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公开(公告)号：US6107017A
公开(公告)日：2000-08-22
申请号：US103591
申请日：1998-06-24
申请人： Paul B. Merkel , Ronald E. Leone
发明人： Paul B. Merkel , Ronald E. Leone
CPC分类号： G03C7/3885 , G03C1/005
摘要： A photographic element comprises a support bearing at least one silver halide emulsion and at least one high-boiling solvent of structure I, below: ##STR1## wherein: each m is independently 0, 1 or 2;each R.sub.1 is independently methyl or ethyl;n is 2 to 7;each R.sub.2 and each R.sub.3 may be the same or different and is individually selected from hydrogen or an alkyl group with up to five carbon atoms; andthe sum of the number of carbon atoms in each R.sub.1 plus each R.sub.2 plus each R.sub.3 taken together is four to eight.
摘要翻译： 照相元件包括载体，其载有至少一种卤化银乳剂和至少一种以下结构I的高沸点溶剂：其中：每个m独立地为0,1或2; 每个R 1独立地是甲基或乙基; n为2至7; 每个R 2和R 3可以相同或不同，并且各自独立地选自氢或具有至多5个碳原子的烷基; 每个R1加上每个R2加上每个R3一起的碳原子数之和为四至八。
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公开(公告)号：US5965341A
公开(公告)日：1999-10-12
申请号：US873530
申请日：1997-06-12
CPC分类号： G03C7/384 , G03C7/3225 , G03C2003/006 , G03C2200/10 , G03C7/30529 , Y10S430/158
摘要： The invention provides a photographic element comprising a silver halide emulsion layer sensitive to green light having associated therewith (a) a 1-aryl-3-anilino-4-benzotriazolyl-5-pyrazolone magenta dye-forming DIR coupler of a particular formula, and (b) a 1-aryl-3-anilino-4-phenylthio-5-pyrazolone magenta image dye forming coupler of a particular formula. The element of the invention provides an improved interimage of a green sensitized layer in a multicolor silver halide photographic element.
摘要翻译： 本发明提供一种照相元件，其包含对绿色光敏感的卤化银乳剂层（a）具有特定配方的1-芳基-3-苯胺基-4-苯并三唑基-5-吡唑啉酮品红色染料形成DIR成色剂，以及 （b）具有特定结构式的1-芳基-3-苯胺基-4-苯基硫代-5-吡唑啉酮品红色影像染料形成成色剂。 本发明的元件提供了在多色卤化银照相元件中的绿色敏化层的改进的图像。
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公开(公告)号：US6054258A
公开(公告)日：2000-04-25
申请号：US103929
申请日：1998-06-24
申请人： Paul B. Merkel , Ronald E. Leone
发明人： Paul B. Merkel , Ronald E. Leone
CPC分类号： C07C69/78 , C07C69/76 , G03C1/005 , G03C7/3885 , G03C7/39232
摘要： The invention disclosed is a photographic element comprising a support bearing at least one silver halide emulsion and at least one high-boiling solvent of structure I, below: ##STR1## wherein: m is 0, 1 or 2;each R.sub.1 is an individually selected alkyl group with up to four carbon atoms;n is 2 to 5;each R.sub.2 and R.sub.3 may be the same or different and is individually selected from hydrogen or an alkyl group with up to four carbon atoms;p is 0 to 3;each R.sub.4 is independently a methyl or ethyl group; andthe sum of the number of carbon atoms in each R.sub.1 plus each R.sub.2 plus each R.sub.3 plus each R.sub.4 taken together is three to seven.
摘要翻译： 所公开的发明是一种照相元件，其中包含至少一种卤化银乳剂和至少一种以下结构I的高沸点溶剂的载体：其中：m为0,1或2; 每个R 1是具有至多4个碳原子的单独选择的烷基; n为2〜5; 每个R 2和R 3可以相同或不同，并且分别选自氢或具有至多4个碳原子的烷基; p为0〜3; 每个R 4独立地是甲基或乙基; 每个R1加上每个R2加上每个R3加上每个R4一起的碳原子数之和为三到七。
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4.发明授权Photographic elements comprising 2-phenylcarbamoyl-1-naphthol image-modifying couplers yeilding dyes resistant to crystallization and reduction 失效包含2-苯基氨基甲酰基-1-萘酚图像改性成色剂的摄影元件对结晶和还原具有抗性
公开(公告)号：US5521057A
公开(公告)日：1996-05-28
申请号：US99039
申请日：1993-07-28
CPC分类号： G03C11/00 , G03C7/30523 , Y10S430/156
摘要： Photographic elements comprising certain 2-phenylcarbamoyl-1-naphthol image-modifying couplers exhibit proper hue, a resistance to dye crystallization, and a resistance to leuco cyan dye formation. Such couplers can be utilized for their image-modifying effect and can contribute substantially to the overall dye density of an image.
摘要翻译： 包含某些2-苯基氨基甲酰基-1-萘酚图像改性成色剂的照相元件表现出适当的色调，抗染料结晶性和对无色青色染料形成的抗性。 这样的成色剂可以用于其影像修饰效果，并且可以显着地有助于图像的整体染料密度。
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5.发明授权Photographic elements comprising 2-phenylcarbamoyl-1-naphthol image-modifying couplers yielding dyes resistant to crystallization and reduction 失效包含2-苯基氨基甲酰基-1-萘酚图像改性成色剂的摄影元件产生耐结晶和还原的染料
公开(公告)号：US5506094A
公开(公告)日：1996-04-09
申请号：US098552
申请日：1993-07-28
CPC分类号： G03C7/30523 , Y10S430/158
摘要： Photographic elements comprising certain 2-phenylcarbamoyl-1-naphthol image-modifying couplers exhibit proper hue, a resistance to dye crystallization, and a resistance to leuco cyan dye formation. Such couplers can be utilized for their image-modifying effect and can contribute substantially to the overall dye density of an image.
摘要翻译： 包含某些2-苯基氨基甲酰基-1-萘酚图像改性成色剂的照相元件表现出适当的色调，抗染料结晶性和对无色青色染料形成的抗性。 这样的成色剂可以用于其影像修饰效果，并且可以显着地有助于图像的整体染料密度。
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6.发明授权Photographic element and process employing active, stable benzotriazole-releasing DIR couplers 失效使用活性，稳定的苯并三唑释放DIR成色剂的摄影元件和方法
公开(公告)号：US5942381A
公开(公告)日：1999-08-24
申请号：US873516
申请日：1997-06-12
CPC分类号： G03C7/30558 , G03C7/30529 , G03C7/384 , Y10S430/158
摘要： A photographic element comprising a silver halide emulsion layer having associated therewith a 1-phenyl-3-anilino-4-benzotriazolyl-5-pyrazolone magenta dye-forming DIR coupler of structure I: ##STR1## wherein: R.sub.1 is hydrogen, chlorine, fluorine or a methyl group;R.sub.2, R.sub.3, and R.sub.4 are individually selected from the group consisting of hydrogen, halogen, alkyl, phenyl, alkoxy, phenoxy, alkylthio, carbonamido, sulfonamido, carbamoyl, alkoxycarbonyl and aryloxycarbonyl groups;R.sub.5 is hydrogen, bromine, chlorine, fluorine, or an alkyl group;R.sub.6 and R.sub.7 are independently selected from the group consisting of hydrogen, halogen, carbonamido, carbamoyl, sulfonamido, sulfamoyl, alkylsulfonyl, arylsulfonyl, alkylsulfoxyl, arylsulfoxyl, sulfonyloxy, alkoxycarbonyl, aryloxycarbonyl, acyloxy, acyl, imido, trifluoromethyl and cyano groups, provided that at least one of R.sub.6 and R.sub.7 is not hydrogen;R.sub.8 and R.sub.9 are independently selected from the group consisting of hydrogen, halogen, alkyl, phenyl, alkoxy, phenoxy, alkoxycarbonyl, aryloxycarbonyl, carbonamido sulfonamido, carbamoyl and carbamoyloxy groups, provided that at least one of R.sub.8 and R.sub.9 is not hydrogen;further provided that (1) when R.sub.5 is hydrogen, the sum of the Hammett's sigma values of R.sub.6 and R.sub.7, referenced to the position of the anilino nitrogen, is at least 0.30, and R.sub.1 is also hydrogen, and (2) when R.sub.5 is bromine, chlorine, fluorine, or an lakyl group, the sum of the Hammett sigma values of R.sub.6 and R.sub.7, referenced to the position of the anilino nitrogen, is a least 0.20; andthe sum of pi values of R.sub.8 and R.sub.9 taken together is at least 0.60 but not more than 3.00.
摘要翻译： 一种包含卤化银乳剂层的照相元件，其具有结构I的1-苯基-3-苯胺基-4-苯并三唑基-5-吡唑啉酮品红染料形成DIR成色剂：其中：R1是氢，氯，氟或甲基 组; R 2，R 3和R 4分别选自氢，卤素，烷基，苯基，烷氧基，苯氧基，烷硫基，碳酰氨基，亚磺酰氨基，氨基甲酰基，烷氧基羰基和芳氧基羰基。 R5是氢，溴，氯，氟或烷基; R 6和R 7独立地选自氢，卤素，碳酰氨基，氨基甲酰基，亚磺酰氨基，氨磺酰基，烷基磺酰基，芳基磺酰基，烷基亚砜基，芳基亚砜基，磺酰氧基，烷氧基羰基，芳氧基羰基，酰氧基，酰基，亚氨基，三氟甲基和氰基。 R6和R7中的至少一个不是氢; R 8和R 9独立地选自氢，卤素，烷基，苯基，烷氧基，苯氧基，烷氧基羰基，芳氧基羰基，碳酰氨基亚磺酰氨基，氨基甲酰基和氨基甲酰氧基，条件是R 8和R 9中的至少一个不是氢; 进一步规定：（1）当R5为氢时，R6和R7之间的哈米特σ值与以硝基氮的位置为准的总和至少为0.30，R1也为氢，（2）当R5为 溴，氯，氟或烯酰基，参考苯胺基氮的位置的R6和R7的哈米特σ值的总和至少为0.20; 并且R8和R9的π值的总和在一起为至少0.60但不大于3.00。
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公开(公告)号：US5514530A
公开(公告)日：1996-05-07
申请号：US98692
申请日：1993-07-28
IPC分类号： G03C7/00 , C07D257/04 , G03C7/305 , G03C7/333 , G03C7/34
CPC分类号： C07D257/04 , G03C7/30523 , Y10S430/158
摘要： Photographic elements comprising certain 2-phenylcarbamoyl-1-naphthol image-modifying couplers exhibit proper hue, a resistance to dye crystallization, and a resistance to leuco cyan dye formation. Such couplers can be utilized for their image-modifying effect and can contribute substantially to the overall dye density of an image.
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8.发明授权公开(公告)号：US07695783B2
公开(公告)日：2010-04-13
申请号：US10622421
申请日：2003-07-18
申请人： Paul B. Merkel , Gary N. Barber , Alan R. Pitt , Trevor J. Wear
发明人： Paul B. Merkel , Gary N. Barber , Alan R. Pitt , Trevor J. Wear
IPC分类号： B41M5/50
CPC分类号： B41M5/52 , B41M5/5218 , B41M5/529
摘要： The invention relates to an image-recording element comprising a support and an image-receiving layer, wherein the image-receiving layer comprises anionic colloidal silica particles, hydrophilic polymeric binder, and fluorosurfactant, wherein the binder is present in an amount of between 2% and 15% weight of the image-receiving layer, the image-recording element has a 60-degree gloss of greater than 25, and a dry time of less than 1 minute.
摘要翻译： 本发明涉及一种图像记录元件，包括支撑体和图像接收层，其中图像接收层包括阴离子胶体二氧化硅颗粒，亲水性聚合物粘合剂和含氟表面活性剂，其中粘合剂的含量为2％ 和图像接收层的15重量％，图像记录元件具有大于25的60度光泽度和小于1分钟的干燥时间。
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公开(公告)号：US07459263B2
公开(公告)日：2008-12-02
申请号：US10944580
申请日：2004-09-17
申请人： Samir Y. Farid , Douglas R. Robello , Joseph P. Dinnocenzo , Paul B. Merkel , Lorraine Ferrar , Yeonsuk Roh , Mark R. Mis
发明人： Samir Y. Farid , Douglas R. Robello , Joseph P. Dinnocenzo , Paul B. Merkel , Lorraine Ferrar , Yeonsuk Roh , Mark R. Mis
IPC分类号： G11B7/24
CPC分类号： G11B7/24044 , G11B7/245 , G11B2007/0009 , Y10S430/146
摘要： The invention relates to an optical recording material comprising: a polymeric matrix; a dewarbenzene derivative reactant capable of undergoing isomerization to a benzene product upon triplet excitation, thereby causing a change in optical properties; and a sensitizer capable of absorbing actinic radiation to cause triplet energy transfer to said reactant, wherein the algebraic sum of the excitation energy of said sensitizer and its reduction potential is at least 0.05 eV less than the oxidation potential of said reactant, thereby precluding one-electron oxidation of said reactant. The invention further relates to an optical device comprising regional variations in concentrations of reactants and products produced by triplet chain isomerization, thereby providing a pattern of intelligence.
摘要翻译： 本发明涉及一种光学记录材料，包括：聚合物基体; 能够在三重激发时进行苯产物异构化的杜烷苯衍生物反应物，从而引起光学性能的变化; 以及能够吸收光化辐射以使三重态能量转移到所述反应物的敏化剂，其中所述敏化剂的激发能和其还原电位的代数之和小于所述反应物的氧化电位至少0.05eV， 所述反应物的电子氧化。 本发明还涉及一种光学装置，其包括通过三线态异构化产生的反应物和产物的浓度的区域变化，从而提供智力模式。
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公开(公告)号：US06779885B2
公开(公告)日：2004-08-24
申请号：US10011655
申请日：2001-12-04
IPC分类号： B41M500
CPC分类号： B41M5/5218 , B41M5/508 , B41M5/5227 , B41M5/5236 , B41M5/5254
摘要： An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon an image-receiving layer of porous polymeric particles in a polymeric binder, the porous polymeric particles being prepared in the presence of an anionic or ationic dispersant, and the image-receiving layer containing a surfactant having a charge opposite to that of the dispersant used to make the porous polymeric particles, the surfactant being present in an amount from about 0.04 parts to about 0.30 parts by weight of the dispersant; C) loading the printer with an ink jet ink composition; and D) printing on the ink jet recording element using the ink jet ink composition in response to the digital data signals.
摘要翻译： 一种喷墨打印方法，具有以下步骤：A）提供响应于数字数据信号的喷墨打印机; B）用具有支撑体的喷墨记录元件装载打印机，其上具有多孔聚合物颗粒的图像接收层在聚合物粘合剂中，多孔聚合物颗粒在阴离子或异性分散剂的存在下制备， 接收层含有具有与用于制备多孔聚合物颗粒的分散剂相反的电荷的表面活性剂，表面活性剂以分散剂的约0.04重量份至约0.30重量份的量存在; C）用喷墨油墨组合物装载打印机; 和D）响应于数字数据信号，使用喷墨记录元件在喷墨记录元件上进行印刷。
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