摘要:
The invention relates to an activated alkaline earth metal, to a method for its production and the use of the activated alkaline earth metal for the preparation of Grignard compounds and organoalkaline earth metal compounds.
摘要:
The present disclosure relates to a process for the production of a base complex catalyst comprising reacting a hydroxide base with a polyalcohol, under vacuum pressure, at a temperature in the range of about 60° C. to about 220° C., wherein the mole ratio of the hydroxide base to the polyalcohol is greater than about 2:1.
摘要:
This invention relates to a process for preparing magnesium alkoxide granulates. The process includes the steps of reacting magnesium metal with at least one compound of formula AlR3-nHaln and an alcohol in a non-coordinating solvent. R is an alkyl or aryl radical, Hal is a halogen radical and n is in the range of between 0 and 2.
摘要:
A magnesium compound represented by the formula (I): Mg(OC2H5)2−n(OR1)n (I) where R1 is CmH2m+1 (where m is an integer of from 3 to 10), and n is a numerical value satisfying 0
摘要:
A magnesium compound obtained by reacting metallic magnesium having a sphericity (S) of less than 4.00, the sphericity (S) being represented by the following formula (I), an alcohol, and a halogen and/or a halogen-containing compound containing halogen atoms in an amount of 0.0001 gram atom or more relative to one gram atom of the metallic magnesium, S=(L1/L2)3 (I) wherein L1 represents the maximum diameter of projection views of metallic magnesium determined by photographing with a scanning electron microscope and thereafter an image processing, and L2 represents a diameter of a circle having an area equal to the area of the projection view of metallic magnesium. A solid catalyst component is obtained from the magnesium compound and a titanium compound, and a catalyst for olefin polymerization is obtained using the solid catalyst component.
摘要:
The present invention relates to a process for preparing a metal-free, alkoxide-pure alkaline-earth alkoxide of the general formula I M(OR1)2 (I) in which M stands for an element pertaining to the second Main Group of the Periodic Table of the Elements and R1 represents a linear, branched or cyclic alkyl group with 2 to 20 C atoms, by alcoholysis of a compound of the general formula II M(OR2)x(OR3)y(OR4)z (II) in which M stands for an element pertaining to the second Main Group of the Periodic Table of the Elements, groups R2, R3 and R4 are the same or different and represent a linear alkyl group with 1 to 4 C atoms, with the proviso 0≦x≦2, 0≦y≦2, 0≦z≦2 with (x+y+z)=2, with an alcohol, which is employed in excess, of the general formula III HOR1 (III) in which R1 has the same significance as in formula I, is different from groups R2, R3 and R4 according to formula II, and in the alkyl chain possesses at least one C atom more than the longest alkyl group from the series R2, R3 and R4, the compounds of the formula I and/or of the formula II being kept dissolved, at least in a proportion, during the conversion.
摘要:
A method for treating a terminal dihalo hydrocarbyl compound with an alkali metal indenide to produce a bis(indenyl) hydrocarbyl compound is described.