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    Polycyclic, polyamides as precursors for energetic polycyclic polynitramine oxidizers
    3.
    发明授权
    Polycyclic, polyamides as precursors for energetic polycyclic polynitramine oxidizers 失效
    多环，聚酰胺作为能量多环多硝胺氧化剂的前体

    公开(公告)号：US07129348B1

    公开(公告)日：2006-10-31

    申请号：US07292028

    申请日：1988-12-21

    申请人： Robert B. Wardle ,  Jerald C. Hinshaw

    发明人： Robert B. Wardle ,  Jerald C. Hinshaw

    IPC分类号： C07D487/22 ,  C06B25/34

    CPC分类号： C06B25/34 ,  C07D487/22

    摘要： Hexabenzylhexaazaisowurtzitane is converted to tetracetyl, dibenzyl azaisowurtzitane. The benzyl groups are removed by catalytic transfer hydrogenolysis leaving a pair of available nitrogens. The available nitrogens are acetylated, and the resulting intermediate is converted to CL-20 with a strong nitrating agent.

    摘要翻译： 六苄基六氮杂异纤锌矿型结构烷烃转化为四乙酰基二氮杂异纤锌矿型结构烷烃。 通过催化转移氢解除去苄基，留下一对可用的氮。 可用的氮被乙酰化，所得中间体用强硝化剂转化成CL-20。

    Poly(butadiene)poly(lactone) thermoplastic block polymers, methods of making, and uncured high energy compositions containing same as binders
    4.
    发明授权
    Poly(butadiene)poly(lactone) thermoplastic block polymers, methods of making, and uncured high energy compositions containing same as binders 失效
    聚（丁二烯）聚（内酯）热塑性嵌段聚合物，制备方法以及含有与粘合剂相同的未固化的高能组合物

    公开(公告)号：US06350330B1

    公开(公告)日：2002-02-26

    申请号：US07616964

    申请日：1990-11-21

    申请人： Robert B. Wardle ,  Jerald C. Hinshaw

    发明人： Robert B. Wardle ,  Jerald C. Hinshaw

    IPC分类号： C06B2300

    CPC分类号： C06B45/10 ,  C06B21/005 ,  C08G63/00 ,  C08G81/027

    摘要： A thermoplastic, elastomeric block copolymer comprises at least one poly(butadiene) and at least one pair of poly(lactone) blocks flanking the poly(butadiene) block. Each poly(lactone) block is derived from a lactone having between 8 and 18 carbon atoms in the lactone ring, such as &lgr;-laurolactone and 10-hydroxyl decanoic acid lactone. Alternative methods of making these block polymers are also disclosed. In the first procedure diethyl zinc reacts with the hydroxyl end group of a butadiene polymer to form an intermediate zinc alkoxide-tipped polybutadiene which functions as the active initiating species. The laurolactone polymer then grows off the hydroxyl end groups of the butadiene to form the desired ABA block copolymer. In another related procedure for making ABA block polymers, previously prepared difunctional hydroxyl-terminated polybutadiene blocks are linked with monofunctional poly(&lgr;-laurolactone) blocks using a diisocyanate and a catalyst. The poly(&lgr;-laurolactone) is prepared from &lgr;-laurolactone, diethyl zinc and a suitable mono-functional alcohol. Another procedure describes the direct linking of hydroxyl-terminated poly(butadiene) with a poly(&lgr;-laurolactone) with a difunctional isocyanate producing a polymeric material having an (AB)n structure. Also disclosed are chemically uncured high-energy compositions, such as explosives, gasifiers, and especially solid rocket motor propellants, wherein between about 70-91 wt. % of solid particulates, including fuel material and/or oxidizer, and between about 9-30 wt. % of a binder system comprising a thermoplastic, elastomeric block copolymer system as above described and optionally a plasticizer.

    摘要翻译： 热塑性弹性体嵌段共聚物包含至少一种聚（丁二烯）和在聚（丁二烯）嵌段侧面的至少一对聚（内酯）嵌段。 每个聚（内酯）嵌段衍生自在内酯环中具有8至18个碳原子的内酯，例如丁内酯和10-羟基癸酸内酯。还公开了制备这些嵌段聚合物的替代方法。 在第一步骤中，二乙基锌与丁二烯聚合物的羟基端基反应，形成作为活性引发物质的中间体烷氧基烷氧基末端聚丁二烯。 然后，己内酯聚合物从丁二烯的羟基端基生长，形成所需的ABA嵌段共聚物。 在制备ABA嵌段聚合物的另一相关方法中，先前制备的双官能羟基封端的聚丁二烯嵌段与单官能聚（丁二醇 - 丁内酯）嵌段使用二异氰酸酯和催化剂连接。 聚（丁二醇 - 丁内酯）由羔羊脂酮，二乙基锌和合适的单官能醇制备。 另一个方法描述了羟基封端的聚（丁二烯）与聚（丁二醇）与双官能异氰酸酯的直接连接，产生具有（AB）n结构的聚合材料。还公开了化学未固化的高能组合物，例如 爆炸物，气化器，特别是固体火箭发动机推进剂，其中约70-91wt。 ％的固体颗粒，包括燃料和/或氧化剂，以及约9-30重量％ ％的粘合剂体系包含如上所述的热塑性弹性体嵌段共聚物体系和任选的增塑剂。

    Process for the large-scale synthesis of 4,10-dinitro-2,6,8-12-tetraoxa-4,10-diazatetracyclo-[5.5.0.05,903,11]-do decane
    5.
    发明授权
    Process for the large-scale synthesis of 4,10-dinitro-2,6,8-12-tetraoxa-4,10-diazatetracyclo-[5.5.0.05,903,11]-do decane 有权
    大规模合成4,10-二硝基-2,6,8-12-四氧杂-4,10-二氮杂四环[5.5.0.05,903,11] - 十二烷的方法

    公开(公告)号：US6107483A

    公开(公告)日：2000-08-22

    申请号：US362083

    申请日：1999-07-28

    申请人： Robert B. Wardle ,  Robert M. Hajik ,  Jerald C. Hinshaw ,  Thomas K. Highsmith

    发明人： Robert B. Wardle ,  Robert M. Hajik ,  Jerald C. Hinshaw ,  Thomas K. Highsmith

    IPC分类号： C07D267/02 ,  C07D498/22

    CPC分类号： C07D498/22

    摘要： A process for synthesizing 4,10-dinitro-2,6,8,12-tetraoxa-4,10-diazatetracyclo-[5.5.0.0.sup.5,9 0.sup.3,11 ]-dodecane ("TEX") involves combining at least one hexa-substituted piperazine derivative with a medium containing at least one nitronium anion source and at least one acid sufficiently strong to generate nitronium anions from the nitronium anion source. According to this invention, TEX yield is significantly improved by pre-heating the medium to 55.degree. C. to about 70.degree. C. and maintaining the medium from 55.degree. C. to about 70.degree. C. to permit the hexa-substituted piperazine derivative and nitronium anions to react and form the TEX. At least one NO.sub.x scavenger is added to the medium, preferably before the addition of the hexa-substituted piperazine derivative, to increase TEX yield.

    摘要翻译： 合成4,10-二硝基-2,6,8,12-四氧杂-4,10-二氮杂四环[5.5.0.05,903,11] - 十二烷（“TEX”）的方法涉及将至少一种六取代 哌嗪衍生物与含有至少一个硝鎓阴离子源的介质和至少一种足够强的酸从硝鎓阴离子源产生硝鎓阴离子。 根据本发明，通过将培养基预加热至55℃至约70℃，并将培养基保持在55℃至约70℃，可显着改善TEX产率，以允许六取代的哌嗪衍生物 和硝酸根阴离子反应并形成TEX。 向培养基中加入至少一种NO x清除剂，优选在加入六取代的哌嗪衍生物之前，以提高TEX产率。

    Propellant formulations based on dinitramide salts and energetic binders
    6.
    发明授权
    Propellant formulations based on dinitramide salts and energetic binders 失效
    基于二硝酸盐和高能粘合剂的推进剂配方

    公开(公告)号：US5741998A

    公开(公告)日：1998-04-21

    申请号：US614303

    申请日：1996-03-12

    申请人： Carol J. Hinshaw ,  Robert B. Wardle ,  Tom K. Highsmith

    发明人： Carol J. Hinshaw ,  Robert B. Wardle ,  Tom K. Highsmith

    IPC分类号： C06B33/08 ,  C06B25/34 ,  C06B31/00 ,  C06B45/10 ,  C06D5/00

    CPC分类号： C06B31/00 ,  C06B25/34 ,  C06B45/105

    摘要： Composite propellant formulations are disclosed having a dinitramide salt oxidizer, such as ammonium dinitramide, an energetic binder, such as energetically substituted oxetane and oxirane polymers, a reactive metal, such as aluminum, and other typical propellant ingredients such as curatives and stabilizers. Propellant formulations useful for minimum smoke or reduced smoke applications, preferably include little or no reactive metal. The disclosed propellant formulations are able to combust the reactive metal efficiently, possess high burn rates, and produce little or no HCl exhaust gases.

    摘要翻译： 公开了具有二硝酸盐盐氧化剂如二硝化铵铵，能量粘合剂如能量取代的氧杂环丁烷和环氧乙烷聚合物，活性金属如铝和其它典型的推进剂成分如固化剂和稳定剂的复合推进剂配方。 用于最小烟雾或减少烟雾应用的推进剂制剂优选包括很少或没有活性金属。 所公开的推进剂制剂能够有效地燃烧活性金属，具有高燃烧速率，并且产生很少或不产生HCl废气。

    High performance pressable explosive compositions
    9.
    发明授权
    High performance pressable explosive compositions 失效
    高性能可加压炸药组合物

    公开(公告)号：US5587553A

    公开(公告)日：1996-12-24

    申请号：US335097

    申请日：1994-11-07

    申请人： Paul C. Braithwaite ,  Gary K. Lund ,  Robert B. Wardle

    发明人： Paul C. Braithwaite ,  Gary K. Lund ,  Robert B. Wardle

    IPC分类号： C06B21/00 ,  C06B45/10

    CPC分类号： C06B45/105 ,  C06B21/0025

    摘要： High solids pressable explosive compositions containing a liquid energetic polymer and a high performance explosive oxidizer are disclosed. The pressable explosive compositions contain a solids content between 91 and 99 weight percent, with an energetic polymer content less than 9 weight percent. The energetic polymer has a weight average molecular weight greater than 10,000, determined using a polystyrene standard, sufficient to use the polymer precipitation technique in preparing the pressable explosive compositions. Chain-extended PGN (polyglycidyl nitrate) is a preferred energetic polymer. The pressable explosives disclosed herein produce extremely high detonation pressure, high detonation velocity, and excellent metal accelerating capability.

    摘要翻译： 公开了含有液体高分子聚合物和高性能炸药氧化剂的高固体可压制的爆炸性组合物。 可压制的炸药组合物含有91至99重量％的固体含量，高分子聚合物含量低于9重量％。 能量聚合物的重均分子量大于10,000，使用聚苯乙烯标准测定，足以在制备可挤压的炸药组合物时使用聚合物沉淀技术。 链延长的PGN（聚缩水甘油基硝酸酯）是优选的能量聚合物。 本文公开的可压式爆炸物产生极高的爆震压力，高爆震速度和极好的金属加速能力。

    Method of producing thermoplastic elastomers having alternate crystalline structure such as polyoxetane ABA or star block copolymers by a block linking process
    10.
    发明授权
    Method of producing thermoplastic elastomers having alternate crystalline structure such as polyoxetane ABA or star block copolymers by a block linking process 失效
    具有交替结晶结构的热塑性弹性体如聚氧杂环丁烷ABA或通过嵌段连接方法的星形嵌段共聚物的方法

    公开(公告)号：US5516854A

    公开(公告)日：1996-05-14

    申请号：US559179

    申请日：1990-07-27

    申请人： Robert B. Wardle ,  W. Wayne Edwards ,  Jerald C. Hinshaw

    发明人： Robert B. Wardle ,  W. Wayne Edwards ,  Jerald C. Hinshaw

    IPC分类号： C08G18/10 ,  C08G18/28 ,  C08G65/18 ,  C08G65/22 ,  C08G65/28 ,  C08G18/12 ,  C08G65/04

    CPC分类号： C08G65/22 ,  C08G18/10 ,  C08G18/283 ,  C08G18/285 ,  C08G18/2885 ,  C08G65/18 ,  C08G2250/00

    摘要： A method of preparing a thermoplastic elastomer having A blocks and at least one B block, wherein said A blocks are crystalline at temperatures below about 60.degree. C. and said B block is amorphous at temperatures above about -20.degree. C., said A blocks each being polyethers derived from monomers of oxetane and its derivatives and/or tetrahydrofuran and its derivatives, the method comprising:providing monofunctional hydroxyl terminated A blocks which are crystalline at temperatures below about 60.degree. C. and separately providing di-, tri- or tetrafunctional hydroxyl terminated B blocks which are amorphous at temperatures above about -20.degree. C.,end-capping said A blocks by separately reacting said A blocks with a difunctional diisocyanate in which one isocyanate moiety is at least about five times as reactive with the terminal hydroxyl group of the A blocks as the other isocyanate moiety, whereby the more reactive isocyanate moiety tends to react with the terminal hydroxyl group of the A blocks, leaving the less reactive isocyanate moiety free and unreacted, andadding di-, tri- or tetrafunctional B block to the end-capped A blocks at approximately the stoichiometric ratios that they are intended to be present in the thermoplastic elastomer such that the free and unreacted isocyanate moiety on the end-capped A block reacts with a functional moiety of the B block to produce ABA or A.sub.n B thermoplastic elastomers.

    摘要翻译： 一种制备具有A嵌段和至少一个B嵌段的热塑性弹性体的方法，其中所述A嵌段在低于约60℃的温度下是结晶的，并且所述B嵌段在高于约-20℃的温度下是无定形的，所述A嵌段 各自为衍生自氧杂环丁烷及其衍生物和/或四氢呋喃及其衍生物的单体的聚醚，所述方法包括：提供在低于约60℃的温度下为结晶的单官能羟基封端的A嵌段，并分别提供二 - ，三 - 或四官能 羟基封端的B嵌段，其在高于约-20℃的温度下是无定形的，通过将所述A嵌段与双官能二异氰酸酯分开反应来封端所述A嵌段，其中一个异氰酸酯部分与末端羟基反应的至少约五倍 一组A嵌段作为另一异氰酸酯部分，由此更多的反应性异氰酸酯部分倾向于与A b的末端羟基反应 锁定，使较少反应性的异氰酸酯部分游离并未反应，并以其预期存在于热塑性弹性体中的化学计量比近似地将末端封端的A嵌段加入二官能，三官能或四官能团B嵌段， 并且封端的A嵌段上的未反应的异氰酸酯部分与B嵌段的官能部分反应以产生ABA或AnB热塑性弹性体。