公开(公告)号：US20180362673A1

公开(公告)日：2018-12-20

申请号：US16063042

申请日：2016-12-16

申请人： Japan Polypropylene Corporation

发明人： Keiji FUKUDA ,  Shouichi IDA ,  Akio TANNA ,  Shigeo MIZUKAMI

IPC分类号： C08F4/659 ,  C08F4/609 ,  C08F4/649 ,  C08F110/06

CPC分类号： C08F4/65912 ,  C08F4/6093 ,  C08F4/6498 ,  C08F4/658 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/06 ,  C08F4/6492 ,  C08F4/6586 ,  C08F4/6567 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/651 ,  C08F4/6548

摘要： A method for producing a solid catalyst component (Aa) for α-olefin polymerization, which includes: bringing components (A1) to (A4) into contact with one another in an inert solvent; and without washing the contact product with an inert solvent, aging the contact product by keeping for a holding time of 3 days or more and 180 days or less, regarding the time point that all of the components (A1) to (A4) first come into contact, as a starting point.

公开(公告)号：US20180105621A1

公开(公告)日：2018-04-19

申请号：US15564750

申请日：2016-04-07

申请人： RELIANCE INDUSTRIES LIMITED

发明人： Virendrakumar GUPTA ,  Bhavesh Kiritbhai DESAI ,  Ajay Vinodlal KOTHARI

IPC分类号： C08F110/02

CPC分类号： C08F110/02 ,  C07F7/28 ,  C08F10/02 ,  C08F2500/24 ,  C08F2500/12 ,  C08F4/6548

摘要： The present disclosure relates to a process for controlling particle size distribution of a Ziegler-Natta catalyst composition. In order to control the particle size distribution, magnesium metal is reacted with a mixture comprising a first alcohol and a second alcohol to obtain a slurry which includes a mixture of magnesium alkoxides and unreacted alcohol. The unreacted alcohol is separated from the slurry to obtain the mixture of magnesium alkoxides having reduced methoxy content less than 2 wt %. The mixture of magnesium alkoxides is chlorinated to obtain a Ziegler-Natta pro-catalyst. The Ziegler-Natta pro-catalyst is mixed with a co-catalyst to obtain a Ziegler-Natta catalyst composition with controlled particle size distribution in the range of 5 μm to 15 μm.

公开(公告)号：US09790291B2

公开(公告)日：2017-10-17

申请号：US13827509

申请日：2013-03-14

申请人： Formosa Plastics Corporation, USA

发明人： Demin Xu ,  Lei Zhang

IPC分类号： C08F4/52 ,  C08F4/654

CPC分类号： C08F4/52 ,  C08F4/6546 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6548 ,  C08F4/651

摘要： Non-phthalate compounds having a structure represented by the general formula and a method for using same are provided as electron donors in the Ziegler-Natta type catalyst system for the homopolymerization or copolymerization of alpha olefins. The non-phthalate compounds may be used in the preparation of the solid catalyst component, thus serving as “internal electron donors”, or employed during or prior to polymerization as “external electron donors,” and therefore they can be used to prepare phthalate-free polyolefins.

公开(公告)号：US09751965B2

公开(公告)日：2017-09-05

申请号：US14067289

申请日：2013-10-30

申请人： CHINA PETROLEUM & CHEMICAL CORPORATION ,  BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION

发明人： Luqiang Yu ,  Zhichao Yang ,  Jiangbo Chen ,  Jianxin Zhang ,  Yafeng Du ,  Qinyu Tong ,  Kang Sun ,  Yang Liu ,  Jie Zou ,  Lusheng Wang ,  Zengyue Dai ,  Zhong Tan

IPC分类号： C08F210/06

CPC分类号： C08F210/06 ,  C08F10/06 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/21 ,  C08F210/16 ,  C08F10/02 ,  C08F2/001 ,  C08F2/34 ,  C08F4/6548 ,  C08F4/6565

摘要： Disclosed herein is a polymerization method of propylene, which can prepare a propylene homopolymer with both high fluidity and high rigidity as well as a propylene/α-define copolymer having both high fluidity and a good rigidity-toughness balance by, for example, control of polymerization steps and elevation of polymerization temperature, while the catalyst still maintains a relatively high polymerization activity.

公开(公告)号：US20170088642A1

公开(公告)日：2017-03-30

申请号：US15376687

申请日：2016-12-13

申请人： Beijing Lihe Technology Ltd.

发明人： Zhiwu WANG ,  Shuhang LI ,  Huashu LI ,  Junwei ZHANG ,  Hui ZHANG ,  Yena CHEN ,  Jinsong DAI ,  Qingli Ma ,  Jingyu WANG ,  Shubin LI ,  Hao CHEN ,  Fengyao LEI ,  Wei BAI ,  Lige LI ,  Yong GAO

IPC分类号： C08F10/06 ,  C07C69/753 ,  C08F10/02

CPC分类号： C08F10/06 ,  C07C69/753 ,  C08F10/00 ,  C08F10/02 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6492 ,  C08F4/6548 ,  C08F4/6465 ,  C08F2500/15 ,  C08F2500/18

摘要： A catalyst component for olefin polymerization, comprising Mg, Ti, a halogen and an electron donor, wherein the electron donor is at least one unsaturated ring-substituted diacid ester compound. Also provided is a catalyst containing the catalyst component and the use of the catalyst in an olefin polymerization, e.g., propylene polymerization.

公开(公告)号：US20160376384A1

公开(公告)日：2016-12-29

申请号：US15185019

申请日：2016-06-17

申请人： Indian Oil Corporation Limited

发明人： Gurmeet SINGH ,  Naresh KUMAR ,  Sukhdeep KAUR ,  Bhasker BANTU ,  Gurpreet Singh KAPUR ,  SHASHIKANT

IPC分类号： C08F110/02

CPC分类号： C08F110/02 ,  C08F4/654 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/6548

摘要： The present invention describes a process of preparing a catalyst for olefin polymerization comprising: (i) treating a magnesium metal with an organohalide along with an internal donor to obtain a reaction mixture having solid component (A); (ii) treating the reaction mixture having solid component (A) with an acyl halide to obtain a reaction mixture having solid component (B); and (iii) treating the reaction mixture having solid component (B) of step (ii) with a transition metal compound to obtain the catalyst. The present invention also relates to a process for preparation of a catalyst system from said catalyst and preparation of a polyolefins from the catalyst system.

摘要翻译： 本发明描述了一种制备烯烃聚合催化剂的方法，包括：（i）用内部供体处理有机卤化物的镁金属，得到具有固体组分（A）的反应混合物; （ⅱ）用酰卤处理具有固体组分（A）的反应混合物，得到具有固体组分（B）的反应混合物; 和（iii）用过渡金属化合物处理具有步骤（ii）的固体组分（B）的反应混合物以获得催化剂。 本发明还涉及从所述催化剂制备催化剂体系的方法以及从催化剂体系制备聚烯烃。

公开(公告)号：US20150274857A1

公开(公告)日：2015-10-01

申请号：US14416611

申请日：2013-09-24

申请人： INDIAN OIL CORPORATION LIMITED

发明人： Gurmeet Singh ,  Bhasker Bantu ,  Sukhdeep Kaur ,  Naresh Kumar ,  Gurpreet Singh Kapur ,  Shashi Kant ,  Biswajit Basu ,  Ravinder Kumar Malhotra

IPC分类号： C08F110/06 ,  C07F3/02

CPC分类号： C08F110/06 ,  C07F3/02 ,  C07F7/003 ,  C08F4/6548 ,  C08F2500/12 ,  C08F4/6465 ,  C08F4/6545

摘要： The present invention provides a liquid organomagnesium precursor having formula {Mg(OR′)X}.a{MgX2}.b{Mg(OR′)2}.c{R′OH}, wherein R′ is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.1-99.8:0.1-99.8:0.1-99.8, and a process for preparing the same. The said process comprises contacting a magnesium source with an organohalide and alcohol in a solvent to form the liquid organomagnesium precursor. The present invention also provides a catalyst system using the organomagnesium precursor and its use thereof for polymerization of olefins. An illustrative example of the claimed process to make the organomagnesium precursor is: At 25° C., magnesium (powder or turnings) is added to organohalide, followed by alcohol in toluene. After heating to 90° C. and keeping there for 6 h the solution became viscous.

摘要翻译： 本发明提供具有式{Mg（OR'）X} .a {MgX 2} .b {Mg（OR'）2} .c {R'OH}的液体有机镁前体，其中R'选自烃基 X选自卤化物基团，a：b：c在0.1-99.8:0.1〜99.8:0.1〜0.1.8的范围内，及其制备方法。 所述方法包括使镁源与有机卤化物和醇在溶剂中接触以形成液体有机镁前体。 本发明还提供了使用有机镁前体的催化剂体系及其在烯烃聚合中的应用。 所要求的制造有机镁前体的方法的说明性实例是：在25℃下，向有机卤化物中加入镁（粉末或屑），然后在甲苯中加入醇。 加热至90℃并保持6小时后，溶液变粘。

公开(公告)号：US09062135B2

公开(公告)日：2015-06-23

申请号：US14016537

申请日：2013-09-03

申请人： SAMSUNG TOTAL PETROCHEMICALS CO., LTD.

发明人： Sang Yull Kim ,  Joon Ryeo Park ,  Eun Il Kim ,  Jin Woo Lee

IPC分类号： C08F110/06 ,  C08F4/64

CPC分类号： C08F110/06 ,  Y02P20/52 ,  C08F2500/12 ,  C08F2500/03 ,  C08F4/6548 ,  C08F4/651

摘要： Disclosed is a method for preparing a solid catalyst for propylene polymerization, specifically to a method for preparing a solid catalyst for propylene polymerization which can produce a polypropylene having high melt flow rate, a wide molecular distribution and excellent stereoregularity with a high production yield.

摘要翻译： 公开了一种制备用于丙烯聚合的固体催化剂的方法，具体涉及制备用于丙烯聚合的固体催化剂的方法，该方法可以制备具有高熔体流动速率，宽分子量分布和优异的立构规整性并具有高生产率的聚丙烯。

公开(公告)号：US20150126694A1

公开(公告)日：2015-05-07

申请号：US14596536

申请日：2015-01-14

申请人： RELIANCE INDUSTRIES LIMITED

发明人： Virendrakumar GUPTA ,  Saurabh SINGH ,  Jomichan JOSEPH ,  Kamlesh J. SINGALA ,  Bhavesh K. DESAI

IPC分类号： C08F4/52 ,  C08F4/16

CPC分类号： C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6548 ,  C08F2500/12 ,  C08F2500/24 ,  C08F4/6494

摘要： The present invention relates to regular shaped magnesium particles containing attrition resistant precursors and procatalysts thereof and processes for their synthesis and their use in the manufacture of polyolefins. More particularly, the present invention relates to a process for the synthesis of a said precursor particles which give highly active and improved surface area procatalysts for producing high bulk density polyolefin resins containing low fines and capable of incorporating high rubber content. In particular, the present invention relates to process for the synthesis of an attrition resistant precursors to prepare an attrition resistant Zeigler Natta procatalysts synthesized by using the precursors and to the polyolefin resin synthesized using the said procatalysts.

摘要翻译： 本发明涉及含有抗磨损前体及其前催化剂的规则形状的镁颗粒及其合成方法及其在制备聚烯烃中的用途。 更具体地说，本发明涉及一种合成所述前体颗粒的方法，该方法得到高活性和改进的表面积原催化剂，用于生产含低分子且能掺入高橡胶含量的高体积密度聚烯烃树脂。 特别地，本发明涉及合成耐磨前体以制备通过使用前体合成的耐磨Zeigler Natta前催化剂和使用所述前催化剂合成的聚烯烃树脂的方法。

公开(公告)号：US08916649B2

公开(公告)日：2014-12-23

申请号：US13462869

申请日：2012-05-03

申请人： Patrick J. C. Schouterden ,  Ruddy A. J. Nicasy ,  Sarat Munjal ,  Robert J. Jorgesen ,  Burkhard E. Wagner

发明人： Patrick J. C. Schouterden ,  Ruddy A. J. Nicasy ,  Sarat Munjal ,  Robert J. Jorgesen ,  Burkhard E. Wagner

IPC分类号： C08F10/02 ,  C08F210/16 ,  C08L23/04 ,  C08L23/06 ,  C08F10/00 ,  C08F110/02

CPC分类号： C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/908 ,  C08F4/651 ,  C08F4/025 ,  C08F4/6548 ,  C08F4/6555 ,  C08F2/14 ,  C08F2/001 ,  C08F2500/12 ,  C08F2500/07 ,  C08F2500/24 ,  C08F210/08

摘要： The present invention relates to a process of producing an ethylene polymer composition in multiple stages, of which the first stage is preferably a slurry polymerization stage, in the presence of a catalyst system, comprising: a) a solid catalyst precursor, comprising a transition metal selected from titanium and vanadium; magnesium; a halide, optionally an electron donor; and a solid particulate material comprising an inorganic oxide, and wherein the median particle diameter, D50, of the solid catalyst precursor, based upon the total volume of solid catalyst precursor, is from 1 to 13 micrometers; and b) an organoaluminium compound.

摘要翻译： 本发明涉及多阶段制备乙烯聚合物组合物的方法，其中第一阶段优选为淤浆聚合阶段，在催化剂体系的存在下，包括：a）固体催化剂前体，其包含过渡金属 选自钛和钒; 镁; 卤化物，任选的电子给体; 和包含无机氧化物的固体颗粒材料，并且其中固体催化剂前体的中值粒径D 50（基于固体催化剂前体的总体积）为1至13微米; 和b）有机铝化合物。