公开(公告)号：US4262143A

公开(公告)日：1981-04-14

申请号：US012639

申请日：1979-02-16

Applicant: Mitchell Becker

Inventor： Mitchell Becker

IPC: C07C409/08 ,  C07D301/19 ,  C07C179/04

CPC classification number: C07D301/19 ,  C07C407/00 ,  C07C407/003 ,  C07C409/08

Abstract: In the preparation of ethylbenzene hydroperoxide by reacting ethylbenzene with molecular oxygen, selectivity and reaction rate are improved by incorporating in the oxidation mixture a small amount of a hydroxide or salt of sodium or potassium.

Abstract translation: 在乙苯与分子氧反应制备乙苯氢过氧化物时，通过在氧化混合物中加入少量氢氧化钠或钠或钾盐，提高了选择性和反应速率。

公开(公告)号：US4230640A

公开(公告)日：1980-10-28

申请号：US847633

申请日：1977-11-01

Applicant: Sargis Khoobiar

Inventor： Sargis Khoobiar

IPC: B01J23/887 ,  C07C45/35 ,  C07C45/16

CPC classification number: B01J23/8876 ,  C07C45/35 ,  B01J2523/00

Abstract: A catalyst composition useful for the oxidation of olefins, particularly the oxidation of propylene and isobutylene to produce the corresponding unsaturated aldehydes acrolein and methacrolein, respectively, comprises the combination of oxides of molybdenum, cobalt, iron, bismuth, thallium and antimony, and preferably also silicon. When the catalyst is used for the vapor-phase oxidation of the olefins with molecular oxygen, the aldehydes are produced with high selectivity. Alcohol precursors for the olefins can be used as feed instead of the olefins themselves.

Abstract translation: 可用于烯烃氧化的催化剂组合物，特别是丙烯和异丁烯的氧化分别产生相应的不饱和醛丙烯醛和甲基丙烯醛，包括钼，钴，铁，铋，铊和锑的氧化物的组合， 硅。 当催化剂用于用分子氧气相氧化烯烃时，以高选择性生产醛。 烯烃的醇前体可用作进料而不是烯烃本身。

公开(公告)号：US4115444A

公开(公告)日：1978-09-19

申请号：US654661

申请日：1976-02-05

Applicant: Nabil Rizkalla

Inventor： Nabil Rizkalla

IPC: B01J31/18 ,  B01J31/24 ,  C07C51/56 ,  C07C53/12 ,  C07C53/26 ,  C07C63/04

CPC classification number: C07C53/12 ,  B01J31/1805 ,  B01J31/181 ,  B01J31/24 ,  B01J31/2404 ,  C07C51/56 ,  B01J2531/62 ,  B01J2531/80 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/827 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847

Abstract: A carboxylic acid anhydride such as acetic anhydride, is prepared from a carboxylate ester or a hydrocarbyl ether in carbonylation processes comprising the use of a halide, carbon monoxide and a Group VIII noble metal in the presence of promoters comprising at least one metal of Groups IVB, VB, and VIB or a non-noble metal of Group VIII, or their compounds and an organo-nitrogen compound or an organo-phosphorus compound wherein the nitrogen and phosphorus are trivalent.

Abstract translation: 在羰基化方法中，由羧酸酯或烃基醚制备羧酸酐，例如乙酸酐，其包括在包含至少一种IVB族金属的促进剂的存在下使用卤化物，一氧化碳和VIII族贵金属 ，VB和VIB或VIII族的非贵金属，或其化合物和有机氮化合物或其中氮和磷是三价的有机磷化合物。

公开(公告)号：US4028195A

公开(公告)日：1977-06-07

申请号：US612827

申请日：1975-09-12

Applicant: Mitchell Becker ,  Charles C. Yang

Inventor： Mitchell Becker ,  Charles C. Yang

IPC: C07C27/00 ,  C07C29/80 ,  C07C29/82 ,  C07C31/20 ,  C07C67/00 ,  B01D3/34 ,  C07C29/26

CPC classification number: C07C29/82

Abstract: Ethylene glycol or 1,2-propylene glycol contained in mixtures with lower carboxylate esters of the glycol are separated from such mixtures by fractional distillation of the mixtures with the addition to the lower portion of the distillation zone of aqueous formic acid and/or acetic acid.

Abstract translation: 与二醇的低级羧酸酯的混合物中所含的乙二醇或1,2-丙二醇与混合物分离，通过加入到甲酸水溶液和/或乙酸的蒸馏区的下部分进行分馏 。

公开(公告)号：US4021453A

公开(公告)日：1977-05-03

申请号：US679584

申请日：1976-04-23

Applicant: William F. Brill

Inventor： William F. Brill

IPC: C07D301/03 ,  C07C63/08 ,  C07D301/02 ,  C07D301/06 ,  C07D301/19 ,  C07D303/04 ,  C07D301/20

CPC classification number: C07D301/14 ,  C07D303/04

Abstract: Olefins are oxidized to produce the corresponding epoxides by means of an aryl thallic carboxylate in the presence of an inert polar organic solvent and in the presence of water, the novel compound thallic benzoate being a preferred reactant.

Abstract translation: 在惰性极性有机溶剂的存在下，烯化物被氧化以产生相应的环氧化物，在惰性极性有机溶剂的存在下，在水的存在下，新的化合物是非常优选的反应物。

公开(公告)号：US4002678A

公开(公告)日：1977-01-11

申请号：US643208

申请日：1975-12-22

Applicant: Anthony N. Naglieri ,  Nabil Rizkalla

Inventor： Anthony N. Naglieri ,  Nabil Rizkalla

IPC: C07C53/00 ,  B01J31/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/54 ,  C07C51/56 ,  C07C53/12 ,  C07C67/00

CPC classification number: C07C51/56

Abstract: A carboxylic acid anhydride, such as acetic anhydride, is prepared from a carboxylate ester or a hydrocarbyl ether in carbonylation processes comprising the use of an iodide, carbon monoxide and a nickel-chromium catalyst in the presence of a promoter comprising an organo-nitrogen compound or an organo-phosphorus compound wherein the nitrogen and phosphorus are trivalent.

Abstract translation: 在羰基化方法中由羧酸酯或烃基醚制备羧酸酐，例如乙酸酐，其包括在包含有机氮化合物的促进剂存在下使用碘化物，一氧化碳和镍 - 铬催化剂 或其中氮和磷为三价的有机磷化合物。

公开(公告)号：US3968175A

公开(公告)日：1976-07-06

申请号：US528102

申请日：1974-11-29

Applicant: John Kollar

Inventor： John Kollar

IPC: C07C29/00 ,  C07C67/03

CPC classification number: C07C29/00 ,  C07C67/03

Abstract: A polyhydric compound is produced by catalytically disproportionating a precursor which is a lower carboxylate ester of said compound containing at least one lower carboxylate group and at least one free hydroxyl group. Most preferably the invention relates to the production of a diol by the catalytic disproportionation of a lower carboxylate diester of the diol.

Abstract translation: 通过催化歧化前体，产生多羟基化合物，前体是含有至少一个低级羧酸酯基团和至少一个游离羟基的所述化合物的低级羧酸酯。 本发明最优选涉及二醇的低级羧酸二酯的催化歧化制备二醇。

公开(公告)号：US3954831A

公开(公告)日：1976-05-04

申请号：US537295

申请日：1974-12-30

Applicant: Olav Torgeir Onsager

Inventor： Olav Torgeir Onsager

IPC: C07B61/00 ,  B01J31/00 ,  B01J31/12 ,  B01J31/18 ,  C07C67/00 ,  C07C253/00 ,  C07C255/09 ,  C07C120/00

CPC classification number: B01J31/181 ,  B01J31/1805 ,  C07C255/00 ,  B01J2231/323 ,  B01J2531/26 ,  B01J2531/845

Abstract: Acrylonitrile is dimerized by reaction in the presence of a catalyst consisting essentially of (a) at least one metal compound of the formula M(X).sub.n wherein M is Zn or Co, X is an anion derived from an alkyl or aryl sulfonic acid or from a carboxylic acid containing at least two carbon atoms which is substituted by at least one of the groups, --F, --Cl, --Br, --I and --CN in the .alpha.-C-position relative to the acid group and n is a number equal to the valence of the metal M divided by the number of acid equivalents of X and (b) at least one nitrogen-containing Lewis Base which is (1) a tertiary monoamine of the formula ##EQU1## wherein R.sup.1, R.sup.2, and R.sup.3 are the same or different and each is an alkyl, cycloalkyl, benzyl or aryl radical; or (2) a tertiary di- or poly-functional amine which contains at least two Lewis Base nitrogen groups separated from each other by at least one carbon atom, and which are (a) N-disubstituted amino groups wherein each N-substituent is the same or different and is an alkyl, cycloalkyl, benzyl or aryl radical, or (b) N-heterocyclic groups containing 3 to 20 carbon atoms; or (3) an N-substituted heterocyclic amine containing 3 to 20 carbon atoms in the heterocyclic ring wherein the N-substituent is an alkyl, cycloalkyl, benzyl or aryl radical.

Abstract translation: 丙烯腈在基本上由（a）至少一种式M（X）n的金属化合物（其中M是Zn或Co，X是衍生自烷基或芳基磺酸的阴离子）或 由相对于酸基的α-C-位中的至少一个基团-F，-Cl，-Br，-I和-CN取代的至少两个碳原子的羧酸，n是 金属M的化合价除以X的酸当量数，和（b）至少一种含氮路易斯碱，其为（1）式R 2 R 1 -N ANGLE R 3的叔胺，其中R 1 ，R2和R3相同或不同，各自为烷基，环烷基，苄基或芳基; 或（2）含有至少两个由至少一个碳原子彼此分开的路易斯碱氮基团的叔二 - 或多官能胺，它们是（a）N-二取代的氨基，其中每个N-取代基是 相同或不同，为烷基，环烷基，苄基或芳基，或（b）含有3-20个碳原子的N-杂环基; 或（3）在杂环中含有3-20个碳原子的N-取代杂环胺，其中N-取代基是烷基，环烷基，苄基或芳基。

公开(公告)号：US3907874A

公开(公告)日：1975-09-23

申请号：US27890372

申请日：1972-08-09

Applicant: HALCON INTERNATIONAL INC

Inventor： HARVEY ROBERT JOSEPH ,  KOLLAR JOHN ,  SCHMIDT JOHN PHILIP

IPC: C07C67/05 ,  B01J27/00 ,  B01J27/08 ,  B01J31/00 ,  C07B61/00 ,  C07C69/02 ,  C07C67/08 ,  C07C69/16

CPC classification number: B01J27/08 ,  C07C67/05 ,  Y02P20/582 ,  C07C69/16 ,  C07C69/28

Abstract: When vicinal glycol esters are prepared by the liquid phase reaction of (a) ethylene or propylene, (b) molecular oxygen and (c) a carboxylic acid in the presence of a catalyst system which is tellurium cation plus bromide anion or selenium cation plus chloride anion or selenium cation plus bromide anion, significant improvements in selectivity and operability are obtained by employing, in conjunction with these catalyst systems, a basicity control cation of specified characteristics. This cation is employed in an amount at least sufficient to provide at least 0.05 equivalent of cation per gram-atom of halogen present.

Abstract translation: 当连环乙二醇酯通过（a）乙烯或丙烯的液相反应，（b）分子氧和（c）羧酸在催化剂体系的存在下制备，所述催化剂体系是碲阳离子加溴化物阴离子或硒阳离子加氯化物 阴离子或硒阳离子加溴化物阴离子，通过与这些催化剂体系结合使用具有特定特征的碱性控制阳离子，可以获得显着的选择性和可操作性的改善。 该阳离子的使用量至少足以提供每克原子卤素存在至少0.05当量的阳离子。

公开(公告)号：US3884965A

公开(公告)日：1975-05-20

申请号：US35584373

申请日：1973-04-30

Applicant: HALCON INTERNATIONAL INC

Inventor： KOLLAR JOHN

IPC: C07C67/48 ,  C07C67/06

CPC classification number: C07C67/60 ,  C07C67/055 ,  C07C67/29 ,  C07C69/16

Abstract: Esters of C2-C3 vicinal glycols with C1-C5 hydrocarbon carboxylic acids are at least partially freed from organic halogen compound impurities by introducing the impuritycontaining glycol esters into contact with compounds of selected metals, the ratio of total equivalents of metal to total equivalents of halogen during such contact being in excess of 1: 1. Following such contact, the vicinal glycol ester possesses a reduced concentration of organo-halogen compound impurities and can readily be separated from inorganic halogen residues.

Abstract translation: 具有C1-C5烃羧酸的C2-C3连位二醇的酯通过将含杂质的二醇酯引入与所选金属的化合物接触而至少部分地除去有机卤素化合物杂质，金属的总当量比与总当量的比率 的卤素在这种接触过程中超过1：1。 在这种接触之后，连位乙二醇酯具有降低的有机卤素化合物杂质浓度，并且可容易地与无机卤素残基分离。