Low color compositions comprising a cross-linked polycyanurate polymer
and a thermoplastic polymer
    1.
    发明授权
    Low color compositions comprising a cross-linked polycyanurate polymer and a thermoplastic polymer 失效
    包含交联聚氰化脲聚合物和热塑性聚合物的低色组合物

    公开(公告)号:US4334045A

    公开(公告)日:1982-06-08

    申请号:US213530

    申请日:1980-12-05

    CPC分类号: C08L79/04 C08G73/0661

    摘要: A monomeric aromatic dicyanate is purified to remove color forming impurities, combined with a zinc salt catalyst and cured first below 200.degree. C. and then for a limited time at or above 200.degree. C., either alone or in admixture with or on a thermoplastic polymer. For example, purified 2,2-bis(4-cyanatophenyl)propane is purified, combined with a poly(ester carbonate) and zinc chloride, and then cured at increasing temperatures from 150.degree. C. to 250.degree. C.

    摘要翻译: 纯化单体芳族二氰酸酯以除去形成成色杂质,并与锌盐催化剂组合,然后首先在200℃以下固化,然后在200℃或200℃以上的限定时间,单独或与热塑性塑料混合或混合 聚合物。 例如,将纯化的2,2-双(4-氰基苯基)丙烷纯化,与聚(碳酸酯)和氯化锌组合,然后在150℃至250℃的升温下固化。

    Low color compositions comprising a cross-linked polycyanurate polymer
and a thermoplastic polymer
    2.
    发明授权
    Low color compositions comprising a cross-linked polycyanurate polymer and a thermoplastic polymer 失效
    包含交联聚氰化脲聚合物和热塑性聚合物的低色组合物

    公开(公告)号:US4414366A

    公开(公告)日:1983-11-08

    申请号:US384857

    申请日:1982-06-04

    CPC分类号: C08G73/0661 C08L79/04

    摘要: Purified aromatic dicyanates are cured with a catalyst which is an Mn(II), Ag(II), Fe(III), Bi(III), In(III) or Hf(IV) salt at 150.degree.-200.degree. C. and then at 200.degree.-300.degree. C. for a time sufficient to cure the dicyanate without causing color formations to the extent of a Yellowness Index over 30. In some forms the dicyanate is combined with the catalyst and a thermoplastic.

    摘要翻译: 纯化的芳族二氰酸酯在150℃-200℃下用Mn(II),Ag(II),Fe(III),Bi(III),In(III)或Hf(IV)盐催化剂固化, 然后在200°-300℃下搅拌足以固化二氰酸酯的时间,而不会使黄色指数超过30的颜色形成。在某些形式中,二氰酸酯与催化剂和热塑性塑料组合。

    Very low creep, ultra high modulus, low shrink, high tenacity polyolefin
fiber having good strength retention at high temperatures and method to
produce such fiber
    3.
    发明授权
    Very low creep, ultra high modulus, low shrink, high tenacity polyolefin fiber having good strength retention at high temperatures and method to produce such fiber 失效
    非常低的蠕变,超高模量,低收缩,高强度聚烯烃纤维在高温下具有良好的强度保持性和制造这种纤维的方法

    公开(公告)号:US5578374A

    公开(公告)日:1996-11-26

    申请号:US385238

    申请日:1995-02-08

    摘要: By poststretching, at a temperature between about 135.degree. and 160.degree. C., a polyethylene fiber, which has already been oriented by drawing at a temperature within 5.degree. C. of its melting point, an ultra high modulus, very low creep, low shrink, high tenacity polyolefin fiber having good strength retention at high temperatures is obtained. The poststretching can be in multiple stages and/or with previous annealing. The poststretching should be done at a draw rate of less than 1 second.sup.-1. Tensile modulus values over 2,000 g/d for multifilament yarn are consistently obtained for ultrahigh molecular weight-polyethylene, with tensile strength values above 30 g/d while at the same time dramatically improving creep (at 160.degree. F. (71.1.degree. C.) and 39,150 psi load) by values at least 25% lower than fiber which has not been poststretched. Shrinkage is improved to values less than 2.5% of the original length when heated from room temperature to 135.degree. C. Performance at higher temperature is improved by about 15.degree. to 25.degree. C.

    摘要翻译: 通过在约135℃至160℃的温度下拉伸,已经通过在其熔点5℃的温度下拉伸定向的聚乙烯纤维,超高模量,非常低的蠕变,低 获得在高温下具有良好强度保持性的收缩,强韧性聚烯烃纤维。 后拉伸可以在多个阶段和/或先前的退火中。 延期工作应以小于1秒-1的抽签率进行。 对于超高分子量聚乙烯,拉伸强度值高于30g / d,同时显着改善蠕变(在160°F(71.1℃))下,针对复丝纱线的拉伸模量值超过2,000g / d。 和39,150磅/平方英寸负载),比尚未拉伸的纤维低至少25%。 当从室温加热到135℃时,收缩率提高到小于原始长度的2.5%的值。在较高温度下的性能提高约15至25℃。

    Flexible multi-layered armor
    5.
    发明授权
    Flexible multi-layered armor 失效
    灵活多层装甲

    公开(公告)号:US5175040A

    公开(公告)日:1992-12-29

    申请号:US701337

    申请日:1991-05-10

    摘要: The present invention is a flexible impact resistant article comprising a plurality of prepreg packets. Each prepreg packet comprises at least about 2 prepreg layers. Each prepreg layer comprises a plurality of coplanar fibers embedded in a polymeric matrix. There is a means to maintain at least a portion of each prepreg packet in successive layers. The prepreg packets are unattached to each other over a portion of their adjacent areas, preferably over a substantial portion of their adjacent areas. The plurality of packets results in improved flexibility.

    摘要翻译: 本发明是一种具有多个预浸料包的柔性耐冲击制品。 每个预浸料包括至少约2个预浸料层。 每个预浸料层包括嵌入聚合物基质中的多个共面纤维。 存在在每个预浸料包的至少一部分中保持连续层的方法。 预浸料包在其相邻区域的一部分上彼此未连接,优选在其相邻区域的大部分上。 多个分组导致改进的灵活性。

    Prepreg machine with a single endless conveyor belt
    6.
    发明授权
    Prepreg machine with a single endless conveyor belt 失效
    预浸机具有单个环形输送带

    公开(公告)号:US5149391A

    公开(公告)日:1992-09-22

    申请号:US734074

    申请日:1991-07-22

    IPC分类号: B29C70/50

    CPC分类号: B29C70/50 B29C70/504

    摘要: A device for forming a resin impregnated unidirectional fiber reinforced prepreg where the resin impregnated fiber web is supported by a single endless conveyor belt. The device includes a pair of pull rolls which exert force directly and longitudinally onto the conveyor belt and the web.

    摘要翻译: 一种用于形成树脂浸渍的单向纤维增强预浸料的装置,其中树脂浸渍的纤维网由单个环形输送带支撑。 该装置包括一对牵引辊,其直接且纵向地施加在传送带和卷材上。

    Flame resistant article made of phenolic triazine and related method
using a pure cyanato novolac
    9.
    发明授权
    Flame resistant article made of phenolic triazine and related method using a pure cyanato novolac 失效
    使用酚醛三嗪制成的耐火制品及相关方法,使用纯的氰基酚醛清漆

    公开(公告)号:US4988780A

    公开(公告)日:1991-01-29

    申请号:US232407

    申请日:1988-08-15

    CPC分类号: C08G8/28 C08G73/0655

    摘要: The present invention is flame resistant article and related method, made of phenolic triazine resin derived from a cyanato group containing phenolic resin of the formula: ##STR1## wherein: n is a positive whole number greater than or equal to 1;q and r are the same or different at each occurrence and are whole numbers from 0 to 3, with the proviso that the sum of q and r at each occurrence is equal to 3;Z is --CN, or hydrogen and --CN;o and p are the same or different at each occurrence and are whole numbers from 0 to 4 with the proviso that the sum of o and p at each occurrence is equal to 4;--X-- is a divalent organic radical; andR.sub.3 is the same or different at each occurrence and is a substituent other than hydrogen which is unreactive under conditions necessary to completely cure the copolymer.

    摘要翻译: 本发明是由具有下列通式的含氰基的酚醛树脂衍生的酚醛三嗪树脂制成的耐火制品及相关方法:其中:n是大于或等于1的正整数; q和r在每次出现时相同或不同,为0〜3的整数,条件是每次出现时q和r之和等于3; Z是-CN,或氢和-CN; o和p在每次出现时相同或不同,为0至4的整数,条件是每次出现时o和p之和等于4; -X-是二价有机基团; 并且R3在每次出现时相同或不同,并且是在完全固化共聚物所必需的条件下为非反应性的氢以外的取代基。

    Method for preparing tenacity and modulus polyacrylonitrile fiber
    10.
    发明授权
    Method for preparing tenacity and modulus polyacrylonitrile fiber 失效
    制备强度和模量聚丙烯腈纤维的方法

    公开(公告)号:US4883628A

    公开(公告)日:1989-11-28

    申请号:US910245

    申请日:1986-09-18

    IPC分类号: D01D5/00 D01F6/18

    CPC分类号: D01D5/00 D01F6/18

    摘要: Polyacrylonitrile (PAN) fibers are prepared by forming a 2-15 weight % solution of PAN of M.sub.w at least 500,000, extruding, cooling to below the gel temperature, extracting and drying. At least one of the gel fiber, the fiber containing extraction solvent and the dried gel is stretched. The product PAN fibers have a M.sub.w at least 500,000 (e.g. 1,000,000-4,000,000 or 1,500,000-2,500,000), a tenacity at least 5 g/den (e.g., at least 7 g/den) and a secant modulus at least 100 g/den (e.g. at least 125 g/den).

    摘要翻译: 通过形成Mw至少为500,000的2-15重量%的PAN溶液制备聚丙烯腈(PAN)纤维,挤出,冷却至低于凝胶温度,萃取和干燥。 将至少一种凝胶纤维,含纤维的提取溶剂和干燥的凝胶拉伸。 产品PAN纤维具有至少500,000(例如1,000,000-4,000,000或1,500,000-2,500,000)的Mw,至少5g / den(例如至少7g / den)的韧度和至少100g / den的割线模量 例如至少125g / den)。