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公开(公告)号:US20170239772A1
公开(公告)日:2017-08-24
申请号:US15424223
申请日:2017-02-03
Inventor: YOSHIFUMI TAKASU , YOSHIO OKAYAMA , AKIHIKO ISHIBASHI , ISAO TASHIRO , AKIO UETA , MASAKI NOBUOKA , NAOYA RYOKI
Abstract: A RAMO4 substrate includes a single crystal represented by a formula of RAMO4 (in the formula, R indicates one or a plurality of trivalent elements selected from a group consisting of Sc, In, Y, and a lanthanoid element, A indicates one or a plurality of trivalent elements selected from a group consisting of Fe(III), Ga, and Al, and M indicates one or a plurality of bivalent elements selected from a group consisting of Mg, Mn, Fe(II), Co, Cu, Zn, and Cd). An epitaxially-grown surface is provided on at least one surface of the RAMO4 substrate. An unevenness having a height of 500 nm or more is not provided on the epitaxially-grown surface.
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公开(公告)号:US20200263319A1
公开(公告)日:2020-08-20
申请号:US16739105
申请日:2020-01-09
Inventor: KENTARO MIYANO , NAOYA RYOKI , AKIHIKO ISHIBASHI , MASAKI NOBUOKA
Abstract: A ScAlMgO4 monocrystalline substrate that is highly cleavable and that does not easily cause cracking in the GaN film id grown on the substrate and a method for manufacturing such a ScAlMgO4 monocrystalline substrate are provided. The ScAlMgO4 monocrystalline substrate has a crystal oxygen concentration of 57 atom % or less as measured by inductively coupled plasma atomic emission spectroscopy analysis.
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公开(公告)号:US20180174911A1
公开(公告)日:2018-06-21
申请号:US15825035
申请日:2017-11-28
Inventor: SHINSUKE KOMATSU , YOSHIO OKAYAMA , MASAKI NOBUOKA
CPC classification number: H01L21/7813 , C01F17/0025 , C30B25/18 , C30B29/403 , H01L21/02428 , H01L21/0254 , H01L33/007
Abstract: An RAMO4 substrate that includes an RAMO4 monocrystalline substrate formed of a single crystal represented by general formula RAMO4, wherein R represents one or more trivalent elements selected from the group consisting of Sc, In, Y, and lanthanoid elements, A represents one or more trivalent elements selected from the group consisting of Fe(III), Ga, and Al, and M represents one or more divalent elements selected from the group consisting of Mg, Mn, Fe(II), Co, Cu, Zn, and Cd. The RAMO4 monocrystalline substrate has a principal surface with a plurality of grooves. The principal surface has an off-angle θ with respect to a cleaving surface of the single crystal. The RAMO4 monocrystalline substrate satisfies tan θ≤Wy/Wx, where Wx is the width at the top surface of a raised portion between the grooves, and Wy is the height of the raised portion.
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公开(公告)号:US20200181801A1
公开(公告)日:2020-06-11
申请号:US16691542
申请日:2019-11-21
Inventor: NAOYA RYOKI , KENTARO MIYANO , MASAKI NOBUOKA , AKIHIKO ISHIBASHI
Abstract: A RAMO4 substrate that does not easily crack during or after the formation of group III nitride crystal includes a single crystal represented by general formula RAMO4 (wherein R represents one or more trivalent elements selected from the group consisting of Sc, In, Y, and lanthanoid elements, A represents one or more trivalent elements selected from the group consisting of Fe(III), Ga, and Al, and M represents one or more divalent elements selected from the group consisting of Mg, Mn, Fe(II), Co, Cu, Zn, and Cd). The RAMO4 substrate has a crystal plane with a curvature radius r of 52 m or more, and a square value of correlation coefficient ρ of 0.81 or more. The curvature radius r is calculated as an absolute value from X-ray peak position ωi and measurement position Xi after the measurements of X-ray peak positions ωi at a plurality of positions Xi lying on a straight line passing through the center of the RAMO4 substrate. The correlation coefficient ρ is a measure of correlation between ω and measurement position Xi.
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公开(公告)号:US20170260648A1
公开(公告)日:2017-09-14
申请号:US15411792
申请日:2017-01-20
Inventor: YOSHIO OKAYAMA , MASAKI NOBUOKA
CPC classification number: C30B19/12 , C30B19/02 , C30B19/062 , C30B29/403
Abstract: A method for producing a Group III nitride crystal includes: preparing a protective layer on a region except for an epitaxial growth surface of an RAMO4 substrate containing a single crystal represented by the general formula RAMO4 (wherein R represents one or a plurality of a trivaient element selected from a group of elements including: Sc, In, Y, and a lanthanoid element, A represents one or a plurality of a trivalent element selected from a group of elements including: Fe(III), Ga, and Al, and M represents one or a plurality of a divalent element selected from a group of elements including: Mg, Mn, Fe(II), Co, Cu, Zn, and Cd); and forming a Group III nitride crystal on the epitaxial growth surface of the RAMO4 substrate by a flux method.
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公开(公告)号:US20170239773A1
公开(公告)日:2017-08-24
申请号:US15424244
申请日:2017-02-03
Inventor: YOSHIFUMI TAKASU , YOSHIO OKAYAMA , AKIHIKO ISHIBASHI , ISAO TASHIRO , AKIO UETA , MASAKI NOBUOKA , NAOYA RYOKI
Abstract: A RAMO4 substrate includes a single crystal represented by a formula of RAMO4 (in the formula, R indicates one or a plurality of trivalent elements selected from a group consisting of Sc, In, Y, and a lanthanoid element, A indicates one or a plurality of trivalent elements selected from a group consisting of Fe(III), Ga, and Al, and M indicates one or a plurality of bivalent elements selected from a group consisting of Mg, Mn, Fe(II), Co, Cu, Zn, and Cd). An epitaxially-grown surface is provided on one surface of the RAMO4 substrate, a satin-finish surface is provided on another surface. The satin-finish surface has surface roughness which is larger than that of the epitaxially-grown surface.
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