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    O-imino-iso-urea compounds and polymerizable compositions thereof
    1.
    发明授权
    O-imino-iso-urea compounds and polymerizable compositions thereof 失效
    O-亚氨基异脲化合物及其可聚合组合物

    公开(公告)号：US08664288B2

    公开(公告)日：2014-03-04

    申请号：US13319244

    申请日：2010-05-05

    申请人： Peter Nesvadba ,  Lucienne Bugnon Folger ,  Antoine Carroy ,  Marc Faller ,  Bruno Spony

    发明人： Peter Nesvadba ,  Lucienne Bugnon Folger ,  Antoine Carroy ,  Marc Faller ,  Bruno Spony

    IPC分类号： C08F2/46 ,  C08J3/28 ,  C08B37/00 ,  C08F2/50 ,  B29C71/04 ,  C08G61/04

    CPC分类号： C08F120/18 ,  C07C251/58 ,  C07C275/70 ,  C07C2601/14 ,  C07C2601/20 ,  C08F4/00 ,  C08F8/32 ,  C09D135/02

    摘要： The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-lmino-isoureas compounds are compounds of the Formula (I), wherein n is 1, 2, 3 or 4, R100 and R101 are independently H, C1-18 alkyl, C3-C12cycloalkyl, C6-C14aryl, C1-C14heteroaryl, C7-C15aralkyl, C2-C14heteroaralkyl, Cyano, or R100 and R101 form together with the carbon to which they are attached a mono or polycyclic C3-C18 carbocyclic or C1-C18 heterocyclic ring; R102 and R103 are independently C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C6-C14aryl once or more than once substituted by C1-C18alkyl; C7-C15aralkyl, (CH3)3Si—; or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C7-C15aralkyl or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl which are interrupted or substituted by O or by N containing groups selected from C1-C18alkylamino, bis(C1-C18alkyl)amino or tris(C1-C18alkyl)ammonium; R104 if n is 1 is H, C1-C18alkyl, C3-C12cycloalkyl, C7-C14aralkyl, C6-C14aryl or acyl selected from the group consisting of the following acyls —C(═O)—H, —C(═O)—C1-C18alkyl, —C(═O)—C2-d18alkenyl, —C(═O)—C6-C14aryl, —C(═O)—C2-C18alkenyl-C6-C14aryl, —C(═O)—O—C1C18alkyl, —C(═O)—O—C6-C14aryl, —C(═O)—NH—C1-C18alkyl, —C(═O)—NH—C6-C14aryl and —C(═O)—N(C1C18alkyl)2; or R102 and R104 if n is 1 form together with the nitrogen atom to which they are attached a 5 to 12 membered ring which may contain additional heteroatoms, R104 if n is more than 1 is di-, tri-, tetra-C1-C18alkylidene, diacyls, triacyls or tetraacyls and salts thereof.

    摘要翻译： 本发明涉及O-亚氨基 - 异脲化合物作为自由基源的用途，其包含这些O-亚氨基 - 异脲和包含新的O-亚氨基 - 异脲化合物的可聚合组合物。 O - 异喹啉化合物是式（I）的化合物，其中n为1,2,3或4，R 100和R 101独立地为H，C 1-18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 1 -C 14杂芳基 C 7 -C 15芳烷基，C 2 -C 14杂芳烷基，氰基或R 100和R 101与它们所连接的碳一起形成单或多环C 3 -C 18碳环或C 1 -C 18杂环; R 102和R 103独立地是C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 1 -C 14芳基，其一次或多于一个被C 1 -C 18烷基取代; C 7 -C 15芳烷基，（CH 3）3 Si- 或R 102和R 103为C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 7 -C 15芳烷基或R 102和R 103为C 1 -C 18烷基，C 3 -C 12环烷基，其被O或含N的基团中断或取代，所述基团选自C 1 -C 18烷基氨基， 双（C1-C18烷基）氨基或三（C1-C18烷基）铵; 如果n为1，则R 104为H，C 1 -C 18烷基，C 3 -C 12环烷基，C 7 -C 14芳烷基，C 6 -C 14芳基或选自以下酰基-C（= O）-H，-C（= O） - C 1 -C 18烷基，-C（= O）-C 2-d 18烯基，-C（= O）-C 6 -C 14芳基，-C（= O）-C 2 -C 18烯基-C 6 -C 14芳基，-C（= O） C 1 -C 18烷基，-C（= O）-O-C 6 -C 14芳基，-C（= O）-NH-C 1 -C 18烷基，-C（= O）-NHC 6 -C 14芳基和-C（= O） C 1 -C 18烷基）2; 如果n为1，则与R 102和R 104一起形成与它们所连接的氮原子一起形成可含有其它杂原子的5至12元环，如果n大于1，则R104是二 - ，三 - ，四-C1-C18亚烷基 ，二酰基，三酰基或四酰基及其盐。

    O-IMINO-ISO-UREA COMPOUNDS AND POLYMERIZABLE COMPOSITIONS THEREOF
    4.
    发明申请
    O-IMINO-ISO-UREA COMPOUNDS AND POLYMERIZABLE COMPOSITIONS THEREOF 失效

    公开(公告)号：US20120108696A1

    公开(公告)日：2012-05-03

    申请号：US13319244

    申请日：2010-05-05

    申请人： Peter Nesvadba ,  Lucienne Bugnon Folger ,  Antoine Carroy ,  Marc Faller ,  Bruno Spony

    发明人： Peter Nesvadba ,  Lucienne Bugnon Folger ,  Antoine Carroy ,  Marc Faller ,  Bruno Spony

    IPC分类号： C07C251/58 ,  B05D3/00 ,  C08F6/00 ,  C08F20/18 ,  C08F10/06

    CPC分类号： C08F120/18 ,  C07C251/58 ,  C07C275/70 ,  C07C2601/14 ,  C07C2601/20 ,  C08F4/00 ,  C08F8/32 ,  C09D135/02

    摘要： The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-lmino-isoureas compounds are compounds of the Formula (I), wherein n is 1, 2, 3 or 4, R100 and R101 are independently H, C1-18 alkyl, C3-C12cycloalkyl, C6-C14aryl, C1-C14heteroaryl, C7-C15aralkyl, C2-C14heteroaralkyl, Cyano, or R100 and R101 form together with the carbon to which they are attached a mono or polycyclic C3-C18 carbocyclic or C1-C18 heterocyclic ring; R102 and R103 are independently C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C6-C14aryl once or more than once substituted by C1-C18alkyl; C7-C15aralkyl, (CH3)3Si—; or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C7-C15aralkyl or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl which are interrupted or substituted by O or by N containing groups selected from C1-C18alkylamino, bis(C1-C18alkyl)amino or tris(C1-C18alkyl)ammonium; R104 if n is 1 is H, C1-C18alkyl, C3-C12cycloalkyl, C7-C14aralkyl, C6-C14aryl or acyl selected from the group consisting of the following acyls —C(═O)—H, —C(═O)—C1-C18alkyl, —C(═O)—C2-d18alkenyl, —C(═O)—C6-C14aryl, —C(═O)—C2-C18alkenyl-C6-C14aryl, —C(═O)—O—C1C18alkyl, —C(═O)—O—C6-C14aryl, —C(═O)—NH—C1-C18alkyl, —C(═O)—NH—C6-C14aryl and —C(═O)—N(C1C18alkyl)2; or R102 and R104 if n is 1 form together with the nitrogen atom to which they are attached a 5 to 12 membered ring which may contain additional heteroatoms, R104 if n is more than 1 is di-, tri-, tetra-C1-C18alkylidene, diacyls, triacyls or tetraacyls and salts thereof.