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公开(公告)号：US3595898A
公开(公告)日：1971-07-27
申请号：US3595898D
申请日：1968-03-11
IPC分类号： C07C409/38 , C07C69/00
CPC分类号： C07C407/00 , C07C407/003 , C07C409/38
摘要： THIS INVENTION RELATES TO A PROCESS FOR THE MANUFACTURE OF PERESTERS AND MORE PARTICULARLY TO SUCH A PROCESS WHEREIN THE PERESTERS ARE PREPARED BY REACTION BETWEEN AN ORGANIC HYDROPEROXIDE AND A CARBOXYLIC ACID. IN PARTICULARLY PREFERRED EMBODIMENTS, THIS INVENTION RELATES TO PROCESSES FOR THE MANUFACTURE OF TERTIARY ALKYL PERESTES AND TO SECONDARY AND TERTIARY ARALKYL PERESTERS. THUS, THIS INVENTION IS ESPECIALLY APPLICABLE TO THE MANUFACTURE OF SUCH PERESTERS AS, FOR EXAMPLE, T-BUTYL PERACETATE, T-BUTYL PERBENZOATE, ETHYLBENZYL PERPIVALATE AND CUMYL PERISOBUTYRATE.
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公开(公告)号：US3907874A
公开(公告)日：1975-09-23
申请号：US27890372
申请日：1972-08-09
IPC分类号： C07C67/05 , B01J27/00 , B01J27/08 , B01J31/00 , C07B61/00 , C07C69/02 , C07C67/08 , C07C69/16
CPC分类号： B01J27/08 , C07C67/05 , Y02P20/582 , C07C69/16 , C07C69/28
摘要： When vicinal glycol esters are prepared by the liquid phase reaction of (a) ethylene or propylene, (b) molecular oxygen and (c) a carboxylic acid in the presence of a catalyst system which is tellurium cation plus bromide anion or selenium cation plus chloride anion or selenium cation plus bromide anion, significant improvements in selectivity and operability are obtained by employing, in conjunction with these catalyst systems, a basicity control cation of specified characteristics. This cation is employed in an amount at least sufficient to provide at least 0.05 equivalent of cation per gram-atom of halogen present.
摘要翻译： 当连环乙二醇酯通过（a）乙烯或丙烯的液相反应，（b）分子氧和（c）羧酸在催化剂体系的存在下制备，所述催化剂体系是碲阳离子加溴化物阴离子或硒阳离子加氯化物 阴离子或硒阳离子加溴化物阴离子，通过与这些催化剂体系结合使用具有特定特征的碱性控制阳离子，可以获得显着的选择性和可操作性的改善。 该阳离子的使用量至少足以提供每克原子卤素存在至少0.05当量的阳离子。
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