公开(公告)号：US07084312B1

公开(公告)日：2006-08-01

申请号：US10070275

申请日：2000-08-22

Applicant: Sylvia Huber ,  Michael Jolyon Sprague ,  Boris Breitscheidel ,  Joachim Wulff-Döring ,  Michael Hesse ,  Rolf Pinkos ,  Shelue Liang ,  Otto Kumberger ,  Marc Walter

Inventor： Sylvia Huber ,  Michael Jolyon Sprague ,  Boris Breitscheidel ,  Joachim Wulff-Döring ,  Michael Hesse ,  Rolf Pinkos ,  Shelue Liang ,  Otto Kumberger ,  Marc Walter

IPC: C07C29/136 ,  C07C29/14 ,  C07C29/141 ,  C07C29/143 ,  C07C29/147

CPC classification number: B01J23/80 ,  C07C29/149 ,  C07C31/20

Abstract: A process for the hydrogenation of an organic compound containing at least one carbonyl group comprises bringing the organic compound in the presence of hydrogen into contact with a shaped body which can be produced by a process in which (i) an oxidic material comprising copper oxide, zinc oxide and aluminum oxide is made available, (ii) pulverulent metallic copper or pulverulent cement or a mixture thereof is added to the oxidic material, and (iii) the mixture resulting from (ii) is shaped to form a shaped body.

Abstract translation: 氢化含有至少一个羰基的有机化合物的方法包括使氢存在下的有机化合物与成形体接触，成形体可以通过以下工艺制备，其中（i）包含氧化铜的氧化物， 提供氧化锌和氧化铝，（ii）将粉末状金属铜或粉状水泥或其混合物加入到氧化物中，和（iii）由（ii）得到的混合物成形为成形体。

公开(公告)号：US06524996B1

公开(公告)日：2003-02-25

申请号：US09688881

申请日：2000-10-17

Applicant: Michael Bender ,  Otto Kumberger ,  Michael Hesse

Inventor： Michael Bender ,  Otto Kumberger ,  Michael Hesse

IPC: B01J2370

CPC classification number: B01J23/76 ,  B01D2255/2047 ,  B01D2255/20715 ,  B01D2255/20761 ,  B01D2255/2092 ,  B01D2257/404 ,  B01J23/005 ,  B01J23/72 ,  Y10S502/524

Abstract: The spinel monolith catalyst is obtainable by a) preparing or coating a molding, especially a monolith, with an at least surfacial active composition comprising a spinel of the general formula (I) AxB(1−x)E2O4  (I)  where A is Cu, of which up to half may be replaced by Co, Fe, Ni, Mn or Cr, B is at least one element selected from the group consisting of Zn, Mg, Ca, Zr, Ce, Sn, Ti, V, Mo and W, E is Al, of which up to half may be replaced by Fe2O3, Cr2O3, Ga2O3, La2O3 or mixtures thereof, x is from 0 to 1, preferably 0 to 0.9, b) impregnating the monolith with a solution of at least one compound of elements of transition group 5 of the periodic table or adding these elements in step a) in the form of their oxides or salts, c) drying and optionally calcining.

Abstract translation: 所述尖晶石整体催化剂可通过以下方式得到：a）制备或涂覆模制品，特别是整料，所述至少表面活性​​组合物包含通式（I）的尖晶石，其中A是Cu，其中一半可被Co取代， Fe，Ni，Mn或Cr，B是选自Zn，Mg，Ca，Zr，Ce，Sn，Ti，V，Mo和W中的至少一种元素，E是Al，其中一半以上可以 由Fe 2 O 3，Cr 2 O 3，Ga 2 O 3，La 2 O 3或其混合物代替，x为0至1，优选0至0.9，b）用至少一种元素周期表第5族元素化合物的溶液浸渍整块，或 在步骤a）中以其氧化物或盐的形式加入这些元素，c）干燥和任选煅烧。

公开(公告)号：US06177382B1

公开(公告)日：2001-01-23

申请号：US09275801

申请日：1999-03-25

Applicant: Michael Hesse ,  Otto Kumberger

Inventor： Michael Hesse ,  Otto Kumberger

IPC: B01J2372

CPC classification number: B01D53/8662 ,  B01D53/8628 ,  B01J23/005 ,  B01J37/0009

Abstract: In a process for preparing spinel extrudates by extruding molding compositions comprising spinel powder with or without extrusion assistants, stabilizers, shrinkage reducers, pore-formers or mixtures thereof subsequent drying and calcination of the extrudates, the molding composition further comprises aluminum oxides or aluminum oxide hydrates and metal nitrates.

Abstract translation: 在通过挤出具有或不具有挤出助剂，稳定剂，减缩剂，成孔剂或其混合物的尖晶石粉末的模塑组合物来制备尖晶石挤出物的方法中，随后挤出物的干燥和煅烧，模塑组合物还包含氧化铝或氧化铝水合物 和金属硝酸盐。

公开(公告)号：US09346720B2

公开(公告)日：2016-05-24

申请号：US14113829

申请日：2012-04-27

Applicant: Stefan Iselborn ,  Michael Hesse ,  Piotr Makarczyk

Inventor： Stefan Iselborn ,  Michael Hesse ,  Piotr Makarczyk

IPC: C07C5/25 ,  C07C5/13 ,  C07C6/04 ,  B01J23/44

CPC classification number: C07C5/2512 ,  B01J23/44 ,  B01J27/0573 ,  B01J27/0576 ,  C07C5/13 ,  C07C6/04 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/30 ,  C07C2523/36 ,  C07C2523/44 ,  C07C2523/882 ,  C07C2527/057 ,  Y02P20/52 ,  C07C11/08 ,  C07C11/10 ,  C07C11/107 ,  C07C11/02

Abstract: The present invention relates to a process for isomerizing linear alpha-olefins having from 4 to 8 carbon atoms over a heterogeneous catalyst, wherein the catalyst comprises a hydrogenation metal and a selectivity promoter selected from among selenium and tellurium on a support, and also a process for preparing 1-olefins by a metathesis reaction of 2-olefins with ethene, wherein the 2-olefins are prepared by the above mentioned isomerization process.

Abstract translation: 本发明涉及在非均相催化剂上异构化具有4至8个碳原子的直链α-烯烃的方法，其中催化剂包含氢化金属和在载体上选自硒和碲的选择性促进剂，以及工艺 用于通过2-烯烃与乙烯的复分解反应制备1-烯烃，其中2-烯烃通过上述异构化方法制备。

公开(公告)号：US20120296111A1

公开(公告)日：2012-11-22

申请号：US13516124

申请日：2010-12-14

Applicant: Lucia Königsmann ,  Daniela Mirk ,  Thomas Heidemann ,  Michael Hesse ,  Martin Bock ,  Mario Emmeluth ,  Jutta Bickelhaupt

Inventor： Lucia Königsmann ,  Daniela Mirk ,  Thomas Heidemann ,  Michael Hesse ,  Martin Bock ,  Mario Emmeluth ,  Jutta Bickelhaupt

IPC: B01J23/46 ,  C07C69/75 ,  C07C61/08 ,  C07C211/35 ,  C07C211/36 ,  C07C209/72 ,  C07C5/10 ,  B01J23/42 ,  C07C67/303 ,  C07C51/36 ,  C07C29/20 ,  B01J23/44 ,  C07C35/08

CPC classification number: B01J23/40 ,  B01J21/08 ,  B01J23/462 ,  B01J35/0026 ,  B01J35/0053 ,  B01J35/008 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0201 ,  B01J37/0203 ,  B01J37/0205 ,  C07C5/10 ,  C07C29/20 ,  C07C51/36 ,  C07C67/303 ,  C07C209/72 ,  C07C2521/08 ,  C07C2523/46 ,  C07C2601/14 ,  C07C31/1355 ,  C07C35/21 ,  C07C35/08 ,  C07C61/08 ,  C07C69/75 ,  C07C211/35 ,  C07C211/36

Abstract: The present invention relates to an eggshell catalyst comprising an active metal selected from the group consisting of ruthenium, rhodium, palladium, platinum and mixtures thereof, applied to a support material comprising silicon dioxide, wherein the pore volume of the support material is 0.6 to 1.0 ml/g, determined by Hg porosimetry, the BET surface area is 280 to 500 m2/g, and at least 90% of the pores present have a diameter of 6 to 12 nm, to a process for preparing this eggshell catalyst, to a process for hydrogenating an organic compound which comprises at least one hydrogenatable group using the eggshell catalyst, and to the use of the eggshell catalyst for hydrogenating an organic compound.

Abstract translation: 本发明涉及包含选自钌，铑，钯，铂及其混合物的活性金属的蛋壳催化剂，其应用于包含二氧化硅的载体材料，其中载体材料的孔体积为0.6至1.0 ml / g，通过Hg孔隙率法测定，BET表面积为280-500m2 / g，并且至少90％的孔存在的直径为6至12nm，制备该蛋壳催化剂的方法为 使用蛋壳催化剂氢化含有至少一个可氢化基团的有机化合物的方法，以及使用蛋壳催化剂氢化有机化合物。

公开(公告)号：US08163949B2

公开(公告)日：2012-04-24

申请号：US12987548

申请日：2011-01-10

Applicant: Ulrich Mueller ,  Hermann Puetter ,  Michael Hesse ,  Markus Schubert ,  Helge Wessel ,  Juergen Huff ,  Marcus Guzmann

Inventor： Ulrich Mueller ,  Hermann Puetter ,  Michael Hesse ,  Markus Schubert ,  Helge Wessel ,  Juergen Huff ,  Marcus Guzmann

IPC: C07F1/00 ,  C07F3/00 ,  C07F15/00

CPC classification number: C25B3/12 ,  B01D53/02 ,  B01D2253/204 ,  B01J20/226 ,  B01J20/28014 ,  B01J20/28042 ,  B01J31/1691 ,  B01J31/1805 ,  B01J31/1815 ,  B01J31/2239 ,  B01J31/226 ,  B01J2531/16 ,  B01J2531/26 ,  B01J2531/842 ,  C01B3/0015 ,  C01B21/0455 ,  C01B23/0057 ,  F17C11/005 ,  H01M8/04216 ,  Y02C10/08 ,  Y02E60/327 ,  Y02E60/328 ,  Y02P20/133 ,  Y02P70/56 ,  Y10S95/90 ,  Y10S502/526

Abstract: A method of electrochemically preparing a crystalline, porous, metal-organic framework material comprising at least one at least bidentate organic compound coordinately bound to at least one metal ion, in a reaction medium comprising the at least one bidentate organic compound, wherein at least one metal ion is provided in the reaction medium by the oxidation of one anode comprising the corresponding metal.

Abstract translation: 一种在包含至少一种二齿有机化合物的反应介质中电化学制备结晶多孔的金属 - 有机骨架材料的方法，其包含与至少一种金属离子配位结合的至少二齿有机化合物，其中至少一种 金属离子通过包含相应金属的一个阳极的氧化在反应介质中提供。

公开(公告)号：US08057584B2

公开(公告)日：2011-11-15

申请号：US12299330

申请日：2007-04-26

Applicant: Markus Schubert ,  Ulrich Müller ,  Michael Hesse ,  Kerstin Schierle-Arndt ,  Kai Oertel ,  Ian Faye ,  Thorsten Allgeier ,  Jan-Michael Graehn

Inventor： Markus Schubert ,  Ulrich Müller ,  Michael Hesse ,  Kerstin Schierle-Arndt ,  Kai Oertel ,  Ian Faye ,  Thorsten Allgeier ,  Jan-Michael Graehn

IPC: F17C11/00 ,  B01D53/02

CPC classification number: F17C11/005 ,  F17C11/007 ,  F17C2205/0341 ,  F17C2270/0168 ,  Y10S502/526

Abstract: Hydrogen or methane gas pressure container having a minimum volume of 1 m3 a prescribed maximum filling pressure, has a filter through which oxygen, methane respectively, can flow during uptake. The filter has an adsorbent for adsorbing impurities selected from the group consisting of a higher hydrocarbon, ammonia, an odorous substance, hydrogen sulfide and a mixture of two or more of these substances. The pressure container and the filter comprise porous metal organic frameworks as adsorbent.

Abstract translation: 具有规定的最大填充压力的最小体积为1m 3的氢气或甲烷气体压力容器具有分别在吸收期间氧气，甲烷可以通过其的过滤器。 过滤器具有用于吸附选自高级烃，氨，恶臭物质，硫化氢和这些物质中的两种或更多种的混合物的杂质的吸附剂。 压力容器和过滤器包括作为吸附剂的多孔金属有机骨架。

公开(公告)号：US07931960B2

公开(公告)日：2011-04-26

申请号：US12372118

申请日：2009-02-17

Applicant: Michael Hesse ,  Ulrich Mueller ,  Omar Yaghi

Inventor： Michael Hesse ,  Ulrich Mueller ,  Omar Yaghi

IPC: B32B5/16

CPC classification number: F17C11/005 ,  B01J20/0244 ,  B01J20/226 ,  B01J20/28011 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/3007 ,  B01J20/3035 ,  B01J20/3042 ,  B01J31/1691 ,  B01J35/1028 ,  B01J37/0009 ,  B01J2231/005 ,  B01J2531/26 ,  Y02E60/324 ,  Y10T428/249953 ,  Y10T428/249967 ,  Y10T428/24997 ,  Y10T428/25 ,  Y10T428/298

Abstract: The present invention relates to shaped bodies containing a metal-organic framework material (MOF) as well as a process for the preparation thereof and their use especially as catalyst or storage medium.

Abstract translation: 本发明涉及含有金属 - 有机骨架材料（MOF）的成型体以及其制备方法及其特别用作催化剂或储存介质的用途。

公开(公告)号：US20100056364A1

公开(公告)日：2010-03-04

申请号：US12608125

申请日：2009-10-29

Applicant: Sylvia HUBER-DIRR ,  Michael Hesse ,  Andrea Haunert ,  Henrik Junicke

Inventor： Sylvia HUBER-DIRR ,  Michael Hesse ,  Andrea Haunert ,  Henrik Junicke

IPC: B01J21/18

CPC classification number: C07C29/149 ,  B01J23/83 ,  C07C31/20

Abstract: A process for hydrogenating an organic compound which has at least one carbonyl group, in which the organic compound is hydrogenated in the presence of a shaped article which contains (i) an oxidic material comprising copper oxide, aluminum oxide and lanthanum oxide, and (ii) powdered metallic copper, copper flakes, powdered cement, graphite or a mixture thereof, is provided.

Abstract translation: 氢化具有至少一个羰基的有机化合物的方法，其中有机化合物在成型制品存在下氢化，所述成型制品包含（i）包含氧化铜，氧化铝和氧化镧的氧化物质和（ii ）粉末状金属铜，铜薄片，水泥粉末，石墨或其混合物。

公开(公告)号：US20090281365A1

公开(公告)日：2009-11-12

申请号：US12305450

申请日：2007-06-15

Applicant: Stephan Hatscher ,  Michael Hesse

Inventor： Stephan Hatscher ,  Michael Hesse

IPC: C07C7/12 ,  B01J20/06 ,  B01D53/02 ,  B01D53/62 ,  B01J20/34

CPC classification number: B01D53/864 ,  B01D53/02 ,  B01D2253/112 ,  B01D2255/20715 ,  B01D2255/20761 ,  B01D2257/502 ,  B01J20/06 ,  B01J20/3007 ,  B01J20/3078 ,  B01J20/3236 ,  B01J20/3433 ,  B01J20/3458 ,  B01J20/3483 ,  B01J21/066 ,  B01J23/72 ,  B01J37/0009 ,  B01J37/03 ,  B01J2220/42 ,  B01J2220/56 ,  C07C7/12 ,  C10K1/32 ,  C10K3/04 ,  Y02P20/52 ,  C07C11/06

Abstract: Carbon monoxide is removed from streams by adsorption on an adsorption composition which comprises copper and zirconium oxides but no zinc oxide, which comprises from 70 to 99.8% by weight of copper oxide and from 0.2 to 30% by weight of zirconium oxide, based on the total amount of the adsorption composition.

Abstract translation: 通过在包含铜和锆氧化物但不含氧化锌的吸附组合物上吸附一氧化碳，其包含70至99.8重量％的氧化铜和0.2至30重量％的氧化锆，基于 吸附组合物的总量。