Abstract:
An alternating stack of insulator layers and spacer material layers is formed over a substrate. Stepped surfaces are formed in a contact region in which contact via structures are to be subsequently formed. An epitaxial semiconductor pedestal can be formed by a single epitaxial deposition process that is performed after formation of the stepped surfaces and prior to formation of memory openings, or a combination of a first epitaxial deposition process performed prior to formation of memory openings and a second epitaxial deposition process performed after formation of the memory openings. The epitaxial semiconductor pedestal can have a top surface that is located above a topmost surface of the alternating stack. The spacer material layers are formed as, or can be replaced with, electrically conductive layers. Backside contact via structures can be subsequently formed.
Abstract:
A monolithic three dimensional NAND string including a stack of alternating first material layers and second material layers different from the first material layers over a major surface of a substrate. The first material layers include a plurality of control gate electrodes and the second material layers include an insulating material and the plurality of control gate electrodes extend in a first direction. The NAND string also includes a semiconductor channel, a blocking dielectric, and a plurality of vertically spaced apart floating gates. Each of the plurality of vertically spaced apart floating gates or each of the second material layers includes a first portion having a first thickness in the second direction, and a second portion adjacent to the first portion in the first direction and having a second thickness in the second direction which is different than the first thickness.
Abstract:
A memory film and a semiconductor channel can be formed within each memory opening that extends through a stack including an alternating plurality of insulator layers and sacrificial material layers. After formation of backside recesses through removal of the sacrificial material layers selective to the insulator layers, a ruthenium portion can be formed in each backside recess, and a polycrystalline conductive material portion can be formed on each ruthenium portion. Each ruthenium portion can be employed in lieu of a tungsten seed layer to function as a lower resistivity seed layer that enables subsequent deposition of a polycrystalline conductive material. The resulting electrically conductive lines can have a lower resistivity than conductive lines of comparable dimensions that employ tungsten seed layers.
Abstract:
A first blocking dielectric layer is formed in a memory opening through a stack of an alternating plurality of material layers and insulator layers. A spacer with a bottom opening is formed over the first blocking dielectric layer by deposition of a conformal material layer and an anisotropic etch. A horizontal portion of the first blocking dielectric layer at a bottom of the memory opening can be etched by an isotropic etch process that minimizes overetch into the substrate. An optional additional blocking dielectric layer, at least one charge storage element, a tunneling dielectric, and a semiconductor channel can be sequentially formed in the memory opening to provide a three-dimensional memory stack.
Abstract:
A method of making a three dimensional NAND string includes providing a stack of alternating first material layers and second material layers over a substrate. The method further includes forming a front side opening in the stack, forming a tunnel dielectric in the front side opening, forming a semiconductor channel in the front side opening over the tunnel dielectric and forming a back side opening in the stack. The method also includes selectively removing the second material layers through the back side opening to form back side recesses between adjacent first material layers, forming a metal charge storage layer in the back side opening and in the back side recesses and forming discrete charge storage regions in the back side recesses by removing the metal charge storage layer from the back side opening and selectively recessing the metal charge storage layer in the back side recesses.
Abstract:
Fluorine-induced formation of voids and electrical shorts can be avoided by forming fluorine-free metal lines. Specifically, control gate electrodes of a three-dimensional memory device can be formed employing fluorine-free deposition processes. Fluorine-free tungsten nitride can be deposited as a metallic barrier liner employing atomic layer deposition. Fluorine-free tungsten nucleation layer can be subsequently deposited. Fluorine-free tungsten fill process can be employed to form the control gate electrodes. The fluorine-free control gate electrodes do not include fluorine therein, and thus, circumvents yield and reliability issues associated with residual fluorine that are present in fluorine-containing metal lines.
Abstract:
A method of making a monolithic three dimensional NAND string includes forming a stack of alternating first and second material layers over a substrate, etching the stack to form a front side opening, partially removing the second material layers through the front side opening to form front side recesses, forming a first blocking dielectric in the front side recesses, forming charge storage regions over the first blocking dielectric in the front side recesses, forming a tunnel dielectric layer and a semiconductor channel over the charge storage regions in the front side opening, etching the stack to form a back side opening, removing the second material layers through the back side opening to form back side recesses using the first blocking dielectric as an etch stop, forming a second blocking dielectric in the back side recesses, and forming control gates over the second blocking dielectric in the back side recesses.
Abstract:
A memory device and a method of making a memory device that includes a semiconductor channel, a tunnel dielectric layer located over the semiconductor channel, a floating gate located over the tunnel dielectric layer, the floating gate comprising a continuous layer of an electrically conductive material and at least one protrusion of an electrically conductive material facing the tunnel dielectric layer and electrically shorted to the continuous layer, a blocking dielectric region located over the floating gate, and a control gate located over the blocking dielectric layer.
Abstract:
Methods of making a monolithic three dimensional NAND string may enable selective removal of a blocking dielectric material, such as aluminum oxide, without otherwise damaging the device. Blocking dielectric may be selectively removed from the back side (e.g., slit trench) and/or front side (e.g., memory opening) of the NAND string. Also disclosed are NAND strings made in accordance with the embodiment methods.
Abstract:
A method of making a monolithic three dimensional NAND string includes providing a first stack of alternating first material layers and second material layers over a major surface of a substrate. The first material layers include first silicon oxide layers, the second material layers include second silicon oxide layers, and the first silicon oxide layers have a different etch rate from the second silicon oxide when exposed to the same etching medium. The first stack includes a back side opening, a front side opening, and at least a portion of a floating gate layer, a tunnel dielectric and a semiconductor channel located in the front side opening. The method also includes selectively removing the first material layers through the back side opening to form back side control gate recesses between adjacent second material layers.