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公开(公告)号：US08969577B2
公开(公告)日：2015-03-03
申请号：US13130331
申请日：2009-11-18
IPC分类号： C07D213/74 , C07D215/38 , C08G59/50 , C08G59/68 , C08L63/00 , C08G59/42
CPC分类号： C07D213/74 , C07D215/38 , C08G59/4246 , C08G59/686 , C08L63/00
摘要： The present invention relates to curable compositions comprising a thermolatent amidine base and an organic material which is polymerizable or crosslinkable with a basic or nucleophilic catalyst. In particular, the invention relates to curable coating compositions, especially powder coating compositions, and curable adhesive compositions, as well as to the use a thermolatent amidine base as a curing catalyst for thermally induced base-catalyzed polymerization or crosslinking reactions.
摘要翻译： 本发明涉及可固化组合物，其包含热中和脒碱和可与碱性或亲核催化剂可聚合或交联的有机材料。 特别地，本发明涉及可固化涂料组合物，特别是粉末涂料组合物和可固化粘合剂组合物，以及使用热中和脒碱作为热诱导的碱催化聚合或交联反应的固化催化剂。
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公开(公告)号：US20110245375A1
公开(公告)日：2011-10-06
申请号：US13130331
申请日：2009-11-18
IPC分类号： C09D163/00 , C08L63/00 , C07D213/72 , C07D215/38
CPC分类号： C07D213/74 , C07D215/38 , C08G59/4246 , C08G59/686 , C08L63/00
摘要： The present invention relates to curable compositions comprising a thermolatent amidine base and an organic material which is polymerisable or crosslinkable with a basic or nucleophilic catalyst. In particular, the invention relates to curable coating compositions, especially powder coating compositions, and curable adhesive compositions, as well as to the use a thermo-latent amidine base as a curing catalyst for thermally induced base- catalyzed polymerisation or crosslinking reactions.
摘要翻译： 本发明涉及可固化组合物，其包含热中和脒碱和可与碱性或亲核催化剂聚合或可交联的有机材料。 特别地，本发明涉及可固化涂料组合物，特别是粉末涂料组合物和可固化粘合剂组合物，以及使用热潜伏脒碱作为热诱导的碱催化聚合或交联反应的固化催化剂。
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公开(公告)号：US08940806B2
公开(公告)日：2015-01-27
申请号：US13258951
申请日：2010-03-26
IPC分类号： C08F2/10 , C08F2/50 , B29C71/04 , C08F2/46 , C08G61/04 , C08F4/04 , C07D211/98 , C09D175/14
CPC分类号： C08F4/04 , C07D211/98 , C08F2/46 , C09D175/14
摘要： The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical —(CR8R9)—, Z1 is —O—, —NR10—, —CH2—, —(CR11R12)— or —C(═O)— and R1 to R12 are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerizable compositions comprising them.
摘要翻译： 本发明涉及其中Q为直接键或二价基 - （CR 8 R 9） - ，Z 1为-O-，-NR 10 - ， - CH 2 - ， - （CR 11 R 12） - 或 - C（= O） - 和R 1至R 12是任选取代的烃残基，作为可用于由自由基引发的反应的基团的前体，例如不饱和单体的聚合和聚烯烃的降解。 式（I）的大多数三氮烯也是新颖的，并且还要求制备式（I）的三氮烯和包含它们的可聚合组合物。
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公开(公告)号：US08664288B2
公开(公告)日：2014-03-04
申请号：US13319244
申请日：2010-05-05
CPC分类号： C08F120/18 , C07C251/58 , C07C275/70 , C07C2601/14 , C07C2601/20 , C08F4/00 , C08F8/32 , C09D135/02
摘要： The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-lmino-isoureas compounds are compounds of the Formula (I), wherein n is 1, 2, 3 or 4, R100 and R101 are independently H, C1-18 alkyl, C3-C12cycloalkyl, C6-C14aryl, C1-C14heteroaryl, C7-C15aralkyl, C2-C14heteroaralkyl, Cyano, or R100 and R101 form together with the carbon to which they are attached a mono or polycyclic C3-C18 carbocyclic or C1-C18 heterocyclic ring; R102 and R103 are independently C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C6-C14aryl once or more than once substituted by C1-C18alkyl; C7-C15aralkyl, (CH3)3Si—; or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C7-C15aralkyl or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl which are interrupted or substituted by O or by N containing groups selected from C1-C18alkylamino, bis(C1-C18alkyl)amino or tris(C1-C18alkyl)ammonium; R104 if n is 1 is H, C1-C18alkyl, C3-C12cycloalkyl, C7-C14aralkyl, C6-C14aryl or acyl selected from the group consisting of the following acyls —C(═O)—H, —C(═O)—C1-C18alkyl, —C(═O)—C2-d18alkenyl, —C(═O)—C6-C14aryl, —C(═O)—C2-C18alkenyl-C6-C14aryl, —C(═O)—O—C1C18alkyl, —C(═O)—O—C6-C14aryl, —C(═O)—NH—C1-C18alkyl, —C(═O)—NH—C6-C14aryl and —C(═O)—N(C1C18alkyl)2; or R102 and R104 if n is 1 form together with the nitrogen atom to which they are attached a 5 to 12 membered ring which may contain additional heteroatoms, R104 if n is more than 1 is di-, tri-, tetra-C1-C18alkylidene, diacyls, triacyls or tetraacyls and salts thereof.
摘要翻译： 本发明涉及O-亚氨基 - 异脲化合物作为自由基源的用途，其包含这些O-亚氨基 - 异脲和包含新的O-亚氨基 - 异脲化合物的可聚合组合物。 O - 异喹啉化合物是式（I）的化合物，其中n为1,2,3或4，R 100和R 101独立地为H，C 1-18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 1 -C 14杂芳基 C 7 -C 15芳烷基，C 2 -C 14杂芳烷基，氰基或R 100和R 101与它们所连接的碳一起形成单或多环C 3 -C 18碳环或C 1 -C 18杂环; R 102和R 103独立地是C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 1 -C 14芳基，其一次或多于一个被C 1 -C 18烷基取代; C 7 -C 15芳烷基，（CH 3）3 Si- 或R 102和R 103为C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 7 -C 15芳烷基或R 102和R 103为C 1 -C 18烷基，C 3 -C 12环烷基，其被O或含N的基团中断或取代，所述基团选自C 1 -C 18烷基氨基， 双（C1-C18烷基）氨基或三（C1-C18烷基）铵; 如果n为1，则R 104为H，C 1 -C 18烷基，C 3 -C 12环烷基，C 7 -C 14芳烷基，C 6 -C 14芳基或选自以下酰基-C（= O）-H，-C（= O） - C 1 -C 18烷基，-C（= O）-C 2-d 18烯基，-C（= O）-C 6 -C 14芳基，-C（= O）-C 2 -C 18烯基-C 6 -C 14芳基，-C（= O） C 1 -C 18烷基，-C（= O）-O-C 6 -C 14芳基，-C（= O）-NH-C 1 -C 18烷基，-C（= O）-NHC 6 -C 14芳基和-C（= O） C 1 -C 18烷基）2; 如果n为1，则与R 102和R 104一起形成与它们所连接的氮原子一起形成可含有其它杂原子的5至12元环，如果n大于1，则R104是二 - ，三 - ，四-C1-C18亚烷基 ，二酰基，三酰基或四酰基及其盐。
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公开(公告)号：US20100143805A1
公开(公告)日：2010-06-10
申请号：US12529720
申请日：2008-02-29
IPC分类号： H01M6/16 , H01M10/05 , H01M10/26 , C07D241/04 , C07F9/06 , C07D233/54
CPC分类号： C07D233/32 , C07D233/42 , C07D235/02 , C07D241/08 , C07D241/52 , C07D243/14 , C07D265/32 , C07D265/34 , C07D265/36 , C07D405/06 , C07F9/6584 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M10/4235
摘要： This invention relates to overcharge protection and molecular redox shuttles in rechargeable lithium-ion cells. For this, specific nitroxyls or oxoammonium salts are used in the electrolyte. This invention also relates to a method of producing such lithium-ion cells and to a method of recharging such lithium-ion cells. This invention also pertains to some nitroxyls compounds and oxoammonium salts.
摘要翻译： 本发明涉及可充电锂离子电池中的过充电保护和分子氧化还原梭。 为此，在电解质中使用特定的硝酰氧基或氧代铵盐。 本发明还涉及这种锂离子电池的制造方法和锂离子电池的充电方法。 本发明还涉及一些硝酰基化合物和氧代铵盐。
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公开(公告)号：US20110288251A1
公开(公告)日：2011-11-24
申请号：US13143355
申请日：2009-12-28
IPC分类号： C08F4/00 , C07C249/04 , C07D211/94
CPC分类号： C07D211/94 , C07C291/02 , C07C2601/14
摘要： The invention relates to novel O-dialkylamino-isoureas and polymerizable compositions comprising these O-dialkylamino-isoureas of compounds of the general formula (I). The invention further relates to the use of O-dialkylamino-isoureas as polymerization initiators, especially to prepare coatings or for controlled degradation of polyolefins.
摘要翻译： 本发明涉及新的O-二烷基氨基 - 异脲和包含通式（I）化合物的这些O-二烷基氨基 - 异脲的可聚合组合物。 本发明还涉及O-二烷基氨基 - 异脲作为聚合引发剂的用途，特别是制备涂层或用于聚烯烃的可控降解。
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公开(公告)号：US20100181527A1
公开(公告)日：2010-07-22
申请号：US12664420
申请日：2008-06-09
IPC分类号： H01M4/505 , C07D241/04 , C07D265/32
摘要： This invention relates to a stable secondary battery utilizing as active principle the oxidation and reduction cycle of a sterically hindered nitroxide radical, a sterically hindered oxoammonium cation, a sterically hindered hydroxylamine or a sterically hindered aminoxide anion containing a piperazin-2,6-dione, a piperazin-2-one or morpholin-2-one structural unit. Further aspects of the invention are a method for providing such a secondary battery, the use of the respective compounds as active elements in secondary batteries and selected novel compounds.
摘要翻译： 本发明涉及一种利用空间位阻氮氧自由基的空间位阻氧化铵阳离子，空间位阻羟胺或含有哌嗪-2,6-二酮的空间位阻氨基氧阴离子的氧化和还原循环作为活性成分的稳定二次电池， 哌嗪-2-酮或吗啉-2-酮结构单元。 本发明的另外的方面是提供这种二次电池的方法，各种化合物作为二次电池中的活性元素的用途和选择的新型化合物。
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公开(公告)号：US08669398B2
公开(公告)日：2014-03-11
申请号：US13143355
申请日：2009-12-28
IPC分类号： C07C275/70
CPC分类号： C07D211/94 , C07C291/02 , C07C2601/14
摘要： The invention relates to novel O-dialkylamino-isoureas and polymerizable compositions comprising these O-dialkylamino-isoureas of compounds of the general formula (I). The invention further relates to the use of O-dialkylamino-isoureas as polymerization initiators, especially to prepare coatings or for controlled degradation of polyolefins.
摘要翻译： 本发明涉及新的O-二烷基氨基 - 异脲和包含通式（I）化合物的这些O-二烷基氨基 - 异脲的可聚合组合物。 本发明还涉及O-二烷基氨基 - 异脲作为聚合引发剂的用途，特别是制备涂层或用于聚烯烃的可控降解。
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公开(公告)号：US20120108696A1
公开(公告)日：2012-05-03
申请号：US13319244
申请日：2010-05-05
IPC分类号： C07C251/58 , B05D3/00 , C08F6/00 , C08F20/18 , C08F10/06
CPC分类号： C08F120/18 , C07C251/58 , C07C275/70 , C07C2601/14 , C07C2601/20 , C08F4/00 , C08F8/32 , C09D135/02
摘要： The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-lmino-isoureas compounds are compounds of the Formula (I), wherein n is 1, 2, 3 or 4, R100 and R101 are independently H, C1-18 alkyl, C3-C12cycloalkyl, C6-C14aryl, C1-C14heteroaryl, C7-C15aralkyl, C2-C14heteroaralkyl, Cyano, or R100 and R101 form together with the carbon to which they are attached a mono or polycyclic C3-C18 carbocyclic or C1-C18 heterocyclic ring; R102 and R103 are independently C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C6-C14aryl once or more than once substituted by C1-C18alkyl; C7-C15aralkyl, (CH3)3Si—; or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C7-C15aralkyl or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl which are interrupted or substituted by O or by N containing groups selected from C1-C18alkylamino, bis(C1-C18alkyl)amino or tris(C1-C18alkyl)ammonium; R104 if n is 1 is H, C1-C18alkyl, C3-C12cycloalkyl, C7-C14aralkyl, C6-C14aryl or acyl selected from the group consisting of the following acyls —C(═O)—H, —C(═O)—C1-C18alkyl, —C(═O)—C2-d18alkenyl, —C(═O)—C6-C14aryl, —C(═O)—C2-C18alkenyl-C6-C14aryl, —C(═O)—O—C1C18alkyl, —C(═O)—O—C6-C14aryl, —C(═O)—NH—C1-C18alkyl, —C(═O)—NH—C6-C14aryl and —C(═O)—N(C1C18alkyl)2; or R102 and R104 if n is 1 form together with the nitrogen atom to which they are attached a 5 to 12 membered ring which may contain additional heteroatoms, R104 if n is more than 1 is di-, tri-, tetra-C1-C18alkylidene, diacyls, triacyls or tetraacyls and salts thereof.
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公开(公告)号：US20120041093A1
公开(公告)日：2012-02-16
申请号：US13258951
申请日：2010-03-26
IPC分类号： C07D211/98 , C08F2/00 , C08F2/50
CPC分类号： C08F4/04 , C07D211/98 , C08F2/46 , C09D175/14
摘要： The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical —(CR8R9)—, Z1 is —O—, —NR10—, —CH2—, —(CR11R12)— or —C(═O)— and R1 to R12 are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerisable compositions comprising them.
摘要翻译： 本发明涉及其中Q为直接键或二价基 - （CR 8 R 9） - ，Z 1为-O-，-NR 10 - ， - CH 2 - ， - （CR 11 R 12） - 或 - C（= O） - 和R 1至R 12是任选取代的烃残基，作为可用于由自由基引发的反应的基团的前体，例如不饱和单体的聚合和聚烯烃的降解。 式（I）的大多数三氮烯也是新型的，并且还要求制备式（I）的三氮烯和包含它们的可聚合组合物。
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