公开(公告)号：US20240279144A1

公开(公告)日：2024-08-22

申请号：US18436505

申请日：2024-02-08

Applicant: LyondellBasell Acetyls, LLC

Inventor： Noel C. Hallinan ,  David L. Ramage ,  Daniel F. White

IPC: C07C29/44 ,  C07C29/94

CPC classification number: C07C29/44 ,  C07C29/94

Abstract: A process for producing and recovering acetic acid in an acetic acid production system is disclosed, the process comprising contacting methanol and carbon monoxide in the presence of a liquid reaction medium comprising iodide under carbonylation conditions sufficient to form acetic acid. The liquid reaction medium comprises a carbonylation catalyst, water, and an additive comprising a bidentate phosphine dioxide, a tertiary arsine oxide, or a combination thereof. An aspect of the process includes a method for reducing water in an acetic acid production process.

公开(公告)号：US20240190798A1

公开(公告)日：2024-06-13

申请号：US18469170

申请日：2023-09-18

Applicant: Genomatica, Inc.

Inventor： Julia Khandurina ,  Rachel Diane Pacheco ,  Lauri Hannunpoika Suominen ,  Rainer Wagester

IPC: C07C29/80 ,  B01D3/14 ,  B01D15/36 ,  C07C29/94 ,  C07C31/20

CPC classification number: C07C29/80 ,  B01D3/143 ,  B01D15/361 ,  C07C29/94 ,  B01D2202/20 ,  C07C31/207

Abstract: Provided herein are bioderived 1,3-butanediol compositions and systems and processes for producing such bioderived 1,3-butanediol compositions.

公开(公告)号：US20230339830A1

公开(公告)日：2023-10-26

申请号：US18194814

申请日：2023-04-03

Applicant: University of Kansas

Inventor： Bala Subramaniam ,  Hongda Zhu ,  Timothy A. Jackson

IPC: C07C29/50 ,  C07C29/94

CPC classification number: C07C29/50 ,  C07C29/94

Abstract: A process for oxidizing an alkyl substrate may comprise combining an alkyl substrate (e.g., propane, n-butane) and ozone in a liquid phase medium comprising a branched alkane activator (e.g., isobutane) and a protic additive (e.g., water) under conditions sufficient to oxidize the alkyl substrate to products. The alkyl substrate may be selected from linear and cyclic alkanes.

公开(公告)号：US20230265031A1

公开(公告)日：2023-08-24

申请号：US18014128

申请日：2021-06-17

Applicant: ANDRITZ OY

Inventor： Johan OLSSON

IPC: C07C29/80 ,  C07C29/94

CPC classification number: C07C29/80 ,  C07C29/94

Abstract: A method of purifying raw methanol obtained in chemical pulping, wherein heavy oil is admixed with the raw methanol to prevent precipitation, and the methanol mixture is distilled or evaporated to recover the methanol. The heavy oil is formed by mixing and heating raw methanol obtained from a side stream of chemical hardwood pulping with an acidic aqueous solution to vaporize low boiling point sulfurous compounds and provide acidified raw methanol. The acidified raw methanol is separated into a liquid top phase, a liquid aqueous middle phase, and a liquid bottom phase. The liquid bottom phase is extracted to obtain the heavy oil.

公开(公告)号：US09975829B2

公开(公告)日：2018-05-22

申请号：US15030627

申请日：2014-10-13

Applicant: BASF SE

Inventor： Rolf Pinkos ,  Olga Osetska ,  Irene de Wispelaere ,  Stefan Dudenhoeffer ,  Christina Walczuch

IPC: B01D3/34 ,  C07C29/80 ,  C07C29/88 ,  B01D3/14 ,  C07C29/94

CPC classification number: C07C29/80 ,  B01D3/141 ,  B01D3/34 ,  C07C29/88 ,  C07C29/94 ,  C07C31/207

Abstract: Method for preparing 1,4-butanediol having an APHA color index of less than 30 by treating substance mixtures comprising 1,4-butanediol by distillation of the 1,4-butanediol in the presence of complex hydrides.

公开(公告)号：US20160101403A1

公开(公告)日：2016-04-14

申请号：US14973443

申请日：2015-12-17

Applicant: Cameron Solutions, Inc.

Inventor： Brian E. Messenger

IPC: B01J19/24

CPC classification number: B01J19/24 ,  B01D53/1425 ,  B01D53/263 ,  B01D2252/2023 ,  B01D2257/80 ,  B01J2219/00177 ,  B01J2219/24 ,  C07C29/88 ,  C07C29/94 ,  C09K8/52 ,  C09K2109/00 ,  C09K2208/22 ,  C07C31/202

Abstract: A lean MEG stream having a first pH level is contacted with a CO2-rich gas stream to yield a lean MEG product having a second different and lower pH level preferably in a range of 6.5 to 7.0. The system and method can be readily incorporated into a slipstream MEG recovery package, with a source of the lean MEG stream being a MEG regeneration section of the package. The CO2-rich gas could be a vented CO2 stream from the MEG reclamation section of the package. Unlike hydrochloric and acetic acid overdosing, CO2 overdosing of the lean MEG stream does not lead to rapid acidification of the lean MEG product to be stored or injected.

Abstract translation: 将具有第一pH值的贫MEG流与富含CO 2的气流接触以产生具有第二不同和较低pH值的贫MEG产物，优选在6.5至7.0的范围内。 该系统和方法可以容易地并入到滑流MEG回收包中，其中瘦MEG流的源是包装的MEG再生部分。 富含二氧化碳的气体可以是来自包装的MEG回收部分的排出的CO 2流。 与过量的盐酸和乙酸不同，稀释的MEG流过量的CO 2不会导致要被储存或注入的瘦MEG产物的快速酸化。

公开(公告)号：US20160045414A1

公开(公告)日：2016-02-18

申请号：US14879472

申请日：2015-10-09

Applicant: OSAKA ORGANIC CHEMICAL INDUSTRY LTD.

Inventor： Yutaka Hoshino ,  Takahiro Mukaiyama

IPC: A61K8/34 ,  C09D7/12 ,  A61K8/49 ,  C09D11/38 ,  A61Q19/00 ,  A61Q5/00

CPC classification number: A61K8/345 ,  A61K8/347 ,  A61K8/4926 ,  A61K2800/10 ,  A61Q5/00 ,  A61Q19/00 ,  A61Q19/007 ,  C07C29/94 ,  C09D7/40 ,  C09D7/48 ,  C09D7/63 ,  C09D11/38 ,  C09D201/00 ,  C07C31/20

Abstract: Provided is a composition containing, as an alkane polyol, a C4-18 1,2-alkane polyol in which the degradation over time of the C4-18 1,2-alkane polyol, which has inferior chemical stability and degrades easily, is suppressed, the composition being suitable for use in a cosmetic, an inkjet ink, a fiber or a coating material such as a paint. A composition containing 1,2-alkane polyol that can be used in a cosmetic, an inkjet ink, a raw material for fibers or a coating material, the alkane polyol being a C4-18 1,2-alkane polyol, and the composition containing a radical scavenger.

Abstract translation: 本发明提供一种组合物，其含有作为烷烃多元醇的C4-18 1,2-烷烃多元醇，其中化学稳定性差并易于降解的C4-18 1,2-烷烃多元醇随时间的劣化被抑制 ，该组合物适用于化妆品，喷墨油墨，纤维或涂料等涂料。 可用于化妆品，喷墨油墨，纤维原料或涂料的1,2-烷烃多元醇的组合物，所述烷烃多元醇为C 4-18 1,2-链烷烃多元醇，所述组合物含有 一个激进的清道夫。

公开(公告)号：US20150252054A1

公开(公告)日：2015-09-10

申请号：US14441444

申请日：2013-11-06

Applicant: SAMYANG GENEX CORPORATION

Inventor： Hoon Ryu ,  Young Jae Jung ,  Jin Kyung Kim ,  Do Hyun Kyung ,  Hyuk Min Park ,  Seong Ho Cho

IPC: C07D493/04

CPC classification number: C07D493/04 ,  B01J19/24 ,  C07C29/132 ,  C07C29/80 ,  C07C29/94 ,  C07C31/26

Abstract: The present invention relates to a technique for preparing an anhydrosugar alcohol using hydrogenated sugar as a raw material and, more specifically, to a technique for preparing a high-purity anhydrosugar alcohol by adding an acid to hydrogenated sugar (for example, hexitol) to convert same to an anhydrosugar alcohol, then distilling the converted liquid, and crystallizing the distilled liquid in a solvent, the technique removing a crystallization solvent from a crystallization mother liquor generated during a crystallization step and then introducing the resultant product together with the distilled liquid and the converted liquid into a distillation step, thereby being capable of improving the total distillation yield of the anhydrosugar alcohol, improving distillation efficiency by improving the mobility of a distillate, and further reducing the amount of generated waste and treatment costs and thus highly efficiently preparing the high-purity anhydrosugar alcohol at reduced costs.

Abstract translation: 本发明涉及一种使用氢化糖作为原料制备脱水葡萄糖醇的技术，更具体地说，涉及通过向氢化糖（例如己糖醇）中加入酸来转化而制备高纯度脱水糖醇的技术 与脱水葡萄糖醇相同，然后蒸馏转化的液体，并将溶剂中的蒸馏液结晶，该技术从结晶步骤中产生的结晶母液中除去结晶溶剂，然后将所得产物与蒸馏液和 从而能够提高脱水葡萄糖的总蒸馏收率，通过提高馏出物的流动性来提高蒸馏效率，进一步减少产生的废弃物和处理成本，从而高效地制备高产率 纯度不溶性葡萄糖醇，降低成本。

公开(公告)号：US08273927B2

公开(公告)日：2012-09-25

申请号：US12858566

申请日：2010-08-18

Applicant: John E. Stauffer

Inventor： John E. Stauffer

IPC: C07C29/74

CPC classification number: C07C29/94 ,  C07C29/86 ,  C07C31/08 ,  C07C31/10 ,  C07C31/12

Abstract: A process is provided for the recovery of alcohol from its aqueous solution by dissolving caustic in the solution to generate a phase separation. One layer contains the alcohol product and the other layer waste water. By recovering and recycling the caustic, a self-contained process is realized.

Abstract translation: 提供了通过将苛性碱溶解在溶液中以产生相分离从其水溶液中回收醇的方法。 一层含有酒精产品和其他层废水。 通过回收和回收苛性碱，实现了一个独立的过程。

公开(公告)号：US20100305344A1

公开(公告)日：2010-12-02

申请号：US12745277

申请日：2008-12-01

Applicant: Martin J.T. Reaney ,  Jianheng Shen ,  Douglas W. Soveran

Inventor： Martin J.T. Reaney ,  Jianheng Shen ,  Douglas W. Soveran

IPC: C07C67/02 ,  B01J31/12 ,  C07C29/70 ,  C07C31/30 ,  B01J31/02

CPC classification number: C11C3/003 ,  B01J31/0212 ,  B01J2231/49 ,  B01J2531/11 ,  B01J2531/12 ,  B01J2531/13 ,  B01J2531/14 ,  C07C29/70 ,  C07C29/94 ,  C07C31/30 ,  C07C67/03 ,  C07C69/24 ,  C07C69/52

Abstract: The present disclosure relates to a process for the production of a base complex catalyst comprising reacting a hydroxide base with a polyalcohol, under vacuum pressure, at a temperature in the range of about 60° C. to about 220° C., wherein the mole ratio of the hydroxide base to the polyalcohol is greater than about 2:1.

Abstract translation: 本发明涉及生产碱配合物催化剂的方法，包括在真空压力下，在约60℃至约220℃的温度范围内使氢氧化物碱与多元醇反应，其中该摩尔 氢氧化物碱与多元醇的比例大于约2:1。