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    Process for polymer reactions with functionalized peroxides
    2.
    发明授权
    Process for polymer reactions with functionalized peroxides 失效
    用官能化过氧化物进行聚合反应的方法

    公开(公告)号：US5710210A

    公开(公告)日：1998-01-20

    申请号：US465899

    申请日：1995-06-06

    申请人： Daryl L. Stein

    发明人： Daryl L. Stein

    IPC分类号： C07C409/00 ,  C07C409/38 ,  C07C409/40 ,  C07C409/42 ,  C08F4/28 ,  C08F4/34 ,  C08F4/36 ,  C08F283/01 ,  C08G18/86 ,  C08K5/14 ,  C08F8/00 ,  C08F8/50 ,  C08F10/06 ,  C08G63/91 ,  C08G69/48

    CPC分类号： C08G18/86 ,  C07C409/38 ,  C08F283/01 ,  C07C2101/14 ,  C07C2102/42

    摘要： Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.

    摘要翻译： 可用作交联，接枝和固化剂的新型官能化过氧化物，用于聚合反应的引发剂和用于缩合聚合的单体以形成过氧化物聚合物，其又可用于制备嵌段和接枝共聚物，具有下式I ：R1，R2，R3，R4，R5，R6，R7，X，Y1，Y2，Y3，Z1，Z2，x，y和z如发明概述中所定义。 式I化合物可以通过使含羟基的叔氢过氧化物与二酸卤化物，光气，二氯甲酸酯，二异氰酸酯，酸酐和内酯反应形成官能化过氧化物来制备。 如果需要，这些反应产物可以进一步与二醇，二胺，氨基醇，环氧化物，环氧醇，环氧胺，二酸卤化物，二氯甲酸酯和二异氰酸酯反应以形成另外的官能化过氧化物。

    Process for polymerization reactions with functionalized peroxides
    3.
    发明授权
    Process for polymerization reactions with functionalized peroxides 失效
    用官能化过氧化物进行聚合反应的方法

    公开(公告)号：US5612439A

    公开(公告)日：1997-03-18

    申请号：US467665

    申请日：1995-06-06

    申请人： Daryl L. Stein

    发明人： Daryl L. Stein

    IPC分类号： C07C409/00 ,  C07C409/38 ,  C07C409/40 ,  C07C409/42 ,  C08F4/28 ,  C08F4/34 ,  C08F4/36 ,  C08F283/01 ,  C08G18/86 ,  C08K5/14 ,  C08G18/28 ,  C08G63/02 ,  C08G69/02 ,  C08G73/10

    CPC分类号： C08G18/86 ,  C07C409/38 ,  C08F283/01 ,  C07C2101/14 ,  C07C2102/42

    摘要： Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.

    摘要翻译： 可用作交联，接枝和固化剂的新型官能化过氧化物，用于聚合反应的引发剂和用于缩合聚合的单体以形成过氧化物聚合物，其又可用于制备嵌段和接枝共聚物，具有下式I ：＆lt; IMAGE＆gt; + E，不I + EE R1，R2，R3，R4，R5，R6，R7，X，Y1，Y2，Y3，Z1，Z2，x，y和z如 发明。 式I化合物可以通过使含羟基的叔氢过氧化物与二酸卤化物，光气，二氯甲酸酯，二异氰酸酯，酸酐和内酯反应形成官能化过氧化物来制备。 如果需要，这些反应产物可以进一步与二醇，二胺，氨基醇，环氧化物，环氧醇，环氧胺，二酸卤化物，二氯甲酸酯和二异氰酸酯反应以形成另外的官能化过氧化物。

    Process for polymer reaction with functionalized peroxides
    4.
    发明授权
    Process for polymer reaction with functionalized peroxides 失效
    与官能化过氧化物进行聚合反应的方法

    公开(公告)号：US5536790A

    公开(公告)日：1996-07-16

    申请号：US467491

    申请日：1995-06-06

    申请人： Daryl L. Stein

    发明人： Daryl L. Stein

    IPC分类号： C07C409/00 ,  C07C409/38 ,  C07C409/40 ,  C07C409/42 ,  C08F4/28 ,  C08F4/34 ,  C08F4/36 ,  C08F283/01 ,  C08G18/86 ,  C08K5/14 ,  C07C69/96 ,  C08L23/10

    CPC分类号： C08G18/86 ,  C07C409/38 ,  C08F283/01 ,  C07C2101/14 ,  C07C2102/42

    摘要： Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.

    摘要翻译： 可用作交联，接枝和固化剂的新型官能化过氧化物，用于聚合反应的引发剂和用于缩合聚合的单体以形成过氧化物聚合物，其又可用于制备嵌段和接枝共聚物，具有下式I ：R1，R2，R3，R4，R5，R6，R7，X，Y1，Y2，Y3，Z1，Z2，x，y和z如发明概述中所定义。 式I化合物可以通过使含羟基的叔氢过氧化物与二酸卤化物，光气，二氯甲酸酯，二异氰酸酯，酸酐和内酯反应形成官能化过氧化物来制备。 如果需要，这些反应产物可以进一步与二醇，二胺，氨基醇，环氧化物，环氧醇，环氧胺，二酸卤化物，二氯甲酸酯和二异氰酸酯反应以形成另外的官能化过氧化物。

    Diacylated dipercarboxylic acid as bleaching agent
    5.
    发明授权
    Diacylated dipercarboxylic acid as bleaching agent 失效
    二酰基二过羧酸作为漂白剂

    公开(公告)号：US5415668A

    公开(公告)日：1995-05-16

    申请号：US946343

    申请日：1992-11-06

    申请人： Hans Lagnemo ,  Annbritt Forsstrom

    发明人： Hans Lagnemo ,  Annbritt Forsstrom

    IPC分类号： C07C291/04 ,  C07C409/30 ,  C07C409/34 ,  C07C409/40 ,  C07C409/42 ,  C11D3/39 ,  C11D3/395 ,  D06L3/02

    CPC分类号： C07C291/04 ,  C07C409/34 ,  C07C409/40 ,  C07C409/42 ,  C11D3/3945

    摘要： ##STR1## The invention concerns diacylated dipercarboxylic acids according to general formula (I), in which R
    1 and R
    2 are hydrocarbon groups having from 1 to 15 carbon atoms, and X is electron attracting by being an optionally substituted phenyl group, an optionally substituted heterocycle in which the hetero atom is positioned so that from 2 to 4 carbon atoms are present between the hetero atom and each one of the carbonyl carbons of the diperacid, or by comprising at least one electron attracting functional group positioned so that a carbon chain having from 2 to 4 carbon atoms is present between said electron attracting group and each one of the carbonyl carbons of the diperacid, wherein the electron attracting group contains oxygen, sulfur, nitrogen, phosphorus, halogen, optionally substituted phenyl, or at least two conjugated double bonds, R
    1 and R
    2 are hydrocarbon groups having from 1 to 15 carbon atoms, except compounds in which X consists of a phenyl group having the carbonyl carbons in 1,4 position and both of R
    1 and R
    2 are acetyl or both of R
    1 and R
    2 are nonyl. The invention also concerns a method of their preparation, a composition useful for bleaching and a method of bleaching.

    摘要翻译： PCT No.PCT / SE91 / 00291 Sec。 371日期：1992年11月6日 102（e）日期1992年11月6日PCT 1991年4月24日PCT PCT。 第WO91 / 17143号公报 （I）本发明涉及根据通式（I）的二酰化二元羧酸，其中R 1和R 2是具有1至15个碳原子的烃基，X是通过 任选取代的苯基，任选取代的杂环，其中所述杂原子被定位使得2至4个碳原子存在于所述杂原子和所述二酸的每个羰基碳之间，或通过包含至少一个吸电子 官能团定位使得具有2至4个碳原子的碳链存在于所述吸电子基团和二酸的每个羰基碳之间，其中电子吸引基团含有氧，硫，氮，磷，卤素，任选地 取代的苯基或至少两个共轭双键，R 1和R 2是具有1至15个碳原子的烃基，除了其中X由苯基 具有1,4位的羰基碳原子，R1和R2两者都是乙酰基，R1和R2都是壬基。 本发明还涉及它们的制备方法，可用于漂白的组合物和漂白方法。

    Sulfone peroxycarboxylic acids
    7.
    发明授权
    Sulfone peroxycarboxylic acids 失效
    砜过氧羧酸

    公开(公告)号：US5004558A

    公开(公告)日：1991-04-02

    申请号：US281440

    申请日：1988-12-08

    申请人： David R. Dyroff ,  Daniel P. Getman ,  Joan K. Glascock

    发明人： David R. Dyroff ,  Daniel P. Getman ,  Joan K. Glascock

    IPC分类号： C07C407/00 ,  C07C409/42 ,  C11D3/39

    CPC分类号： C07C407/006 ,  C11D3/3945

    摘要： There are disclosed novel, highly stable sulfone peroxycarboxylic acids useful in detergent compositions or alone as bleaching agents which are represented by the formula ##STR1## wherein A and B are organic moieties bonded to the sulfur atom by a carbon atom and one of A and B contains from 1 to 4 ##STR2## groups bonded to carbon atoms.

    摘要翻译： 公开了可用于洗涤剂组合物或单独作为漂白剂的新颖的，高度稳定的砜过氧羧酸，其由下式表示：其中A和B是通过碳原子和A和B之一键合到硫原子的有机部分 含有与碳原子键合的1至4个基团。

    Diperoxyacid precursors and method
    9.
    发明授权
    Diperoxyacid precursors and method 失效
    二过氧酸前体和方法

    公开(公告)号：US4735740A

    公开(公告)日：1988-04-05

    申请号：US915133

    申请日：1986-10-03

    申请人： Alfred G. Zielske

    发明人： Alfred G. Zielske

    IPC分类号： C11D7/38 ,  C07C67/00 ,  C07C309/42 ,  C07C407/00 ,  C07C409/42 ,  C11D3/39 ,  C11D7/54 ,  D06L3/02 ,  C07C69/017

    CPC分类号： C07C309/00 ,  C11D3/3915

    摘要： Novel sulfonated phenyl esters of dicarboxylic acids are useful as diperoxyacid precursors in bleaching and laundering applications when combined with a source of peroxide. These diperoxyacid precursors can be produced by reacting a dicarboxylic acid, a phenol sulfonate, and a lower alkyl acid anhydride in an alkyl hydrocarbon solvent and removing a carboxylic acid byproduct through distillation. The diperoxyacid precursors have the structure: ##STR1## wherein n is an integer from about 4 to about 18 and M is an alkali metal, an alkaline earth metal, or ammonium. The diperoxyacid precursors have a high perhydrolysis profile coupled with a relatively low-to-moderate hydrolysis profile.

    Process for synthesizing alkyl monoperoxysuccinic acid bleaching compositions
    10.
    发明授权
    Process for synthesizing alkyl monoperoxysuccinic acid bleaching compositions 失效
    合成烷基单过氧化琥珀酸漂白组合物的方法

    公开(公告)号：US4659519A

    公开(公告)日：1987-04-21

    申请号：US626826

    申请日：1984-07-02

    申请人： Hao Ku

    发明人： Hao Ku

    IPC分类号： C07C409/24 ,  C07C409/40 ,  C07C409/42 ,  C11D3/39 ,  C07C87/00

    CPC分类号： C07C409/24 ,  C11D3/3945

    摘要： The invention relates to a novel process for synthesizing surface active peroxyacid bleaching agents and compositions which are named .alpha. or .beta. alkyl monoperoxysuccinic acids and have the general structure ##STR1## wherein R is an unsubstituted or substituted straight chain alkyl of 6 to 16 carbon atoms, unsubstituted or substituted branched chain alkyl of 6 to 20 carbon atoms, or a phenyl group substituted with one or more of H, alkyl of 1 to 14 carbon atoms, F, Cl, NO.sub.3, OSO.sub.3 M, SO.sub.3 M, or COOM, and M is further defined as H, an alkali metal or ammonium cation.The invention provides a novel process for synthesizing these alkyl monoperoxysuccinic acids which is relatively inexpensive, high yielding, and safe.The bleaching compositions are useful for bleaching fabrics and other laundering purposes. The bleaching compositions of the invention may also contain peroxyacid stabilizers, builders, fillers, and surfactants.

    摘要翻译： 本发明涉及用于合成表面活性过氧酸漂白剂和组合物的新方法，其被称为α或β烷基单过氧化琥珀酸，并具有通用结构，其中R是未取代或取代的6至16个碳原子的直链烷基， 或未取代或取代的碳原子数6〜20的支链烷基，或被1至14个碳原子的一个或多个取代的苯基，F，Cl，NO 3，OSO 3 M，SO 3 M或COOM，M进一步 定义为H，碱金属或铵阳离子。 本发明提供了一种合成这些烷基单过氧化琥珀酸的新方法，其相对便宜，高产率和安全。 漂白组合物可用于漂白织物和其他洗涤用途。 本发明的漂白组合物还可以含有过氧酸稳定剂，助洗剂，填料和表面活性剂。