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    Polymers made from polyhedral oligomeric silsesquioxanes acetylene-containing compounds
    4.
    发明授权
    Polymers made from polyhedral oligomeric silsesquioxanes acetylene-containing compounds 有权
    由多面体低聚倍半硅氧烷含乙炔的化合物制成的聚合物

    公开(公告)号：US08263727B1

    公开(公告)日：2012-09-11

    申请号：US13479386

    申请日：2012-05-24

    申请人： Manoj K. Kolel-Veetil ,  Teddy M Keller

    发明人： Manoj K. Kolel-Veetil ,  Teddy M Keller

    IPC分类号： C08G77/20

    CPC分类号： C08F238/02 ,  C08F230/08 ,  C08G77/04 ,  C08G77/50 ,  C08G77/52 ,  C08G77/60 ,  C09D183/14 ,  C09D183/16

    摘要： A compound having the formula below. Each R is methyl or phenyl; R2 comprises one or more of silane, siloxane, and aromatic groups; n is a nonnegative integer; and m is 1 or 2. The dashed bond is a single bond and the double dashed bond is a double bond, or the dashed bond is a double bond and the double dashed bond is a triple bond. A polymer made by a hydrosilation reaction of a polyhedral oligomeric silsesquioxane having pendant siloxane groups with an acetylene- and silicon-containing compound having at least two vinyl or ethynyl groups, and a crosslinked polymer thereof. The reaction occurs between the pendant siloxane groups and the vinyl or ethynyl groups.

    摘要翻译： 具有下式的化合物。 每个R是甲基或苯基; R2包括硅烷，硅氧烷和芳族基团中的一种或多种; n是非负整数; 并且m为1或2.虚线键为单键，双键键为双键，虚键为双键，双键键为三键。 通过具有侧硅氧烷基团的多面体低聚倍半硅氧烷与具有至少两个乙烯基或乙炔基的乙炔和含硅化合物及其交联聚合物的硅氢化反应制备的聚合物。 反应发生在侧链硅氧烷基团与乙烯基或乙炔基之间。

    Coating of organic fibers with siloxane-carborane polymers
    6.
    发明授权
    Coating of organic fibers with siloxane-carborane polymers 有权

    公开(公告)号：US07705100B2

    公开(公告)日：2010-04-27

    申请号：US11468367

    申请日：2006-08-30

    申请人： Teddy M Keller ,  Manoj K. Kolel-Veetil

    发明人： Teddy M Keller ,  Manoj K. Kolel-Veetil

    IPC分类号： C08G77/56

    CPC分类号： C08G77/56 ,  C07F7/081 ,  D01F11/14 ,  D06M11/77 ,  D06M11/79 ,  D06M11/80 ,  D06M15/227 ,  D06M15/643 ,  D06M15/647

    摘要： A fiber of linear polymer coated with a siloxane-carborane polymer or a thermoset or ceramic made therefrom. An organic fiber coated with a siloxane-carborane polymer or a thermoset or ceramic made therefrom and a surfactant. An organic fiber coated with a siloxane-carborane polymer made from a hydrosilation reaction of a siloxane-carborane compound containing at least two unsaturated carbon-carbon bonds and a silane compound or a thermoset or ceramic made therefrom. A method of coating a fiber by contacting a fiber to an aqueous solution of a siloxane-carborane polymer and a surfactant or to a solution of a siloxane-carborane polymer in a non-halogenated organic solvent. A method of contacting a fiber to a solution of a siloxane-carborane polymer, drying the coating to a temperature that does not change the polymer to a thermoset or ceramic, and using the dried, coated fiber in a process that requires that the fiber be flexible.

    Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions
    7.
    发明授权
    Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions 有权
    通过硅氢化反应合成弹性体碳硼烷 - 硅氧烷

    公开(公告)号：US07449535B2

    公开(公告)日：2008-11-11

    申请号：US11688317

    申请日：2007-03-20

    申请人： Teddy M Keller ,  Manoj K. Kolel-Veetil

    发明人： Teddy M Keller ,  Manoj K. Kolel-Veetil

    IPC分类号： C08G77/398

    CPC分类号： C08G77/48 ,  C08G77/56

    摘要： A carborane-siloxane compound is provided having the repeat unit Q contains any of —SiR2—, —SiR2—O—, —C≡C—C≡C—, carboranyl, and U′. Each R and R′ is alkyl, aryl, alkylaryl, haloalkyl, haloaryl, or mixtures thereof. Each U′ is derivable from hydrosilation of an alkenyl or alkynyl group. Each T is alkyl, aryl, alkylaryl, haloalkyl, haloaryl, mixtures thereof, —(O—SiR′2)xH, or the repeat unit. Each x and x′ is a positive integer. The compounds may be made be reacting a carborane-siloxane precursor having unsaturated end groups with a siloxane crosslinker in the presence of a hydrosilation catalyst.

    摘要翻译： 提供了碳硼烷 - 硅氧烷化合物，其具有重复单元Q包含-SiR 2 - ， - SiR 2 -O - ， - C≡C≡C-，碳硼烷基 ， 和你'。 每个R和R'是烷基，芳基，烷基芳基，卤代烷基，卤代芳基或其混合物。 每个U'可衍生自烯基或炔基的硅氢化。 每个T是烷基，芳基，烷基芳基，卤代烷基，卤代芳基，它们的混合物， - （O-SiR'2）x H或重复单元。 每个x和x'是一个正整数。 化合物可以在硅氢化催化剂存在下使具有不饱和端基的碳硼烷 - 硅氧烷前体与硅氧烷交联剂反应。

    Polymers made from polyhedral oligomeric silsesquioxanes and diacetylene-containing compounds
    9.
    发明授权
    Polymers made from polyhedral oligomeric silsesquioxanes and diacetylene-containing compounds 有权
    由多面体低聚倍半硅氧烷和含有乙炔的化合物制成的聚合物

    公开(公告)号：US08211994B2

    公开(公告)日：2012-07-03

    申请号：US13211347

    申请日：2011-08-17

    申请人： Manoj K. Kolel-Veetil ,  Teddy M Keller

    发明人： Manoj K. Kolel-Veetil ,  Teddy M Keller

    IPC分类号： C08G77/20

    CPC分类号： C08F238/02 ,  C08F230/08 ,  C08G77/04 ,  C08G77/50 ,  C08G77/52 ,  C08G77/60 ,  C09D183/14 ,  C09D183/16

    摘要： A compound having the formula. Each R is methyl or phenyl; R2 comprises one or more of silane, siloxane, and aromatic groups; n is a nonnegative integer; and m is 1 or 2. The dashed bond is a single bond and the double dashed bond is a double bond, or the dashed bond is a double bond and the double dashed bond is a triple bond. A polymer made by a hydrosilation reaction of a polyhedral oligomeric silsesquioxane having pendant siloxane groups with an acetylene- and silicon-containing compound having at least two vinyl or ethynyl groups, and a crosslinked polymer thereof. The reaction occurs between the pendant siloxane groups and the vinyl or ethynyl groups.

    摘要翻译： 具有下式的化合物。 每个R是甲基或苯基; R2包括硅烷，硅氧烷和芳族基团中的一种或多种; n是非负整数; 并且m为1或2.虚线键为单键，双键键为双键，虚键为双键，双键键为三键。 通过具有侧硅氧烷基团的多面体低聚倍半硅氧烷与具有至少两个乙烯基或乙炔基的乙炔和含硅化合物及其交联聚合物的硅氢化反应制备的聚合物。 反应发生在侧链硅氧烷基团与乙烯基或乙炔基之间。

    POLYARYLACETYLENES CONTAINING SILOXANE, SILANE, AND CARBORANE MOIETIES
    10.
    发明申请
    POLYARYLACETYLENES CONTAINING SILOXANE, SILANE, AND CARBORANE MOIETIES 有权
    含硅氧烷，硅烷和碳氢化合物的聚阴离子

    公开(公告)号：US20110306744A1

    公开(公告)日：2011-12-15

    申请号：US13157573

    申请日：2011-06-10

    申请人： Manoj K. Kolel-Veetil ,  Teddy M. Keller

    发明人： Manoj K. Kolel-Veetil ,  Teddy M. Keller

    IPC分类号： C08F130/08 ,  C07F7/08 ,  C07F5/02

    CPC分类号： C08G77/52 ,  C07F7/0838

    摘要： Disclosed herein are the compounds shown below. Each R is an organic group, Cb is a carborane group, and —C6H4— is phenylene. The value of each m is a nonnegative integer, q is 0 or 1, with the proviso that if q is 0 then m is 0 or 1, p is a positive integer, r is a positive integer, and n is an integer greater than or equal to 10. Also disclosed are methods of making and crosslinking the compounds. —{SiR2—([O]q—SiR2)m-[Cb-SiR2—([O]q—SiR2)m]p—C≡C—C6H4—C≡C}— —{SiR2—(O—SiR2)m—C≡C—C6H4—C≡C}n—; —{SiR2—([O]q—SiR2)m—[C≡C—C6H4—C≡C—SiR2—([O]q—SiR2)m]p-Cb-[SiR2—([O]q—SiR2)m-Cb]r}-

    摘要翻译： 本文公开的是下面所示的化合物。 每个R是有机基团，Cb是碳硼烷基团，-C6H4-是亚苯基。 每个m的值是非负整数，q是0或1，条件是如果q是0，那么m是0或1，p是正整数，r是正整数，n是大于 或等于10.还公开了制备和交联化合物的方法。 - {SiR 2 - （[O] q -SiR 2）m - [Cb-SiR 2 - （[O] q -SiR 2）m] p-C≡C-C 6 H 4-C≡C - {SiR 2 - （O-SiR 2 ）m-C≡C-C6H4-C≡C} n-; - {SiR 2 - （[O] q -SiR 2）m - [C≡C-C 6 H 4-C≡C-SiR 2 - （[O] q -SiR 2）m] p -C b - [SiR 2 - （[O] SiR2）m-Cb] r} -