Metal-catalysed carbonylation of unsaturated compounds
    2.
    发明授权
    Metal-catalysed carbonylation of unsaturated compounds 有权
    不饱和化合物的金属催化羰基化

    公开(公告)号:US08686183B2

    公开(公告)日:2014-04-01

    申请号:US13394946

    申请日:2010-09-10

    摘要: The invention provides a method for the hydroxycarbonylation, alkoxycarbonylation, aryloxycarbonylation or thiocarbonylation of an unsaturated molecule. The method includes a hydroxycarbonylation, alkoxycarbonylation, aryloxycarbonylationor thiocarbonylation reaction on the unsaturated molecule in which a complex including a ligand comprising a [n,n′] cyclophane comprising two non-fused monocyclic aromatic rings bridged by two linear and aliphatic linkages, in which each of the non-fused monocyclic aromatic rings is substituted with a phosphorus atom-containing substituent, is used to catalyse the reaction.

    摘要翻译: 本发明提供了不饱和分子的羟基羰基化,烷氧基羰基化,芳氧基羰基化或硫代羰基化的方法。 该方法包括在不饱和分子上的羟基羰基化,烷氧基羰基化,芳氧基羰基化羰基化,硫代羰基化反应,其中包括包含由两个线性和脂族键连接的两个非稠合单环芳环的[n,n']环烷的配体的络合物, 的非稠合单环芳环被含磷原子的取代基取代,用于催化反应。

    Polymer additive compositions comprising highly versatile thermoplastic nucleators

    公开(公告)号:US07094820B2

    公开(公告)日:2006-08-22

    申请号:US10288040

    申请日:2002-11-05

    IPC分类号: C08K5/09

    摘要: Bicyclic nucleator compounds that provide highly versatile nucleation benefits for different polyolefins are provided. Such nucleator compounds provide very high peak crystallization temperatures and significantly reduced crystallization cycle time for certain thermoplastic formulations with or without the presence of other calcium stearate and/or peroxide components within the same type of formulation. Furthermore, such inventive nucleator compounds exhibits very little if any fugitivity from such thermoplastic formulations thereby providing excellent processing characteristics as well as excellent nucleation capabilities for a variety of different thermoplastic resins, independent of the presence of different, potentially necessary, additives (such as calcium stearate). Thermoplastic compositions as well as thermoplastic additive packages comprising such inventive nucleator compounds are also contemplated within this invention.

    Polymer additive compositions comprising highly versatile thermoplastic nucleators
    6.
    发明申请
    Polymer additive compositions comprising highly versatile thermoplastic nucleators 有权
    包含高通用热塑性成核剂的聚合物添加剂组合物

    公开(公告)号:US20030096895A1

    公开(公告)日:2003-05-22

    申请号:US10288040

    申请日:2002-11-05

    摘要: Bicyclic nucleator compounds that provide highly versatile nucleation benefits for different polyolefins are provided. Such nucleator compounds provide very high peak crystallization temperatures and significantly reduced crystallization cycle time for certain thermoplastic formulations with or without the presence of other calcium stearate and/or peroxide components within the same type of formulation. Furthermore, such inventive nucleator compounds exhibits very little if any fugitivity from such thermoplastic formulations thereby providing excellent processing characteristics as well as excellent nucleation capabilities for a variety of different thermoplastic resins, independent of the presence of different, potentially necessary, additives (such as calcium stearate). Thermoplastic compositions as well as thermoplastic additive packages comprising such inventive nucleator compounds are also contemplated within this invention.

    摘要翻译: 提供了为不同聚烯烃提供高通用成核优点的双环成核剂化合物。 这种成核剂化合物提供非常高的峰值结晶温度,并且在相同类型制剂中有或没有其它硬脂酸钙和/或过氧化物组分存在的情况下,某些热塑性制剂的结晶循环时间显着降低。 此外,这种本发明的成核剂化合物显示出非常少的任何来自这种热塑性制剂的飞行性,从而为各种不同的热塑性树脂提供优异的加工特性以及优异的成核能力,而与不同的潜在必需的添加剂(例如钙 硬脂酸酯)。 包含本发明的成核剂化合物的热塑性组合物以及热塑性添加剂包装也在本发明范围内。

    Highly versatile thermoplastic nucleators
    7.
    发明授权
    Highly versatile thermoplastic nucleators 有权
    高度通用的热塑性成核剂

    公开(公告)号:US06559211B2

    公开(公告)日:2003-05-06

    申请号:US09864460

    申请日:2001-05-23

    IPC分类号: C08K509

    摘要: Bicyclic nucleator compounds that provide highly versatile nucleation benefits for different polyolefins are provided. Such nucleator compounds provide very high peak crystallization temperatures and significantly reduced crystallization cycle time for certain thermoplastic formulations with or without the presence of other calcium stearate and/or peroxide components within the same type of formulation. Furthermore, such inventive nucleator compounds exhibits very little if any fugitivity from such thermoplastic formulations thereby providing excellent processing characteristics as well as excellent nucleation capabilities for a variety of different thermoplastic resins, independent of the presence of different, potentially necessary, additives (such as calcium stearate). Thermoplastic compositions as well as thermoplastic additive packages comprising such inventive nucleator compounds are also contemplated within this invention.

    摘要翻译: 提供了为不同聚烯烃提供高通用成核优点的双环成核剂化合物。 这种成核剂化合物提供非常高的峰值结晶温度,并且在相同类型制剂中有或没有其它硬脂酸钙和/或过氧化物组分存在的情况下,某些热塑性制剂的结晶循环时间显着降低。 此外,这种本发明的成核剂化合物显示出非常少的任何来自这种热塑性制剂的飞行性,从而为各种不同的热塑性树脂提供优异的加工特性以及优异的成核能力,而与不同的潜在必需的添加剂(例如钙 硬脂酸酯)。 包含本发明的成核剂化合物的热塑性组合物以及热塑性添加剂包装也在本发明范围内。

    Monomers for photoresist, polymers thereof, and photoresist compositions using the same

    公开(公告)号:US06291131B1

    公开(公告)日:2001-09-18

    申请号:US09383547

    申请日:1999-08-26

    IPC分类号: G03F7004

    摘要: The present invention relates to novel monomers for preparing photoresist polymers, polymers thereof, and photoresist compositions using the same. The monomers of the iinvention are represented by the following Chemical Formula 1: wherein, X and Y individually represent oxygen, sulfur, CH2 or CH2CH2; n is an integer of 1 to 5; and R1, R2, R3 and R4 individually represent hydrogen, C1-C10 alkyl having substituent(s) on its main or branched chain, C1-C10 ester having substituent(s) on its main or branched chain, C1-C10 ketone having substituent(s) on its main or branched chain, C1-C10 carboxylic acid having substituent(s) on its main or branched chain, C1-C10 acetal having substituent(s) on its main or branched chain, C1-C10 alkyl having substituent(s) including one or more hydroxyl group(s) on its main or branched chain, C1-C10 ester having substituent(s) including one or more hydroxyl group(s ) on its main or branched chain, C1-C10 ketone having substituent(s) including one or more hydroxyl group(s) on its main or branched chain, C1-C10 carboxylic acid having substituent(s) including one or more hydroxyl group(s) on its main or branched chain, or C1-C10 acetal having substituent(s) including one or more hydroxyl group(s) on its main or branched chain; provided that at least one of R1 to R4 represent(s) —COO—R′—OH wherein R′ is a linear or branched chain alkyl group with or without substituent(s) on its linear or branched chain. Polymers according to the present invention preferably comprise (i) a monomer of Chemical Formula 1 above as the first comonomer, (ii) a polyalicyclic derivative having one or more acid labile protective group(s) as the second comonomer, and (iii) at least one polymerization-enhancing monomer, preferably selected from the group consisting of maleic anhydride, maleimide derivatives, and combinations thereof. In order to increase photosensitivity, it is also preferable for the photoresist copolymer to comprise (iv) a polyalicyclic derivative having one or more carboxylic acid groups, as an additional comonomer.