摘要:
A crystalline, completely soluble lithium bis(oxalato)borate (LiBOB), to a method for producing the same and to the use of the lithium bis(oxalato)borate.
摘要:
Methods are described for the production of hydrogen-bis(chelato)borates of the general formula H[BL1L2] and of alkali metal-bis(chelato)borates of the general formula M[BL1L2] where M=Li, Na, K, Rb, Cs L1=—OC(O)—(CR1R2)n—C(O)O— or —OC(O)—(CR3R4)—O— where n=0 or 1, R1, R2, R3, R4 independently of one another denote H, alkyl, aryl or silyl, L2=—OC(O)—(CR5R6)n—C(O)O— or —OC(O)—(CR7R8)—O— where n=0 or 1, R5, R6, R7, R8 independently of one another denote H, alkyl, aryl or silyl, wherein the respective raw materials are mixed in solid form without the addition of solvents and are reacted. Lithium-bis(oxalato)borate, lithium-bis(malonato)borate, caesium-bis-(oxalato)borate, caesium-bis-(malonato)borate and the mixed salts lithium(lactato,oxalato)borate and lithium(glycolato,oxalato)borate for example may be produced in this way.
摘要:
Boron chelate complexes of the general formula are described, where X is either —C(R1R2)— or —C(R1R2)—C(═O)—, in which R1, R2 independently of one another denote H, alkyl (with 1 to 5 C atoms), aryl, silyl or a polymer, and one of the alkyl radicals R1 or R2 may be bonded to a further chelatoborate radical, or X denotes 1,2-aryl with up to two substituents S in the positions 3 to 6 in which S1, S2 independently of one another denote alkyl (with 1 to 5 C atoms), fluorine or a polymer, as well as M+ denotes Li+, Na+, K+, Rb+, Cs+ or [(R3R4R5R6)N]+ or H+, where R3, R4, R5, R6 independently of one another denote H or alkyl with preferably 1 to 4 C atoms.
摘要:
The invention relates to a solution of lithium aluminum hydride in 2-methyltetrahydrofuran or a solvent mixture containing 2-methyltetrahydrofuran, a method for producing said solution and use of the same.
摘要:
The invention relates to a solution of lithium aluminum hydride in 2-methyltetrahydrofuran or a solvent mixture containing 2-methyltetrahydrofuran, a method for producing said solution and use of the same.
摘要:
Methods are described for the production of hydrogen-bis(chelato)borates of the general formula H[BL1L2] and of alkali metal-bis(chelato)borates of the general formula M [BL1L2] where M=Li, Na, K, Rb, Cs L1=—OC(O)—(CR1R2)n—C(O)O— or —OC(O)—(CR3R4)—O—where n=0 or 1, R1, R2, R3, R4 independently of one another denote H, alkyl, aryl or silyl, L2=—OC(O)—(CR5R6)n—C(O)O— or —OC(O)—(CR7R8)—O—where n=0 or 1, R5, R6, R7, R8 independently of one another denote H, alkyl, aryl or silyl, wherein the respective raw materials are mixed in solid form without the addition of solvents and are reacted. Lithium-bis (oxalato) borate, lithium-bis (malonato)borate, caesium-bis-(oxalato)borate, caesium-bis-(malonato)borate and the mixed salts lithium (lactato, oxalato) borate and lithium(glycolato,oxalato)borate for example may be produced in this way.
摘要:
The invention relates to a method for producing alkali metal alcoholates by reacting alcohol with alkali metal in an aprotic, organic solvent in the presence of an H acceptor such as e.g. isoprene, butadiene, styrene or methyl styrene.
摘要:
The method of making the stable non-pyrophoric solution containing a lithium diorganoamide of the formula, LiNR'R" wherein R' and R" each have from 2 to 6 carbon atoms, in an inert liquid hydrocarbon solvent includes mixing a secondary amine including the R' and R" groups and an alcohol having 3 to 6 carbon atoms with a lithium granulate or powder in the hydrocarbon solvent and reacting the secondary amine, the alcohol and the lithium with addition of an electron acceptor compound, advantageously styrene or isobutene, to form the stable non-pyrophoric solution containing the lithium diorganoamide and a lithium alkoxide having 3 to 6 carbon atoms.