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    Process for producing fluorine-containing alkene
    1.
    发明授权
    Process for producing fluorine-containing alkene 有权
    含氟烯烃的制备方法

    公开(公告)号：US08865952B2

    公开(公告)日：2014-10-21

    申请号：US13575403

    申请日：2011-02-08

    申请人： Yuzo Komatsu ,  Daisuke Karube

    发明人： Yuzo Komatsu ,  Daisuke Karube

    IPC分类号： C07C17/25 ,  C07C19/08 ,  C07C21/18

    CPC分类号： C07C17/25 ,  Y02P20/582 ,  C07C21/18

    摘要： The present invention provides a process for producing fluorine-containing alkene represented by Formula (2): Rf1C(Rf2)=CH2 wherein Rf1 and Rf2 are the same or different, and are F, H, F(CF2)n- wherein n is an integer of 1 to 5, or H(CF2)m- wherein m is an integer of 1 to 5, with the proviso that Rf1 and Rf2 are not simultaneously H, by heating fluorine-containing alkane represented by Formula (1): Rf1CF(Rf2))CH3 wherein Rf1 and Rf2 are as defined above, in a gas phase to perform a dehydrofluorination reaction, the dehydrofluorination reaction being carried out in the presence of 5 mol or more of anhydrous hydrogen fluoride per mol of the fluorine-containing alkane. The process of the present invention can significantly enhance the selectivity of fluorine-containing alkene without reducing conversion in the production of fluorine-containing alkene from fluorine-containing alkane, such as fluorine-containing propane.

    摘要翻译： 本发明提供由式（2）表示的含氟烯烃的制造方法：Rf1C（Rf2）= CH2其中Rf1和Rf2相同或不同，为F，H，F（CF2）n-，其中n为 1〜5的整数，或H（CF 2）m - ，其中m为1〜5的整数，条件是通过加热由式（1）表示的含氟烷烃，Rf1和Rf2不同时为H：Rf1CF （Rf2））CH3，其中Rf1和Rf2如上定义，在气相中进行脱氟化氢反应，脱氟化氢反应在每摩尔含氟烷烃5摩尔或更多的无水氟化氢存在下进行 。 本发明的方法可以显着提高含氟烯烃的选择性，而不会在含氟烷烃如含氟丙烷生产含氟烯烃时降低转化率。

    PROCESS FOR PREPARING 2,3,3,3-TETRAFLUOROPROPENE
    2.
    发明申请
    PROCESS FOR PREPARING 2,3,3,3-TETRAFLUOROPROPENE 有权
    制备2,3,3,3-四氯丙烯的方法

    公开(公告)号：US20140121424A1

    公开(公告)日：2014-05-01

    申请号：US14127258

    申请日：2012-06-22

    申请人： Masatoshi Nose ,  Yuzo Komatsu

    发明人： Masatoshi Nose ,  Yuzo Komatsu

    IPC分类号： C07C17/20

    CPC分类号： C07C17/20 ,  C07C17/206 ,  C07C17/25 ,  C07C21/18 ,  C07C19/08

    摘要： The present invention provides a method for efficiently preparing 2,3,3,3-tetrafluoropropene (HFO-1234yf) by a simple and economically advantageous method that is suitable for implementation on an industrial scale. The present invention provides a process for preparing 2,3,3,3-tetrafluoropropene, comprising the step of: (1) in a reactor, (1-1) reacting 1,1,1,2,3-pentachloropropane with hydrogen fluoride in an amount of 10 to 100 mol per mole of the 1,1,1,2,3-pentachloropropane 1; (1-2) in the presence of chromic oxide represented by composition formula: CrOm (1.5

    摘要翻译： 本发明提供了一种通过简单且经济上有利的方法有效地制备2,3,3,3-四氟丙烯（HFO-1234yf）的方法，其适用于工业规模的实施。 本发明提供一种制备2,3,3,3-四氟丙烯的方法，包括以下步骤：（1）在反应器中，（1-1）使1,1,1,2,3-五氯丙烷与氟化氢 每摩尔1,1,1,2,3-五氯丙烷1为10-100摩尔量; （1-2），在由CrOm（1.5

    Nonlinear optical materials comprising fluorine-containing polymer
    4.
    发明授权
    Nonlinear optical materials comprising fluorine-containing polymer 有权
    包含含氟聚合物的非线性光学材料

    公开(公告)号：US07262252B2

    公开(公告)日：2007-08-28

    申请号：US10704829

    申请日：2003-11-12

    申请人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi ,  Yuzo Komatsu

    发明人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi ,  Yuzo Komatsu

    IPC分类号： F21V9/04 ,  C07D211/78 ,  C07D211/90 ,  C08F20/02 ,  C08F4/34 ,  C08F226/06 ,  C09K19/52

    CPC分类号： G02F1/3615 ,  G02F1/3616 ,  G02F1/3617

    摘要： There is provided a fluorine-containing resin composition which is used for nonlinear optical material and comprises (I) a fluorine-containing prepolymer and (II) an organic compound exhibiting a second- or higher-order nonlinear optical effect, in which the fluorine-containing prepolymer (I): (1) is a non-crystalline polymer having a fluorine content of not less than 25% and (2) has a carbon-carbon double bond in a polymer side chain or at an end of a polymer trunk chain and also there is provided a nonlinear optical waveguide device produced from the fluorine-containing resin composition. A suitable nonlinear optical material having a stable structure with a nonlinear substance is produced, and an excellent nonlinear optical waveguide device is produced by relatively simple steps while maintaining transparency in a near infrared region.

    摘要翻译： 提供一种用于非线性光学材料的含氟树脂组合物，其包含（I）含氟预聚物和（II）表现出二级或更高级非线性光学效应的有机化合物，其中氟 - 含氟预聚物（I）：（1）是氟含量不小于25％的非结晶聚合物，（2）在聚合物侧链或聚合物主链的末端具有碳 - 碳双键 并且还提供了由含氟树脂组合物制造的非线性光波导器件。 产生具有非线性物质的稳定结构的合适的非线性光学材料，并且通过相对简单的步骤产生优异的非线性光波导器件，同时保持近红外区域的透明度。

    Nonlinear optical materials comprising fluorine-containing polymer
    6.
    发明申请
    Nonlinear optical materials comprising fluorine-containing polymer 有权
    包含含氟聚合物的非线性光学材料

    公开(公告)号：US20050004253A1

    公开(公告)日：2005-01-06

    申请号：US10704829

    申请日：2003-11-12

    申请人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi ,  Yuzo Komatsu

    发明人： Takayuki Araki ,  Yoshito Tanaka ,  Mihoko Ohashi ,  Yuzo Komatsu

    IPC分类号： G02F1/361 ,  C08F2/46

    CPC分类号： G02F1/3615 ,  G02F1/3616 ,  G02F1/3617

    摘要： There is provided a fluorine-containing resin composition which is used for nonlinear optical material and comprises (I) a fluorine-containing prepolymer and (II) an organic compound exhibiting a second- or higher-order nonlinear optical effect, in which the fluorine-containing prepolymer (I): (1) is a non-crystalline polymer having a fluorine content of not less than 25% and (2) has a carbon-carbon double bond in a polymer side chain or at an end of a polymer trunk chain and also there is provided a nonlinear optical waveguide device produced from the fluorine-containing resin composition. A suitable nonlinear optical material having a stable structure with a nonlinear substance is produced, and an excellent nonlinear optical waveguide device is produced by relatively simple steps while maintaining transparency in a near infrared region.

    摘要翻译： 提供一种用于非线性光学材料的含氟树脂组合物，其包含（I）含氟预聚物和（II）表现出二级或更高级非线性光学效应的有机化合物，其中氟 - 含氟预聚物（I）：（1）是氟含量不小于25％的非结晶聚合物，（2）在聚合物侧链或聚合物主链的末端具有碳 - 碳双键 并且还提供了由含氟树脂组合物制造的非线性光波导器件。 产生具有非线性物质的稳定结构的合适的非线性光学材料，并且通过相对简单的步骤产生优异的非线性光波导器件，同时保持近红外区域的透明度。

    Process for production of fluorine-containing block copolymer
    7.
    发明授权
    Process for production of fluorine-containing block copolymer 有权
    含氟嵌段共聚物的制备方法

    公开(公告)号：US09127111B2

    公开(公告)日：2015-09-08

    申请号：US13384115

    申请日：2010-07-16

    申请人： Yuzo Komatsu ,  Kenichi Katsukawa ,  Haruhiko Mohri ,  Takashi Kanemura

    发明人： Yuzo Komatsu ,  Kenichi Katsukawa ,  Haruhiko Mohri ,  Takashi Kanemura

    IPC分类号： C08F259/08 ,  C08F214/22 ,  C08F293/00 ,  C08F214/26

    CPC分类号： C08F293/005 ,  C08F214/22 ,  C08F214/262 ,  C08F259/08 ,  C08F293/00 ,  C08J3/24 ,  C08J2327/22 ,  C08F214/28 ,  C08F214/26 ,  C08F216/1408

    摘要： Provided is a process for the production of a fluorine-containing block copolymer, which suppresses the formation of a homopolymer as a by-product and which, regardless of whether the chain transfer constant of the iodine end is large or small, achieves nearly 100% conversion into a block copolymer. The process is characterized by reacting (A) a fluorine-containing polymer which has an iodine atom or a bromine atom at either or both terminals of the backbone chain and/or at a side-chain terminal with (M) a radical-polymerizable monomer in the presence of (C) a sulfur compound represented by general formula (2): (Y1)nH2-nS2O4 (wherein Y1 is a mono- or di-valent metal ion or an ammonium ion; and n is an integer of 0 to 2).

    摘要翻译： 提供一种抑制作为副产物形成均聚物的含氟嵌段共聚物的方法，无论碘末端的链转移常数是大还是小，均可实现接近100％ 转化成嵌段共聚物。 该方法的特征在于：（A）在主链的一端或两端和/或侧链端具有碘原子或溴原子的含氟聚合物与（M）可自由基聚合单体 在（C）由通式（2）表示的硫化合物的存在下，（Y1）nH2-nS2O4（其中Y1是一价或二价金属离子或铵离子; n为0〜 2）。

    Process for producing 2,3,3,3-tetrafluoropropene
    8.
    发明授权
    Process for producing 2,3,3,3-tetrafluoropropene 有权
    制备2,3,3,3-四氟丙烯的方法

    公开(公告)号：US09040760B2

    公开(公告)日：2015-05-26

    申请号：US13879668

    申请日：2011-10-27

    申请人： Kazuhiro Takahashi ,  Yuzo Komatsu ,  Akinori Ueda

    发明人： Kazuhiro Takahashi ,  Yuzo Komatsu ,  Akinori Ueda

    IPC分类号： C07C17/25 ,  C07C17/20 ,  C07C17/087

    CPC分类号： C07C17/25 ,  C07C17/087 ,  C07C17/20 ,  C07C17/206 ,  C12Q1/686 ,  G01N21/6428 ,  G01N21/6486 ,  G01N2021/6439 ,  G01N2201/061 ,  Y02P20/582 ,  C07C21/18

    摘要： This invention provides a process for producing 2,3,3,3-tetrafluoropropene, the process comprising: (1) a first reaction step of reacting hydrogen fluoride with at least one chlorine-containing compound selected from the group consisting of a chloropropane represented by Formula (1): CClX2CHClCH2Cl, wherein each X is the same or different and is CI or F, a chloropropene represented by Formula (2): CClY2CCl═CH2, wherein each Y is the same or different and is CI or F, and a chloropropene represented by Formula (3): CZ2═CClCH2Cl, wherein each Z is the same or different and is CI or F in a gas phase in the absence of a catalyst while heating; and (2) a second reaction step of reacting hydrogen fluoride with a reaction product obtained in the first reaction step in a gas phase in the presence of a fluorination catalyst while heating. According to the process of this invention, 2,3,3,3-tetrafluoropropene (HFO-1234yf) can be obtained with high selectivity, and catalyst deterioration can be suppressed.

    摘要翻译： 本发明提供一种生产2,3,3,3-四氟丙烯的方法，该方法包括：（1）使氟化氢与至少一种选自以下的含氯化合物反应的第一反应步骤：选自由 式（1）：CClX 2 CHClCH 2 Cl，其中每个X相同或不同，为Cl或F，式（2）表示的氯丙烯：CClY 2 CCl = CH 2，其中每个Y相同或不同，为Cl或F， 由式（3）表示的氯丙烯：CZ2 = CClCH2Cl，其中每个Z相同或不同，并且在加热时不存在催化剂的气相中为Cl或F; 和（2）在加热下在氟化催化剂存在下，在气相中使氟化氢与第一反应步骤中得到的反应产物反应的第二反应步骤。 根据本发明的方法，可以高选择性地获得2,3,3,3-四氟丙烯（HFO-1234yf），并且可以抑制催化剂劣化。

    Process for producing fluorine-containing alkene compound
    9.
    发明授权
    Process for producing fluorine-containing alkene compound 有权
    含氟烯烃化合物的制备方法

    公开(公告)号：US08816140B2

    公开(公告)日：2014-08-26

    申请号：US13574921

    申请日：2011-02-08

    申请人： Daisuke Karube ,  Yuzo Komatsu ,  Atsushi Suzuki

    发明人： Daisuke Karube ,  Yuzo Komatsu ,  Atsushi Suzuki

    IPC分类号： C07C17/25 ,  C07C17/07 ,  C07C17/087

    CPC分类号： C07C17/21 ,  C07C17/25 ,  Y02P20/582 ,  C07C19/08 ,  C07C21/18

    摘要： The present invention provides a process for producing a fluorine-containing alkene of the general formula CF3(CX2)nCF═CH2, wherein X each independently represents F or Cl, and n is an integer of 0 to 2. The process includes a first reaction step of allowing a specific chlorine-containing compound to react with a fluorinating agent under increased pressure in a gas phase in the presence of at least one fluorination catalyst selected from the group consisting of chromium oxide and fluorinated chromium oxide, and a second reaction step of heating the product of the first reaction step in a gas phase under a pressure lower than the pressure in the first reaction step. The process of the present invention can produce a fluorine-containing alkene with a high selectivity with the use of a catalyst that can be easily handled, while suppressing production of by-products that cannot be easily converted into the target or separated.

    摘要翻译： 本发明提供通式CF 3（CX 2）n CF = CH 2的含氟烯烃的制造方法，其中X各自独立地表示F或Cl，n为0〜2的整数。该方法包括第一反应 在选自氧化铬和氟化氧化铬的至少一种氟化催化剂存在下，在气相中，在特定的含氯化合物与氟化剂在增压下反应的步骤，和第二反应步骤 在低于第一反应步骤中的压力的​​压力下，在气相中加热第一反应步骤的产物。 本发明的方法可以通过使用易于处理的催化剂，同时抑制不容易转化成靶或分离的副产物的产生而产生具有高选择性的含氟烯烃。

    Process for preparing 2,3,3,3-tetrafluoropropene
    10.
    发明授权
    Process for preparing 2,3,3,3-tetrafluoropropene 有权
    制备2,3,3,3-四氟丙烯的方法

    公开(公告)号：US08772554B2

    公开(公告)日：2014-07-08

    申请号：US14127258

    申请日：2012-06-22

    申请人： Masatoshi Nose ,  Yuzo Komatsu

    发明人： Masatoshi Nose ,  Yuzo Komatsu

    IPC分类号： C07C17/20 ,  C07C21/18

    CPC分类号： C07C17/20 ,  C07C17/206 ,  C07C17/25 ,  C07C21/18 ,  C07C19/08

    摘要： The present invention provides a method for efficiently preparing 2,3,3,3-tetrafluoropropene (HFO-1234yf) by a simple and economically advantageous method that is suitable for implementation on an industrial scale. The present invention provides a process for preparing 2,3,3,3-tetrafluoropropene, comprising the step of: (1) in a reactor, (1-1) reacting 1,1,1,2,3-penta-chloropropane with hydrogen fluoride in an amount of 10 to 100 mol per mole of the 1,1,1,2,3-pentachloropropane 1; (1-2) in the presence of chromic oxide represented by composition formula: CrOm (1.5

    摘要翻译： 本发明提供了一种通过简单且经济上有利的方法有效地制备2,3,3,3-四氟丙烯（HFO-1234yf）的方法，其适用于工业规模的实施。 本发明提供一种制备2,3,3,3-四氟丙烯的方法，包括以下步骤：（1）在反应器中，（1-1）使1,1,1,2,3-五氯丙烷与 每摩尔1,1,1,2,3-五氯丙烷1为10〜100摩尔的氟化氢; （1-2），在由CrOm（1.5