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    Method for producing acyl peroxides
    1.
    发明申请
    Method for producing acyl peroxides 有权
    酰基过氧化物的制备方法

    公开(公告)号：US20100022794A1

    公开(公告)日：2010-01-28

    申请号：US12309161

    申请日：2007-06-18

    Applicant: Hans Appel ,  Wilfried Meichelböck ,  Josef Helmut Weinmaier ,  Helmut Zellner

    Inventor： Hans Appel ,  Wilfried Meichelböck ,  Josef Helmut Weinmaier ,  Helmut Zellner

    IPC: C07C409/24

    CPC classification number: C07C407/00 ,  C07C407/003 ,  C07C409/38

    Abstract: The invention relates to a method for producing acyl peroxides. According to said method, an acyl compound is reacted with an organic hydroperoxide and a base, the pH of the two-phase mixture so obtained is adjusted to 6 to 13, the obtained organic phase is extracted with an aqueous solution of a base and the aqueous extract is recirculated to the reaction step. The method according to the invention allows the recirculation of unreacted hydroperoxide to the reaction step.

    Abstract translation: 本发明涉及一种生产酰基过氧化物的方法。 根据所述方法，将酰基化合物与有机氢过氧化物和碱反应，将得到的两相混合物的pH调节至6〜13，将得到的有机相用碱的水溶液萃取， 水提取物再循环到反应步骤。 根据本发明的方法允许未反应的氢过氧化物再循环到反应步骤。

    Peroxyester preparation method
    2.
    发明授权
    Peroxyester preparation method 有权
    过氧化物的制备方法

    公开(公告)号：US07439384B2

    公开(公告)日：2008-10-21

    申请号：US10467782

    申请日：2002-02-07

    Applicant: Sandra Grimaldi ,  Gurusamy Jeyaraj

    Inventor： Sandra Grimaldi ,  Gurusamy Jeyaraj

    IPC: C07C67/02 ,  C07C69/02

    CPC classification number: C08K5/14 ,  C07C407/00 ,  C07C409/38

    Abstract: The present invention relates to a process for the preparation of a peroxyester which can be used in particular in polymerizations, such as the polymerization of vinyl chloride, or in the thermosetting of polyester resins.This process comprises the reaction of a hydroxyhydroperoxide salt with an acid halide or an acid anhydride under the following conditions: the molar ratio Rb of the hydroxyhydroperoxide corresponding to the hydroxyhydroperoxide salt to the acid halide is between 0.5 and 1.5; or alternatively the molar ratio Rb′ of the hydroxyhydroperoxide corresponding to the hydroxyhydroperoxide salt to the acid anhydride is between 1.0 and 3.0; the hydroxyhydroperoxide salt was prepared beforehand by reaction of the corresponding hydroxyhydroperoxide with a base according to a molar ratio Ra of the base to the hydroxyhydroperoxide of between 0.5 and 1.5; and this process is carried out in aqueous media. The invention also relates to an aqueous emulsion comprising the peroxyester obtained and to a polymerization process employing a radical initiator comprising this peroxyester.

    Abstract translation: 本发明涉及一种制备过氧酯的方法，特别可用于聚合中，如氯乙烯的聚合，或在聚酯树脂的热固化中。 该方法包括在以下条件下羟基氢过氧化物盐与酰卤或酸酐的反应：对应于羟基氢过氧化物盐的羟基氢过氧化物与酰基卤的摩尔比R b为0.5至 1.5; 或者对应于羟基氢过氧化物盐的羟基氢过氧化物与酸酐的摩尔比R bb为1.0至3.0; 预先通过相应的羟基氢过氧化物与碱的反应来制备羟基氢过氧化物盐，根据碱的摩尔比与羟基氢过氧化物的摩尔比为0.5-1.5; 并且该方法在含水介质中进行。 本发明还涉及包含所获得的过氧酯和使用包含该过氧酯的自由基引发剂的聚合方法的水性乳液。

    Peroxide compositions with reactive diluents
    3.
    发明授权
    Peroxide compositions with reactive diluents 失效
    具有活性稀释剂的过氧化物组合物

    公开(公告)号：US07160951B2

    公开(公告)日：2007-01-09

    申请号：US10451049

    申请日：2001-12-19

    Applicant: Jan H Udding ,  Agnes E Wolters ,  Heinz Wilhelm ,  Armin Pfeil ,  Thomas Bürgel ,  Lutz Sager

    Inventor： Jan H Udding ,  Agnes E Wolters ,  Heinz Wilhelm ,  Armin Pfeil ,  Thomas Bürgel ,  Lutz Sager

    IPC: C08F261/06

    CPC classification number: C07C407/006 ,  C07C407/00 ,  C08F4/32 ,  C07C409/22 ,  C07C409/38 ,  C07C409/34 ,  C07C409/10

    Abstract: The invention relates to peroxide compositions comprising a reactive diluent for the peroxide, wherein the diluent is either a component containing one or more vinyl ether group(s) and having a monomeric structure according to formula 1, (A—CH═CH—O)n—R, or is a suitable resinous compound comprising, in a covalently built-in manner, a component containing one or more vinyl ether group(s). In the formula A represents hydrogen or an alkyl group with 1–3 C atoms, and individual A groups may be different R either represents an aliphatic group, optionally branched, with 1–20 C atoms, etc.  or represents a polyethylene or polypropylene glycol with 2 to 120 glycol units, etc. and n is 1, 2, 3 or 4. The resinous compounds comprising, in a covalently built-in manner, a component containing one or more vinyl ether group(s)are obtained by reaction of: a) a first compound (the HVE-compound) containing at least one hydroxyl group and at least one vinyl ether group, and b) a second compound (the D/HIC-compound), being an isocyanate, reacting with formation of one or more urethane group(s), and c) a third compound (the G/P/HP-compound) chosen from the groups of (1) C2-6 glycols, (2) C5-20 polyols having 2–5 hydroxyl groups and (3) hydroxyl terminated polyester compounds, not being alkyd resins, having 1–5 free hydroxyl groups and from 2–50 monomeric ester units (the G/P/HP-compound), or mixtures thereof. The invention also relates to the preparation of such compositions and to the use of such reactive diluents for peroxides in radically curing of unsaturated polyester resins for structural applications.

    Abstract translation: 本发明涉及包含用于过氧化物的反应性稀释剂的过氧化物组合物，其中稀释剂是含有一个或多个乙烯基醚基团并且具有根据式1的单体结构的组分（A-CH-CH-O） 或者是合适的树脂化合物，其以共价内置的方式包含含有一个或多个乙烯基醚基团的组分。 式A表示氢或具有1-3个C原子的烷基，各个A基团可以不同，R表示任选支链的1-20个C原子的脂族基团等，或代表聚乙烯或聚丙二醇 2〜120个二醇单元等，n为1,2,3或4.含有一个或多个乙烯基醚基的成分以共价内置的方式包含的树脂化合物是通过 ：a）含有至少一个羟基和至少一个乙烯基醚基团的第一化合物（HVE-化合物），和b）作为异氰酸酯的第二化合物（D / HIC-化合物）与形成一个 或更多个氨基甲酸酯基团，和c）选自（1）C 2-6 - 二醇的第三化合物（G / P / HP-化合物），（2）C < 具有2-5个羟基的（3）羟基封端的聚酯化合物，不具有1-5个游离羟基的醇酸树脂和2-50个单体酯单元（t 他G / P / HP-化合物）或其混合物。 本发明还涉及这种组合物的制备以及这种反应性稀释剂在不饱和聚酯树脂的自由基固化中用于结构应用的过氧化物的用途。

    Multi-component ethylenically unsaturated peroxyesters
    8.
    发明授权
    Multi-component ethylenically unsaturated peroxyesters 失效
    多组分烯属不饱和过氧酯

    公开(公告)号：US5644004A

    公开(公告)日：1997-07-01

    申请号：US378148

    申请日：1995-01-25

    Applicant: Jose Sanchez

    Inventor： Jose Sanchez

    IPC: C07C409/00 ,  C07C409/38 ,  C08F2/46 ,  C08F2/48 ,  C08F4/38 ,  C08F299/04 ,  C08F20/00

    CPC classification number: C08F299/045 ,  C07C409/38 ,  C08F4/38

    Abstract: A novel and safe ethylenically unsaturated peroxyester composition derived from an ethylenically unsaturated dicarboxylic acid is provided, as well as processes for making and using the composition. The peroxyester composition comprises about 0.04 to about 0.70 mole fraction of a first component compound having a formula I: ##STR1## about 0.32 to about 0.50 mole fraction of a second component compound having a formula II: ##STR2## about 0.04 to about 0.70 mole fraction of a third component compound having a formula III: ##STR3## wherein Q is an unsaturated ethylene divalent radical and R.sup.1 and R.sup.2 are organic substituents. Polymeric-peroxides are prepared via polymerizing the peroxyester compositions. The peroxyester compositions are also used for curing unsaturated polyester resins and for initiating polymerization of ethylenically unsaturated monomers.

    Abstract translation: 提供了一种由烯键式不饱和二羧酸衍生的新型和安全的烯属不饱和过氧酯组合物，以及制备和使用该组合物的方法。 过氧酯组合物包含约0.04至约0.70摩尔分数的具有式I的第一组分化合物：具有式II的第二组分化合物的约0.32至约0.50摩尔分数：约0.04至约 0.70摩尔分数的具有式III的第三组分化合物：其中Q是不饱和乙烯二价基团，R 1和R 2是有机取代基。 通过聚合过氧酯组合物制备聚合物 - 过氧化物。 过氧酯组合物也用于固化不饱和聚酯树脂和用于引发烯属不饱和单体的聚合。

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