US10035915B2

公开(公告)日：2018-07-31

申请号：US14515118

申请日：2014-10-15

Applicant: OFS Fitel, LLC

Inventor： Xiaoguang Sun ,  Debra A Simoff ,  Andrei A Stolov ,  Adam Hokansson ,  Natalia Reyngold

IPC: C09D4/00 ,  C09D5/00 ,  C08F220/24 ,  C08F220/22 ,  G02B1/04 ,  G02B6/02 ,  G02B1/111 ,  C08K5/5425

CPC classification number: C09D4/00 ,  C08F120/24 ,  C08F220/24 ,  C08K5/5425 ,  C09D5/00 ,  G02B1/048 ,  G02B1/111 ,  G02B6/02033 ,  C08F220/26 ,  C08F2222/1013 ,  C08F2230/085

Abstract: Disclosed herein is a composition comprising 65 to 95 weight percent of a fluorinated monofunctional monomer; 5 to 35 weight percent of a fluorinated multifunctional monomer; and 0.5 to 3 weight percent of a silane coupling agent; where all weight percents are based on the total weight of the composition; where the fluorinated monofunctional monomer and the fluorinated multifunctional monomer are devoid of any trifunctional fluorocarbon moieties when they have 6 or more fluorocarbon repeat units; where the fluorocarbon repeat units are CF2 or CF moieties; and where a crosslinked composition has a shore D hardness of 56 to 85 and has a refractive index (RI) that meets the limitation of the equation RI≤1.368+10.8/X, where X denotes wavelength in nanometers.

公开(公告)号：US20170291971A1

公开(公告)日：2017-10-12

申请号：US15510409

申请日：2014-09-11

Applicant: SUSOS AG

Inventor： Angela SERRANO ,  Stefan ZUERCHER ,  Samuele TOSATTI

IPC: C08F120/22 ,  C09D133/16 ,  C09D5/16 ,  C08F220/60 ,  C09D133/26

CPC classification number: C08F120/22 ,  C08F8/32 ,  C08F8/40 ,  C08F8/44 ,  C08F120/24 ,  C08F220/60 ,  C08F2220/603 ,  C08F2220/606 ,  C08F2438/03 ,  C08G81/025 ,  C08G2650/50 ,  C08L71/02 ,  C09D5/16 ,  C09D5/1656 ,  C09D133/14 ,  C09D133/16 ,  C09D133/26 ,  C09D171/02 ,  C09D201/02 ,  C08F220/06

Abstract: A functional polymer including at least two different types of side chains, having the general formula (1), wherein A is an at least monosubstituted alkylene or arylene group; B is an amide, ester or ether group and n is 0 or 1; F is selected from: an ester, secondary amine, amide, ether, thio ether, thio ester, and may be the same or different for the different side chains; D is a side chain intended to reversible bind to a substrate or has a coating function; E is a side chain intended to irreversible bind to a substrate, the side chain E and polymer includes 1 to 10 different side chains D and 1 to 10 different side chains E, but at least one of each, and includes a plurality of each type, whereby the different types of side chains are randomly or regularly distributed in the polymer.

公开(公告)号：US20150209447A1

公开(公告)日：2015-07-30

申请号：US14421882

申请日：2013-09-10

Applicant: University of Massachusetts

Inventor： Sankaran Thayumanavan

IPC: A61K47/48 ,  C08F20/68 ,  A61K31/485 ,  C08L33/14

CPC classification number: A61K47/6949 ,  A61K9/06 ,  A61K31/485 ,  A61K47/42 ,  C08F20/68 ,  C08F120/24 ,  C08F220/28 ,  C08F2438/03 ,  C08L33/14 ,  C08F2220/286 ,  C08F2220/1875 ,  C08F2220/385 ,  C08F2220/1825 ,  C08F2220/1841 ,  C08F2220/1858 ,  C08F220/24 ,  C08F220/54 ,  C08F220/60 ,  C08F2220/606

Abstract: The invention provides powerful methods and compositions for designing, selecting, fine-tuning and optimizing polymer nanogel and other supramolecular assemblies for various properties including, for example, particle size, density and morphology, guest loading capacity and encapsulation stability, and dynamic release control.

Abstract translation: 本发明提供了用于设计，选择，微调和优化聚合物纳米凝胶和其他超分子组合物的各种性能的强大的方法和组合物，包括例如粒度，密度和形态，客体负载能力和包封稳定性以及动态释放控制。

公开(公告)号：US08236425B2

公开(公告)日：2012-08-07

申请号：US12519573

申请日：2007-12-27

Applicant: George G. I. Moore ,  Yu Yang ,  Richard M. Flynn

Inventor： George G. I. Moore ,  Yu Yang ,  Richard M. Flynn

IPC: B32B27/00

CPC classification number: C08F2/38 ,  C07C17/275 ,  C07C19/14 ,  C07C19/16 ,  C07C43/126 ,  C07C69/63 ,  C07C309/82 ,  C07C311/09 ,  C08F8/10 ,  C08F8/12 ,  C08F8/14 ,  C08F120/24 ,  C08F120/36 ,  C08F220/24 ,  C08G18/2885 ,  C09D175/04 ,  D06M15/256 ,  Y10T428/3154 ,  C08F110/02

Abstract: A composition comprises a distribution of telomers of ethylene and at least one fluoroalkyl or perfluoroalkyl halide, the telomers comprising at least one polymethylene segment (—(CH2)n—) and at least one halomethyl group (—CXH2) and optionally comprising at least one non-fluorine heteroatom, and the halogen being selected from iodine and bromine; wherein the distribution has a number average ratio of methylene moieties of the polymethylene segment to the halomethyl groups of at least about 15.

Abstract translation: 组合物包含乙烯和至少一种氟代烷基或全氟烷基卤化物的调聚物的分布，所述调聚物包含至少一个多亚亚乙基链段（ - （CH 2）n - ）和至少一个卤代甲基（-CXH 2），并且任选地包含至少一个 非氟杂原子，卤素选自碘和溴; 其中所述分布具有至少约15的多亚甲基部分的亚甲基部分与卤代甲基的数均比例。

公开(公告)号：US07638575B2

公开(公告)日：2009-12-29

申请号：US10594011

申请日：2005-03-25

Applicant: Ikuo Yamamoto ,  Yutaka Ohira ,  Yoshio Funakoshi ,  Shinichi Minami

Inventor： Ikuo Yamamoto ,  Yutaka Ohira ,  Yoshio Funakoshi ,  Shinichi Minami

IPC: C08L27/12

CPC classification number: C08F214/18 ,  C07C323/12 ,  C08F120/24 ,  C08F120/38 ,  C08F220/24 ,  C08F220/38 ,  C09D5/1668 ,  C09D133/16 ,  C09K3/18 ,  D06M15/277 ,  D06M15/295 ,  D06M2200/10 ,  D06M2200/11 ,  D06M2200/12 ,  D21H17/11 ,  D21H21/16 ,  Y10T442/2287

Abstract: Disclosed is a surface treating agent containing fluorine-containing polymer having: (A) a repeating unit derived from a fluorine-containing compound which is represented by the following formula: CH2═C(—X)—C(═O)—Y—[—(CH2)m-Z-]p—(CH2)n-Rf  (I) (wherein X is a hydrogen atom or a methyl group), (B) a repeating unit derived from a monomer containing no fluorine atom, if necessary and (C) a repeating unit derived from a crosslinkable monomer, if necessary. This surface treating agent has excellent water repellency, oil repellency and antifouling property.

Abstract translation: 公开了含有含氟聚合物的表面处理剂，其具有：（A）由下式表示的含氟化合物的重复单元：CH2-C（-X）-C（-O）-Y- [ - （CH 2）m Z-] p-（CH 2）n -R f（I）（其中X为氢原子或甲基），（B）衍生自不含氟原子的单体的重复单元，如果需要， （C）衍生自交联性单体的重复单元。 该表面处理剂具有优异的防水性，防油性和防污性。