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    Aryl and heteroarylcyclopropyl oxime ethers and their use as fungicides
    1.
    发明授权
    Aryl and heteroarylcyclopropyl oxime ethers and their use as fungicides 失效
    芳基和杂芳基环丙基肟醚及其作为杀真菌剂的用途

    公开(公告)号：US06348627B1

    公开(公告)日：2002-02-19

    申请号：US09572487

    申请日：2000-05-15

    申请人： Ronald Ross, Jr. ,  Duyan Vuong Nguyen ,  Edward Michael Szapacs ,  Frisby Davis Smith ,  Steven Howard Shaber

    发明人： Ronald Ross, Jr. ,  Duyan Vuong Nguyen ,  Edward Michael Szapacs ,  Frisby Davis Smith ,  Steven Howard Shaber

    IPC分类号： C07C23305

    CPC分类号： C07D213/53 ,  A01N37/36 ,  A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/40 ,  A01N43/42 ,  A01N43/50 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N43/60 ,  A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  A01N53/00 ,  C07C251/60 ,  C07C2601/02 ,  C07C2602/02 ,  C07D213/62 ,  C07D215/12 ,  C07D231/12 ,  C07D233/64 ,  C07D237/08 ,  C07D239/26 ,  C07D239/34 ,  C07D241/12 ,  C07D261/08 ,  C07D263/32 ,  C07D275/02 ,  C07D277/28 ,  C07D307/52 ,  C07D307/56 ,  C07D333/22

    摘要： Compounds with fungicidal and insecticidal properties having formula wherein X is N or CH; Z is O, S or NR8; A is hydrogen, halo, cyano, (C1-C12)alkyl, or (C1-C12)alkoxy; R1 and R8 are independently hydrogen or (C1-C4)alkyl; R2 is hydrogen, (C1-C12)alkyl, halo(C1-C12)alkyl, (C3-C7)cycloalkyl, halo(C3-C7)cycloalkyl, (C2-C8)alkenyl, halo(C2-C8)alkenyl, (C2-C8)alkynyl, halo(C2-C8)alkynyl, aryl, aralkyl, heterocyclic, heterocyclic(C1-C4)alkyl or C(R10)═N—OR9; R3 is hydrogen, (C1-C12)alkyl, halo(C1-C12)alkyl, (C3-C7)cycloalkyl, halo(C3-C7)cycloalkyl, (C2-C8)alkenyl, halo(C2-C8)alkenyl, (C2-C8)alkynyl, halo(C2-C8)alkynyl, aryl, aralkyl, aryl(C3-C7)cycloalkyl, heterocyclic or heterocyclic(C1-C4)alkyl; R4 and R5 are independently hydrogen, (C1-C12)alkyl, halo(C1-C12)alkyl, (C3-C7)cycloalkyl, halo(C3-C7)cycloalkyl, (C2-C8)alkenyl, halo(C2-C8)alkenyl, (C2-C8)alkynyl, halo(C2-C8)alkynyl, halo, cyano, (C1-C4)alkoxycarbonyl, aryl, aralkyl, aryl(C3-C7)cycloalkyl, heterocyclic or heterocyclic(C1-C4)alkyl; R6 is hydrogen, (C1-C12)alkyl, halo(C1-C12)alkyl, (C3-C7)cycloalkyl, halo(C3-C7)cycloalkyl, (C2-C8)alkenyl, halo(C2-C8)alkenyl, (C2-C8)alkynyl, halo(C2-C8)alkynyl, halo, cyano, (C1-C4)alkoxycarbonyl, aryl, aralkyl, aryl(C3-C7)cycloalkyl, heterocyclic or heterocyclic(C1-C4)alkyl; R7 is aryl, aralkyl, heterocyclic or heterocyclic(C1-C4)alkyl; R9 is hydrogen, (C1-C12)alkyl, halo(C1-C12)alkyl, (C2-C8)alkenyl, halo(C2-C8)alkenyl, (C2-C8)alkynyl, halo(C2-C8)alkynyl, (C1-C4)alkylcarbonyl, (C1-C4)alkoxycarbonyl, aryl, or aralkyl; and R10 is hydrogen, (C1-C12)alkyl, halo(C1-C12)alkyl, (C3-C7)cycloalkyl, halo(C3-C7)cycloalkyl, (C2-C8)alkenyl, halo(C2-C8)alkenyl, (C2-C8)alkynyl, halo(C2-C8)alkynyl, aryl, aralkyl, heterocyclic, or heterocyclic(C1-C4)alkyl.

    摘要翻译： 具有杀虫和杀虫性质的化合物，其具有式（X）的化合物是N或CH; Z是O，S或NR8; A是氢，卤素，氰基，（C 1 -C 12）烷基或（C 1 -C 12）烷氧基; R1和R8独立地是氢或（C1-C4）烷基; （C 1 -C 12）烷基，（C 3 -C 7）环烷基，卤代（C 3 -C 7）环烷基，（C 2 -C 8）烯基，卤代（C 2 -C 8） C 2 -C 8炔基，卤代（C 2 -C 8）炔基，芳基，芳烷基，杂环，杂环（C 1 -C 4）烷基或C（R 10）= N-OR 9; （C 1 -C 12）烷基，（C 3 -C 7）环烷基，卤代（C 3 -C 7）环烷基，（C 2 -C 8）烯基，卤代（C 2 -C 8） C 2 -C 8）炔基，卤代（C 2 -C 8）炔基，芳基，芳烷基，芳基（C 3 -C 7）环烷基，杂环或杂环（C 1 -C 4） （C 1 -C 12）烷基，（C 3 -C 7）环烷基，卤代（C 3 -C 7）环烷基，（C 2 -C 8）烯基，卤代（C 2 -C 8） 烯基，（C 2 -C 8）炔基，卤代（C 2 -C 8）炔基，卤素，氰基，（C 1 -C 6）

    Dihydropyridazinones and pyridazinones and their use as fungicides and insecticides
    5.
    发明授权
    Dihydropyridazinones and pyridazinones and their use as fungicides and insecticides 失效
    二氢哒嗪酮和哒嗪酮及其作为杀真菌剂和杀虫剂的用途

    公开(公告)号：US6121251A

    公开(公告)日：2000-09-19

    申请号：US938552

    申请日：1997-09-26

    申请人： Steven Howard Shaber ,  Edward Michael Szapacs ,  Ronald Ross

    发明人： Steven Howard Shaber ,  Edward Michael Szapacs ,  Ronald Ross

    IPC分类号： A01N43/58 ,  A01N47/24 ,  A01N55/10 ,  C07D237/04 ,  C07D237/14 ,  C07F9/6509 ,  C07D237/16

    CPC分类号： C07D237/04 ,  A01N47/24 ,  C07D237/14 ,  C07F9/650911

    摘要： Compounds with fungicidal and insecticidal properties having formula I ##STR1## wherein W is ##STR2## n is 0 or 1; Y is O, S, NR.sub.1, or R.sub.6 ;the ring bond containing R.sub.4 and R.sub.5 is a single or double bond;X is independently selected from hydrogen, halo, (C.sub.1 -C.sub.4)alkyl, (C.sub.1 -C.sub.4)alkoxy and --HC.dbd.CH--CH.dbd.CH-- thereby forming a napthyl ring;R is independently selected from (C.sub.1 -C.sub.12)alkyl and halo(C.sub.1 -C.sub.12)alkyl;R.sub.1 is independently selected from (C.sub.1 -C.sub.12)alkyl, (C.sub.2 -C.sub.8)alkenyl and aryl;R.sub.2 is independently selected from hydrogen, (C.sub.1 -C.sub.12)alkyl (C.sub.1 -C.sub.12)alkoxy, halo(C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkoxy, hydroxy(C.sub.1 -C.sub.12)alkyl, (C.sub.1 -C.sub.12)alkoxy(C.sub.1 -C.sub.12)alkyl, (C.sub.1 -C.sub.12)alkoxycarbonyl(C.sub.1 -C.sub.12)alkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.3 -C.sub.10)alkynyl, halo(C.sub.3 -C.sub.10)alkynyl, (C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.1 -C.sub.4)alkyl, epoxy(C.sub.1 -C.sub.12)alkyl, PO(OR.sub.1).sub.2 (C.sub.1 -C.sub.12)alkyl, R.sub.1 S(O).sub.2 (C.sub.1 -C.sub.12)alkyl, (R.sub.1).sub.3 Si(C.sub.1 -C.sub.12)alkyl, aryl, aryloxy(C.sub.1 -C.sub.12)alkyl, arylcarbonyl(C.sub.1 -C.sub.12)alkyl, aralkyl, arylalkenyl, heterocyclic, heterocyclic (C.sub.1 -C.sub.12)alkyl, N-morpholino(C.sub.1 -C.sub.12)alkyl, N-piperidinyl(C.sub.1 -C.sub.12)alkyl;R.sub.4, and R.sub.5 are independently selected from hydrogen, halo, (C.sub.1 -C.sub.8)alkyl, (C.sub.1 -C.sub.8)alkoxy, cyano, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.2 -C.sub.8)alkenyl, (C.sub.3 -C.sub.10)alkynyl, aryl and aralkyl; andR.sub.6 is (C.sub.1 -C.sub.12) alkylenyl and (C.sub.2 -C.sub.12)alkenylenyl.

    摘要翻译： 具有式I的具有杀真菌性和杀虫性的化合物，其中W是n是0或1; Y是O，S，NR1或R6; 含有R 4和R 5的环键是单键或双键; X独立地选自氢，卤素，（C 1 -C 4）烷基，（C 1 -C 4）烷氧基和-HC = CH-CH = CH-，从而形成萘基环; R独立地选自（C 1 -C 12）烷基和卤代（C 1 -C 12）烷基; R 1独立地选自（C 1 -C 12）烷基，（C 2 -C 8）烯基和芳基; R2是独立选自氢，（C1-C12）烷基（C1-C12）烷氧基，卤代（C1-C12）烷基，卤代（C1-C12）烷氧基，羟基（C1-C12）烷基，（C1-C12）烷氧基 （C1-C12）烷基，（C1-C12）烷氧基羰基（C1-C12）烷基，（C2-C8）烯基，卤代（C2-C8）烯基，（C3-C10）炔基，卤代（C3-C10）炔基， （C 3 -C 7）环烷基，（C 3 -C 7）环烷基（C 1 -C 4）烷基，环氧（C 1 -C 12）烷基，PO（OR 1）2（C 1 -C 12）烷基， 烷基，（R1）3Si（C1-C12）烷基，芳基，芳氧基（C1-C12）烷基，芳基羰基（C1-C12）烷基，芳烷基，芳基烯基，杂环，杂环（C1-C12）烷基，N-吗啉代 -C 12）烷基，N-哌啶基（C 1 -C 12）烷基; （C 1 -C 8）烷氧基，氰基，卤代（C 1 -C 12）烷基，（C 2 -C 8）烯基，（C 3 -C 10）炔基， 芳基和芳烷基; 并且R 6是（C 1 -C 12）亚烷基和（C 2 -C 12）烯基。

    Benzyloxy substituted aromatics and their use as fungicides and insecticides
    7.
    发明授权
    Benzyloxy substituted aromatics and their use as fungicides and insecticides 失效

    公开(公告)号：US5945557A

    公开(公告)日：1999-08-31

    申请号：US102713

    申请日：1998-06-23

    申请人： Ronald Ross ,  Ted Tsutomu Fujimoto ,  Steven Howard Shaber

    发明人： Ronald Ross ,  Ted Tsutomu Fujimoto ,  Steven Howard Shaber

    IPC分类号： A01N37/38 ,  A01N37/42 ,  A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/40 ,  A01N43/54 ,  C07C69/734 ,  C07C69/736 ,  C07C69/738 ,  C07C69/743 ,  C07C69/757 ,  C07C251/44 ,  C07C251/48 ,  C07C255/46 ,  C07D213/30 ,  C07D213/50 ,  C07D213/55 ,  C07D213/57 ,  C07D239/26 ,  C07D307/42 ,  C07D307/46 ,  C07D333/16 ,  C07D333/22 ,  C07C69/76 ,  C07C233/00

    CPC分类号： C07D213/30 ,  A01N37/38 ,  A01N37/50 ,  C07C251/44 ,  C07C251/48 ,  C07C255/46 ,  C07C69/736 ,  C07C69/757 ,  C07D213/50 ,  C07D239/26 ,  C07D307/42 ,  C07D307/46 ,  C07D333/16 ,  C07D333/22 ,  C07C2101/02

    摘要： Compounds with fungicidal and insecticidal properties having formula ##STR1## wherein A is N or CH; V is O or NH; m and n are the integers 0 and 1, provided that m+n is 0 or 1;X is independently selected from hydrogen, halo, (C.sub.1 -C.sub.4)alkyl, and (C.sub.1 -C.sub.4)alkoxy;R is independently selected from hydrogen, (C.sub.1 -C.sub.12)alkyl, (C.sub.1 -C.sub.12)alkoxy, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.2 -C.sub.12)alkenyl, (C.sub.2 -C.sub.12)alkynyl, (C.sub.1 -C.sub.12)alkoxy(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.2 -C.sub.12)alkenyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.2 -C.sub.12)alkynyl, (C.sub.1 -C.sub.12)alkyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.1 -C.sub.12)alkoxy(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.1 -C.sub.12)alkoxy(C.sub.1 -C.sub.12)alkyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.12)alkenyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.12)alkynyl(C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.1 -C.sub.12)alkyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.1 -C.sub.12)alkoxy(C.sub.2 -C.sub.12)alkenyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.1 -C.sub.12)alkoxy(C.sub.2 -C.sub.12)alkynyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.1 -C.sub.12)alkyl(C.sub.3 -C.sub.7)cycloalkyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.12)alkenyl(C.sub.3 -C.sub.7)cycloalkyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.12)alkynyl(C.sub.3 -C.sub.7)cycloalkyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.1 -C.sub.12)alkyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.2 -C.sub.12)alkenyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.2 -C.sub.12)alkynyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.1 -C.sub.12)alkoxy(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.1 -C.sub.12)alkoxy(C.sub.1 -C.sub.12)alkyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.1 -C.sub.12)alkoxy(C.sub.1 -C.sub.12)alkenyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkyl(C.sub.1 -C.sub.12)alkoxy(C.sub.1 -C.sub.12)alkynyl(C.sub.3 -C.sub.7)cycloalkyl, aryl, aralkyl, aryl(C.sub.3 -C.sub.7)cycloalkyl, aryl(C.sub.3 -C.sub.7)cycloalkyl(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.3 -C.sub.7)cycloalkylaryl, aryl(C.sub.1 -C.sub.4)alkyl(C.sub.3 -C.sub.7)cycloalkyl, heterocyclic, aryl(C.sub.1 -C.sub.4)alkylheterocyclic heterocyclic(C.sub.1 -C.sub.4)alkyl, heterocyclic(C.sub.3 -C.sub.7)cycloalkyl andR.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from hydrogen, halogen, (C.sub.1 -C.sub.12)alkyl, (C.sub.1 -C.sub.12)alkoxy, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.2 -C.sub.12)alkenyl, (C.sub.2 -C.sub.12)alkynyl, (C.sub.3 -C.sub.7)cycloalkyl, cyano, carboxy, (C.sub.1 -C.sub.4)alkoxycarbonyl, aryl, and when taken together R.sub.2 and R.sub.3 form a (C.sub.3 -C.sub.7)cycloalkyl ring, provided that when n=0 or 1 and m=0 R and R.sub.1 are not both hydrogen and when A is N and V is NH and n and m are both zero than R, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are other than 1 to 3 substituents independently selected from halogen and (C.sub.1 -C.sub.4)alkyl.

    Aryl and heteroarylcyclopropyl oxime ethers and their use as fungicides and insecticides
    10.
    发明授权
    Aryl and heteroarylcyclopropyl oxime ethers and their use as fungicides and insecticides 失效

    公开(公告)号：US6063956A

    公开(公告)日：2000-05-16

    申请号：US238196

    申请日：1999-01-27

    申请人： Ronald Ross ,  Steven Howard Shaber ,  Duyan Vuong Nguyen

    发明人： Ronald Ross ,  Steven Howard Shaber ,  Duyan Vuong Nguyen

    IPC分类号： A01N37/10 ,  A01N37/18 ,  A01N37/36 ,  A01N37/38 ,  A01N37/50 ,  A01N43/06 ,  A01N43/08 ,  A01N43/10 ,  A01N43/40 ,  A01N43/60 ,  A01N47/42 ,  C07C251/60 ,  C07D213/53 ,  C07D215/12 ,  C07D239/26 ,  C07D241/12 ,  C07D307/52 ,  C07D333/22 ,  C07D401/08 ,  C07D403/08 ,  C07D405/08 ,  C07D409/08 ,  C07C229/00 ,  A01N53/00 ,  C07C233/00 ,  C07C249/00 ,  C07C327/00

    CPC分类号： C07D213/53 ,  A01N37/36 ,  A01N37/38 ,  A01N37/50 ,  A01N43/06 ,  A01N43/40 ,  C07C251/60 ,  C07D215/12 ,  C07D239/26 ,  C07D241/12 ,  C07D307/52 ,  C07D333/22 ,  C07C2101/02

    摘要： Compounds with fungicidal and insecticidal properties having formula ##STR1## wherein X is N or CH; Z is O, S or NR.sub.8 ; A is hydrogen, halo, cyano, (C.sub.1 -C.sub.12)alkyl, or (C.sub.1 -C.sub.12)alkoxy; R.sub.1 and R.sub.8 are independently hydrogen or (C.sub.1 -C.sub.4)alkyl; R.sub.2 is hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, aryl, aralkyl, heterocyclic, heterocyclic(C.sub.1 -C.sub.4)alkyl or C(R.sub.10).dbd.N--OR.sub.9 ; R.sub.3 is hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, aryl, aralkyl, aryl(C.sub.3 -C.sub.7)cycloalkyl, heterocyclic or heterocyclic(C.sub.1 -C.sub.4)alkyl; R.sub.4 and R.sub.5 are independently hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, halo, cyano, (C.sub.1 -C.sub.4)alkoxycarbonyl, aryl, aralkyl, aryl(C.sub.3 -C.sub.7)cycloalkyl, heterocyclic or heterocyclic(C.sub.1 -C.sub.4)alkyl; R.sub.6 is hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, halo, cyano, (C.sub.1 -C.sub.4)alkoxycarbonyl, aryl, aralkyl, aryl(C.sub.3 -C.sub.7)cycloalkyl, heterocyclic or heterocyclic(C.sub.1 -C.sub.4)alkyl; R.sub.7 is aryl, aralkyl, heterocyclic or heterocyclic(C.sub.1 -C.sub.4)alkyl; R.sub.9 is hydrogen, (C.sub.1 -C.sub.12,)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, (C.sub.1 -C.sub.4)alkylcarbonyl, (C.sub.1 -C.sub.4)alkoxycarbonyl, aryl, or aralkyl; and R.sub.10 is hydrogen, (C.sub.1 -C.sub.12)alkyl, halo(C.sub.1 -C.sub.12)alkyl, (C.sub.3 -C.sub.7)cycloalkyl, halo(C.sub.3 -C.sub.7)cycloalkyl, (C.sub.2 -C.sub.8)alkenyl, halo(C.sub.2 -C.sub.8)alkenyl, (C.sub.2 -C.sub.8)alkynyl, halo(C.sub.2 -C.sub.8)alkynyl, aryl, aralkyl, heterocyclic, or heterocyclic(C.sub.1 -C.sub.4)alkyl.