Multi-ply cellulosic products using high-bulk cellulosic fibers
    1.
    发明授权
    Multi-ply cellulosic products using high-bulk cellulosic fibers 失效
    使用大体积纤维素纤维的多层纤维素产品

    公开(公告)号:US06306251B1

    公开(公告)日:2001-10-23

    申请号:US08912055

    申请日:1997-08-18

    Abstract: A multi-ply paperboard comprising at least one ply of conventional cellulose fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent; and at least one ply of chemically intrafiber crosslinked cellulosic high-bulk fibers and from about 0.1 to about 6 weight percent of a water-borne binding agent. The water-borne binding agent may be a starch, a modified starch, a polyvinyl alcohol, a polyvinyl acetate, a polyethylene/acrylic acid copolymer, an acrylic acid polymer, a polyacrylate, a polyacrylamide, a polyamine, guar gum, an oxidized polyethylene, a polyvinyl chloride, a polyvinyl chloride/acrylic acid copolymer, an acrylonitrile/butadiene/styrene copolymer or polyacrylonitrile. A method for making the paperboard is disclosed.

    Abstract translation: 包含至少一层常规纤维素纤维和约0.1至约6重量%水性粘合剂的多层纸板; 和至少一层化学纤维内交联的纤维素高松散纤维和约0.1至约6重量%的水性粘合剂。 水性粘合剂可以是淀粉,改性淀粉,聚乙烯醇,聚乙酸乙烯酯,聚乙烯/丙烯酸共聚物,丙烯酸聚合物,聚丙烯酸酯,聚丙烯酰胺,多胺,瓜尔胶,氧化聚乙烯 ,聚氯乙烯,聚氯乙烯/丙烯酸共聚物,丙烯腈/丁二烯/苯乙烯共聚物或聚丙烯腈。 公开了制造纸板的方法。

    Lyocell fibers, and compositions for making same
    2.
    发明授权
    Lyocell fibers, and compositions for making same 有权
    Lyocell纤维,以及制造相同的组合物

    公开(公告)号:US06210801B1

    公开(公告)日:2001-04-03

    申请号:US09256197

    申请日:1999-02-24

    Abstract: The present invention provides compositions, useful for making lyocell fibers, having a high hemicellulose content, a low lignin content and including cellulose that has a low average degree of polymerization (D.P.). Further, the present invention provides processes for making compositions, useful for making lyocell fibers, having a high hemicellulose content, a low lignin content and including cellulose that has a low average degree of polymerization. The present invention also provides lyocell fibers containing a high proportion of hemicellulose. Further, the lyocell fibers of the present invention have enhanced dye-binding properties and a reduced tendency to fibrillate.

    Abstract translation: 本发明提供可用于制备具有高半纤维素含量,低木质素含量并且包括具有低平均聚合度(D.P。)的纤维素的莱赛尔纤维的组合物。 此外,本发明提供了制备可用于制备具有高半纤维素含量,低木质素含量并且包括具有低平均聚合度的纤维素的莱赛尔纤维的组合物的方法。 本发明还提供含有高比例的半纤维素的溶胞酶纤维。 此外,本发明的莱赛尔纤维具有增强的染料结合性能和降低的原纤维化趋势。

    Method for producing cellulose fiber having improved biostability and the resulting products
    5.
    发明授权
    Method for producing cellulose fiber having improved biostability and the resulting products 失效
    具有改善的生物稳定性的纤维素纤维的生产方法和所得的产品

    公开(公告)号:US07179348B2

    公开(公告)日:2007-02-20

    申请号:US10228815

    申请日:2002-08-27

    Abstract: A cellulose fiber having extended biostability and the method of its manufacture are described. While prior treatments of cellulose with biotoxic metal compounds have given improved resistance to decay, these treatments have not been entirely satisfactory where the fiber had to be refined before use. Refining energy was very high and fiber length loss was substantial. Treatment of cellulose fiber with didecyldimethylammonium chloride (DDAC) or bromide (DDAB), these materials in combination with low levels of copper, or low levels of copper alone, has given a product with very good biostability without a major increase in refining energy or loss of fiber length. The treated fiber is particularly advantageous as a reinforcing component for cement board products.

    Abstract translation: 描述了具有延长生物稳定性的纤维素纤维及其制造方法。 虽然具有生物毒性金属化合物的纤维素的先前处理已经提供了改善的抗衰老性能,但是在使用前必须精制纤维时,这些处理并不完全令人满意。 精炼能量非常高,纤维长度损失很大。 使用二癸基二甲基氯化铵(DDAC)或溴化物(DDAB)处理纤维素纤维,这些材料与低水平的铜或单独的低含量铜结合使得具有非常好的生物稳定性的产品,而不会大大提高精炼能量或损失 的纤维长度。 经处理的纤维作为水泥板产品的增强组分是特别有利的。

    Hypochlorite free method for preparation of stable carboxylated carbohydrate products

    公开(公告)号:US07135557B2

    公开(公告)日:2006-11-14

    申请号:US10856198

    申请日:2004-09-03

    CPC classification number: D21C9/005 C08B15/04 C08B31/18 D21H11/14 D21H11/20

    Abstract: A method of making a carboxylated carbohydrate is disclosed, cellulose being a preferred carbohydrate material. Carboxylated cellulose fibers can be produced whose fiber strength and degree of polymerization is not significantly sacrificed. The method involves the use of a catalytic amount of a hindered cyclic oxammonium compounds as a primary oxidant and chlorine dioxide as a secondary oxidant in an aqueous environment. The oxammonium compounds may be formed in situ from their corresponding amine, hydroxylamine, or nitroxyl compounds. The oxidized cellulose may be stabilized against D.P. loss and color reversion by further treatment with an oxidant such as sodium chlorite or a chlorine dioxide/hydrogen peroxide mixture. Alternatively it may be treated with a reducing agent such as sodium borohydride. In the case of cellulose the method results in a high percentage of carboxyl groups located at the fiber surface. The product is especially useful as a papermaking fiber where it contributes strength and has a higher attraction for cationic additives. The product is also useful as an additive to recycled fiber to increase strength. The method can be used to improve properties of either virgin or recycled fiber. It does not require high α-cellulose fiber but is suitable for regular market pulps.

    Carboxylated cellulosic fibrous web and method of making the same
    10.
    发明授权
    Carboxylated cellulosic fibrous web and method of making the same 失效
    羧化纤维素纤维网及其制备方法

    公开(公告)号:US06592717B2

    公开(公告)日:2003-07-15

    申请号:US10260784

    申请日:2002-09-27

    CPC classification number: D21H11/20 D06M13/192 D06M15/263 D21C9/005

    Abstract: Carboxylated cellulosic fibers are disclosed. The fibers include a polycarboxylic acid covalently coupled to the fibers. Methods for producing the fibers and for producing fibrous products that incorporate the fibers are also disclosed.

    Abstract translation: 公开了羧化纤维素纤维。 纤维包括与纤维共价偶联的多元羧酸。 还公开了用于生产纤维和用于生产包含纤维的纤维制品的方法。

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