公开(公告)号：US07220809B1

公开(公告)日：2007-05-22

申请号：US10654888

申请日：2003-09-05

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Yuzo Komatsu ,  Yoshito Ando

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Yuzo Komatsu ,  Yoshito Ando

IPC分类号： C08F16/24

CPC分类号： G02B1/04 ,  C08K3/10 ,  C08K5/0091 ,  C08L29/10 ,  C08L33/16 ,  H01S3/178

摘要： There is provided an optical material obtained from an organic composition which is suitable for an optical material in optical communication and comprises a fluorine-containing polymer having functional group and a rare earth metal ion, in which the fluorine-containing polymer having functional group has at least one ketone structure in its side chain and a maximum absorption coefficient of not more than 1 cm−1 in each wavelength range of from 1,290 to 1,320 nm, from 1,530 to 1,570 nm and from 600 to 900 nm and the rare earth metal ion is at least one selected from the group consisting of erbium (Er) ion, thulium (Tm) ion, praseodymium (Pr) ion, holmium (Ho) ion, neodymium (Nd) ion, europium (Eu) ion, dysprosium (Dy) ion, samarium (Sm) ion and cerium (Ce) ion.

摘要翻译： 提供了一种由有机组合物获得的光学材料，其适用于光学连接的光学材料，并且包括具有官能团的含氟聚合物和稀土金属离子，其中具有官能团的含氟聚合物具有 其侧链中的至少一个酮结构和在1,290至1,320nm，1,530至1,570nm和600至900nm的每个波长范围内的最大吸收系数不超过1cm -1 -1 稀土金属离子选自铒（Er）离子，ium（Tm）离子，镨（Pr）离子，钬（Ho）离子，钕（Nd）离子，铕（Eu） 离子，镝（Dy）离子，钐（Sm）离子和铈（Ce）离子。

公开(公告)号：US20050084231A1

公开(公告)日：2005-04-21

申请号：US10970650

申请日：2004-10-22

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Yoshito Ando ,  Yuzo Komatsu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Yoshito Ando ,  Yuzo Komatsu

IPC分类号： G02B6/00 ,  H01S3/17

CPC分类号： H01S3/17 ,  H01S3/178

摘要： There is provided an optical material which is an organic composition comprising a rare earth metal ion and a fluorine-containing polymer having functional group being capable of forming a complex with the rare earth metal ion and is suitable as an optical material for optical communication, in which the fluorine-containing polymer having functional group being capable of forming a complex with the rare earth metal ion has a side chain having at least two hetero-atoms in its structural unit and has a maximum absorption coefficient of not more than 1 cm−1 in each bandwidth of from 1,290 to 1,320 nm, from 1,530 to 1,570 nm and from 600 to 900 nm, and the rare earth metal ion is at least one selected from the group consisting of erbium (Er) ion, thulium (Tm) ion, praseodymium (Pr) ion, holmium (Ho) ion, neodymium (Nd) ion, europium (Eu) ion, dysprosium (Dy) ion, samarium (Sm) ion, cerium (Ce) ion and terbium (Tb) ion.

摘要翻译： 提供了一种光学材料，其是包含稀土金属离子的有机组合物和具有能够与稀土金属离子形成络合物的官能团的含氟聚合物，并且适合作为用于光学通信的光学材料， 具有能够与稀土金属离子形成络合物的官能团的含氟聚合物在其结构单元中具有至少两个杂原子的侧链，并且其最大吸收系数不大于1cm

公开(公告)号：US20060189788A1

公开(公告)日：2006-08-24

申请号：US10552684

申请日：2004-03-31

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Yuzo Komatsu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Yuzo Komatsu

IPC分类号： C08G65/34

CPC分类号： G02B6/1221 ,  C08F234/02 ,  C08G65/14 ,  C08G65/16 ,  C08L71/02 ,  C08L2205/05 ,  C09D145/00 ,  C08L2666/04

摘要： This invention provides a cyclic ether copolymer such as a cyclic ether copolymer excellent in solubility in solvents and easy to form uniform thin films therefrom. The present invention relates to a cyclic ether copolymer obtained from a 1,3-dioxole ring structure-containing compound represented by the following general formula (I) and an ethylenically unsaturated monomer: (wherein R1 and R2 are the same or different and each represents F, H, Cl or a perfluoroalkyl group containing 1 to 5 carbon atoms and X1 and X2 are the same or different and each represents F, H, Cl or —OR3, and R3 represents a perfluoroalkyl group containing 1 to 5 carbon atoms, provided that at least one of R1 and R2 is F or a perfluoroalkyl group containing 1 to 5 carbon atoms), which compolymer has a glass transition point of 100 to 135° C. and an intrinsic viscosity of 0.01 to 0.4 dl/g as determined at 35° C. in perfluoro-2-butyltetrahydrofuran.

摘要翻译： 本发明提供了一种环状醚共聚物，例如在溶剂中溶解性优异的环状醚共聚物，并且易于形成均匀的薄膜。 本发明涉及由以下通式（I）表示的含1,3-二氧杂环环结构的化合物和烯属不饱和单体（其中R 1和R 2）和R 2个相同或不同，各自表示F，H，Cl或含有1至5个碳原子的全氟烷基，X 1和X 2 2 >相同或不同，各自表示F，H，Cl或-OR 3，并且R 3表示含有1至5个碳原子的全氟烷基，条件是在 R 1和R 2中的至少一个为F或含有1至5个碳原子的全氟烷基），该共聚物的玻璃化转变点为100至135℃。 并且在35℃下在全氟-2-丁基四氢呋喃中测定的特性粘度为0.01至0.4dl / g。

公开(公告)号：US07262252B2

公开(公告)日：2007-08-28

申请号：US10704829

申请日：2003-11-12

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi ,  Yuzo Komatsu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi ,  Yuzo Komatsu

IPC分类号： F21V9/04 ,  C07D211/78 ,  C07D211/90 ,  C08F20/02 ,  C08F4/34 ,  C08F226/06 ,  C09K19/52

CPC分类号： G02F1/3615 ,  G02F1/3616 ,  G02F1/3617

摘要： There is provided a fluorine-containing resin composition which is used for nonlinear optical material and comprises (I) a fluorine-containing prepolymer and (II) an organic compound exhibiting a second- or higher-order nonlinear optical effect, in which the fluorine-containing prepolymer (I): (1) is a non-crystalline polymer having a fluorine content of not less than 25% and (2) has a carbon-carbon double bond in a polymer side chain or at an end of a polymer trunk chain and also there is provided a nonlinear optical waveguide device produced from the fluorine-containing resin composition. A suitable nonlinear optical material having a stable structure with a nonlinear substance is produced, and an excellent nonlinear optical waveguide device is produced by relatively simple steps while maintaining transparency in a near infrared region.

摘要翻译： 提供一种用于非线性光学材料的含氟树脂组合物，其包含（I）含氟预聚物和（II）表现出二级或更高级非线性光学效应的有机化合物，其中氟 - 含氟预聚物（I）：（1）是氟含量不小于25％的非结晶聚合物，（2）在聚合物侧链或聚合物主链的末端具有碳 - 碳双键 并且还提供了由含氟树脂组合物制造的非线性光波导器件。 产生具有非线性物质的稳定结构的合适的非线性光学材料，并且通过相对简单的步骤产生优异的非线性光波导器件，同时保持近红外区域的透明度。

公开(公告)号：US20050004253A1

公开(公告)日：2005-01-06

申请号：US10704829

申请日：2003-11-12

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi ,  Yuzo Komatsu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi ,  Yuzo Komatsu

IPC分类号： G02F1/361 ,  C08F2/46

CPC分类号： G02F1/3615 ,  G02F1/3616 ,  G02F1/3617

摘要： There is provided a fluorine-containing resin composition which is used for nonlinear optical material and comprises (I) a fluorine-containing prepolymer and (II) an organic compound exhibiting a second- or higher-order nonlinear optical effect, in which the fluorine-containing prepolymer (I): (1) is a non-crystalline polymer having a fluorine content of not less than 25% and (2) has a carbon-carbon double bond in a polymer side chain or at an end of a polymer trunk chain and also there is provided a nonlinear optical waveguide device produced from the fluorine-containing resin composition. A suitable nonlinear optical material having a stable structure with a nonlinear substance is produced, and an excellent nonlinear optical waveguide device is produced by relatively simple steps while maintaining transparency in a near infrared region.

摘要翻译： 提供一种用于非线性光学材料的含氟树脂组合物，其包含（I）含氟预聚物和（II）表现出二级或更高级非线性光学效应的有机化合物，其中氟 - 含氟预聚物（I）：（1）是氟含量不小于25％的非结晶聚合物，（2）在聚合物侧链或聚合物主链的末端具有碳 - 碳双键 并且还提供了由含氟树脂组合物制造的非线性光波导器件。 产生具有非线性物质的稳定结构的合适的非线性光学材料，并且通过相对简单的步骤产生优异的非线性光波导器件，同时保持近红外区域的透明度。

公开(公告)号：US07214470B2

公开(公告)日：2007-05-08

申请号：US10644953

申请日：2003-08-21

申请人： Takayuki Araki ,  Yuzo Komatsu ,  Meiten Koh

发明人： Takayuki Araki ,  Yuzo Komatsu ,  Meiten Koh

IPC分类号： G03F7/038

CPC分类号： G03F7/091 ,  C07C33/423 ,  C07C43/178 ,  C07C45/45 ,  C07C49/227 ,  C07C49/255 ,  C08F16/04 ,  C08F16/34 ,  C08F216/04 ,  G03F7/0046 ,  G03F7/0382 ,  G03F7/0392

摘要： There are provided a fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and represented by the formula (1): and the formula (14): respectively, wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, Cl or CF3; Rf1 and Rf2 are the same or different and each is a perfluoroalkyl group having 1 to 20 carbon atoms; Rf3 is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having ether bond which has 1 to 100 carbon atoms and the sum of carbon atom and oxygen atom of two or more; a is 0 or 1, a fluorine-containing polymer having a structural unit of the above-mentioned monomer and a composition for a photoresist. The monomer has good polymerizability, particularly radical polymerizability, and the polymer obtained by polymerizing the monomer has excellent optical characteristics and is useful as a base polymer for an antireflection film and for a composition for a resist.

摘要翻译： 提供具有羟基或氟代烷基羰基并由式（1）表示的含氟乙烯性单体：和式（14）：其中X 1和X 2 相同或不同，分别为H或F; X 3是H，F，Cl或CF 3; Rf 1和Rf 2相同或不同，各自为具有1至20个碳原子的全氟烷基; Rf 3是具有1〜40个碳原子的含氟亚烷基或具有1〜100个碳原子的醚键的含氟亚烷基，碳原子和氧原子之和为2 或者更多; a为0或1，具有上述单体的结构单元的含氟聚合物和光致抗蚀剂的组合物。 单体具有良好的聚合性，特别是自由基聚合性，通过聚合单体获得的聚合物具有优异的光学特性，可用作抗反射膜和抗蚀剂组合物的基础聚合物。

公开(公告)号：US20070172763A1

公开(公告)日：2007-07-26

申请号：US11727908

申请日：2007-03-29

申请人： Takayuki Araki ,  Yuzo Komatsu ,  Meiten Koh

发明人： Takayuki Araki ,  Yuzo Komatsu ,  Meiten Koh

IPC分类号： G03C1/00 ,  C08F12/20 ,  C07C43/17

CPC分类号： G03F7/091 ,  C07C33/423 ,  C07C43/178 ,  C07C45/45 ,  C07C49/227 ,  C07C49/255 ,  C08F16/04 ,  C08F16/34 ,  C08F216/04 ,  G03F7/0046 ,  G03F7/0382 ,  G03F7/0392

摘要： There are provided a fluorine-containing ethylenic monomer having hydroxyl group or fluoroalkyl carbonyl group and represented by the formula (1): and the formula (14): respectively, wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, Cl or CF3; Rf1 and Rf2 are the same or different and each is a perfluoroalkyl group having 1 to 20 carbon atoms; Rf3 is a fluorine-containing alkylene group having 1 to 40 carbon atoms or a fluorine-containing alkylene group having ether bond which has 1 to 100 carbon atoms and the sum of carbon atom and oxygen atom of two or more; a is 0 or 1, a fluorine-containing polymer having a structural unit of the above-mentioned monomer and a composition for a photoresist. The monomer has good polymerizability, particularly radical polymerizability, and the polymer obtained by polymerizing the monomer has excellent optical characteristics and is useful as a base polymer for an antireflection film and for a composition for a resist.

公开(公告)号：US07455934B1

公开(公告)日：2008-11-25

申请号：US09700185

申请日：1999-05-10

申请人： Takayuki Araki ,  Noritoshi Oka ,  Yoshito Tanaka ,  Takayuki Nakamura ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Noritoshi Oka ,  Yoshito Tanaka ,  Takayuki Nakamura ,  Tetsuo Shimizu

IPC分类号： H01M10/08

CPC分类号： H01S5/22 ,  C08J5/2237 ,  C08J2327/12 ,  G02B2006/12097 ,  G02B2006/12176 ,  H01B1/122 ,  H01M8/0289 ,  H01M8/1025 ,  H01M8/1039 ,  H01M8/1067 ,  H01S5/0655 ,  H01S5/20 ,  H01S5/2004 ,  H01S5/2213 ,  H01S5/2218 ,  H01S5/2227

摘要： The invention is a material for a solid polyelectrolyte, comprising a multi-segmented fluoropolymer that comprises a block copolymer and/or a graft copolymer, wherein the copolymer contains one or more blocks essentially consisting of segment A and one or more blocks essentially consisting of segment B, the segment A combines with the segment B, wherein the segment A has a molecular weight of 5,000 to 1,000.000, and the Segment A is a copolymer chain comprising (a) an ethylenicfluoromonomer containing sulfonic acid functional groups each represented by Formula (1) CX2═CX1—(O)n—Rf—SO2Y, wherein X and X1 may be the same or different and are each hydrogen or fluorine; Y is FI, Cl, or OY1 wherein y1 is hydrogen, alkali metal or C1-C5 alkyl; Rf is C1 to C40 divalent fluoroalkylene or C1 to C40 divalent fluoroalkylene having one or more ether bonds; and n is 0 or 1; and (b) at least one type of ethylenic fluoromonomer copolymerizable with the ethylenic fluoromonomer (a) and containing no sulfonic acid functional groups, the segment B is a fluoropolymer containing no sulfonic acid functional groups, has a molecular weight of 3,000 to 1,200,000, and has a crystalline melting point of 100° C. or higher or a glass transition point of 100° C. or higher, wherein the ratio of segment A:segment B in the segmented fluoropolymer is 5:9˜to 98:2 30:70 to 90:10 wt. %.

摘要翻译： 本发明是用于固体聚电解质的材料，其包含多段含氟聚合物，其包含嵌段共聚物和/或接枝共聚物，其中所述共聚物含有一个或多个基本上由片段A组成的嵌段和一个或多个基本上由片段 B，段A与段B结合，其中段A的分子量为5,000〜1,000.000，段A为共聚物链，其包含（a）含有各自由式（1）表示的磺酸官能团的烯键式氟单体， CX 2 - - - - - - - - - - - - - - - - - - - - - - - - - - - - （O） SUP> 1可以相同或不同，分别为氢或氟; Y是FI，Cl或OY 1，其中y 1是氢，碱金属或C 1 -C 5 烷基; Rf是C 1至C 40二价氟代亚烷基或C 1至C 40二价氟代亚烷基，其具有一个或多个醚 债券 并且n为0或1; 和（b）至少一种可与烯属含氟单体（a）共聚并且不含磺酸官能团的烯属含氟单体，段B是不含磺酸官能团的含氟聚合物，分子量为3,000至1,200,000， 具有100℃以上的结晶熔点或100℃以上的玻璃化转变温度，其中分段含氟聚合物中A段：B段的比例为5:9〜98:2 30:70 至90:10重量 ％。

公开(公告)号：US07670640B2

公开(公告)日：2010-03-02

申请号：US11226355

申请日：2005-09-15

申请人： Takayuki Araki ,  Mihoko Ohashi ,  Yoshito Tanaka ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Mihoko Ohashi ,  Yoshito Tanaka ,  Tetsuo Shimizu

IPC分类号： B05D5/06

CPC分类号： C09D127/12 ,  C08F8/00 ,  C08F8/14 ,  C08F16/32 ,  C08F214/18 ,  C08F290/04 ,  Y10T428/3154 ,  C08F14/18

摘要： There are provided a curable fluorine-containing polymer which can realize a high hardness by photo-curing while maintaining a low refractive index, an antireflection film possessing improved scratch resistance and abrasion resistance while maintaining a reflection reducing effect, and an antireflection-treated article provided with such an antireflection film. The curable fluorine-containing polymer has a number average molecular weight of from 500 to 1,000,000 and is represented by the formula (1): AM  (1) in which the structural unit M is a structural unit derived from a fluorine-containing ethylenic monomer and represented by the formula (M): wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, CH3 or CF3; X4 and X5 are the same or different and each is H, F or CF3; Rf is an organic group in which 1 to 3 of Y1 (Y1 is a monovalent organic group having 2 to 10 carbon atoms and an ethylenic carbon-carbon double bond at its end) are bonded to a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having 2 to 100 carbon atoms and ether bond; a is 0 or an integer of from 1 to 3; b and c are the same or different and each is 0 or 1, the structural unit A is a structural unit derived from a monomer copolymerizable with the fluorine-containing ethylenic monomer represented by the formula (M), and the structural unit M and the structural unit A are contained in amounts of from 0.1 to 100% by mole and from 0 to 99.9% by mole, respectively.

摘要翻译： 提供了一种可固化的含氟聚合物，其可以通过光固化同时保持低折射率实现高硬度，在保持反射降低效果的同时具有改善的耐擦伤性和耐磨性的抗反射膜，以及提供的抗反射处理制品 具有这样的抗反射膜。 可固化含氟聚合物的数均分子量为500〜1,000,000，由式（1）表示：AM（1）其中，结构单元M是来自含氟乙烯性单体的结构单元， 由式（M）表示：其中X1和X2相同或不同，各自为H或F; X3是H，F，CH3或CF3; X4和X5相同或不同，分别为H，F或CF 3; Rf为1〜3的Y1（Y1为碳原子数为2〜10的一价有机基团，末端为烯属碳 - 碳双键）的1〜3的有机基团与1〜40的含氟烷基 碳原子或碳原子数2〜100的含氟烷基和醚键; a为0或1〜3的整数; b和c相同或不同，分别为0或1，结构单元A是衍生自与式（M）表示的含氟乙烯性单体共聚的单体的结构单元，结构单元M和 结构单元A的含量分别为0.1至100摩尔％和0至99.9摩尔％。

公开(公告)号：USRE41110E1

公开(公告)日：2010-02-09

申请号：US11512391

申请日：2006-08-30

申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

IPC分类号： B32B27/00

CPC分类号： C08F214/262 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/2057 ,  Y10T428/1352

摘要： It is possible to provide the heat resistant material and coating material for OA equipment which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.

摘要翻译： 可以提供包含含氟多层聚合物的OA设备的耐热材料和涂层材料，其具有耐热性，耐磨性，对调色剂的不粘附性和耐油性以及柔性，并且特别用于 定影辊和皮带的表面。 这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％ 的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。