公开(公告)号：US20130061753A1

公开(公告)日：2013-03-14

申请号：US13634416

申请日：2011-03-10

申请人： Masatoshi Fujisawa ,  Isato Morita ,  Yasuyoshi Kato

发明人： Masatoshi Fujisawa ,  Isato Morita ,  Yasuyoshi Kato

IPC分类号： B01D53/14

CPC分类号： B01D53/1493 ,  B01D53/1475 ,  B01D53/8621 ,  B01D2251/102 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01J21/063 ,  B01J23/22 ,  B01J23/28 ,  B01J35/04 ,  B01J37/0203 ,  B01J37/0215 ,  Y02A50/2342 ,  Y02C10/06

摘要： An object of the present invention is to provide a method and a device, which can suppress poisoning due to CO and efficiently remove a low concentration of amines contained in a gas discharged from a CO2 recovery device that uses various absorbing liquids of CO2 even at low temperature. A discharged gas treatment method for removing amines as absorbent contained in a gas discharged from a CO2 removal device, in which the CO2 removal device has used the amines, the method comprising alternatively performing the step of passing the discharged gas through a catalyst-packed bed which is packed with a catalyst composed of titanium oxide and an oxide of vanadium (V) or titanium oxide, an oxide of vanadium and an oxide of molybdenum (Mo) or tungsten (W), to adsorb and remove the amines contained in the discharged gas; and the step of passing heated air through the catalyst-packed bed wherein the amines are adsorbed thereon to heat the catalyst, and at the same time performing elimination and oxidative decomposition of the adsorbed amines.

摘要翻译： 本发明的目的是提供一种方法和装置，其可以抑制由于CO引起的中毒，并且有效地除去使用各种CO 2的吸收液体的CO 2回收装置排出的气体中所含的低浓度的胺， 温度。 一种排出气体处理方法，用于除去从CO 2除去装置排出的气体中含有的吸收剂作为吸收剂，其中CO 2除去装置已经使用了胺，该方法还包括使排气通过催化剂填充床 填充有由氧化钛和钒（V）或氧化钛的氧化物，钒的氧化物和钼（Mo）或钨（W）的氧化物组成的催化剂，以吸附和除去排出的胺 加油站; 以及使热空气通过催化剂填充床的步骤，其中胺吸附在其上以加热催化剂，同时进行吸附的胺的消除和氧化分解。

公开(公告)号：US6063342A

公开(公告)日：2000-05-16

申请号：US48053

申请日：1998-03-26

申请人： Yasuyoshi Kato ,  Tomihisa Ishikawa ,  Yoshinori Nagai ,  Isato Morita ,  Masato Mukai ,  Akihiro Yamada ,  Takashi Michimoto ,  Masaharu Morii ,  Hiroshi Kuroda

发明人： Yasuyoshi Kato ,  Tomihisa Ishikawa ,  Yoshinori Nagai ,  Isato Morita ,  Masato Mukai ,  Akihiro Yamada ,  Takashi Michimoto ,  Masaharu Morii ,  Hiroshi Kuroda

IPC分类号： B01D53/34 ,  B01D53/38 ,  B01D53/86 ,  B01J35/02 ,  B01J35/04 ,  F01N3/28 ,  B01D50/00

CPC分类号： F01N3/2821 ,  B01D53/8631 ,  B01J35/02 ,  B01J35/04 ,  F01N3/2814 ,  F01N2330/42

摘要： A catalyst unit is constructed by alternately stacking rectangular catalyst elements (1) formed by cutting catalyst support plates coated with a catalytic material and having ribs (2) inclined at 45.degree. to one specified side edge (1a) of each thereof, and those turned upside down in a case, and the catalyst unit is disposed in a gas passage with the ribs (2) of the catalyst elements (1) inclined at an angle greater than 0.degree. and smaller than 90.degree. to the direction of the gas flow (6). When the catalyst unit comprising the catalyst elements (1) coated with a denitrating catalyst is placed in the gas passage, the ribs (2) of the catalyst elements (1) blocks the gas flow (6) and generate turbulent currents on the downstream side thereof to promote the contact of ammonia and NOx contained in the exhaust gas with the catalyst. When the gas flow (6) is disturbed, the thickness of laminar films covering the surface of the catalyst elements (1) is reduced, so that ammonia and NOx can be easily diffused and the catalytic activity can be enhanced. The catalyst elements exhibits their catalytic abilities effectively without entailing significant pressure loss in the gas flow.

摘要翻译： 催化剂单元通过交替堆叠通过切割涂覆有催化材料的催化剂支撑板形成的矩形催化剂元件（1），并且具有倾斜45°的肋（2）与其每个的特定侧边（1a） 并且催化剂单元设置在气体通道中，其中催化剂元件（1）的肋（2）相对于气流的方向倾斜大于0°且小于90°（ 6）。 当包含涂有脱硝催化剂的催化剂元件（1）的催化剂单元被放置在气体通道中时，催化剂元件（1）的肋（2）阻挡气流（6）并在下游侧产生湍流 以促进废气中所含的氨和NOx与催化剂的接触。 当气流（6）被扰乱时，覆盖催化剂元件（1）表面的层状膜的厚度减小，使得氨和NOx容易扩散并且可以提高催化活性。 催化剂元素显示出其催化能力，而不会在气流中产生明显的压力损失。

公开(公告)号：US5792432A

公开(公告)日：1998-08-11

申请号：US648139

申请日：1996-05-12

申请人： Yasuyoshi Kato ,  Tomihisa Ishikawa ,  Yoshinori Nagai ,  Isato Morita ,  Masato Mukai ,  Akihiro Yamada ,  Takashi Michimoto ,  Masaharu Morii ,  Hiroshi Kuroda

发明人： Yasuyoshi Kato ,  Tomihisa Ishikawa ,  Yoshinori Nagai ,  Isato Morita ,  Masato Mukai ,  Akihiro Yamada ,  Takashi Michimoto ,  Masaharu Morii ,  Hiroshi Kuroda

IPC分类号： B01D53/34 ,  B01D53/38 ,  B01D53/86 ,  B01J35/02 ,  B01J35/04 ,  F01N3/28 ,  B01D50/00

CPC分类号： F01N3/2821 ,  B01D53/8631 ,  B01J35/02 ,  B01J35/04 ,  F01N3/2814 ,  F01N2330/42

摘要： A catalyst unit is constructed by alternately stacking rectangular catalyst elements (1) formed by cutting catalyst support plates coated with a catalytic material and having ribs (2) inclined at 45.degree. to one specified side edge (1a) of each thereof, and those turned upside down in a case, and the catalyst unit is disposed in a gas passage with the ribs (2) of the catalyst elements (1) inclined at an angle greater than 0.degree. and smaller than 90.degree. to the direction of the gas flow (6). When the catalyst unit comprising the catalyst elements (1) coated with a denitrating catalyst is placed in the gas passage, the ribs (2) of the catalyst elements (1) blocks the gas flow (6) and generate turbulent currents on the downstream side thereof to promote the contact of ammonia and NOx contained in the exhaust gas with the catalyst. When the gas flow (6) is disturbed, the thickness of laminar films covering the surface of the catalyst elements (1) is reduced, so that ammonia and NOx can be easily diffused and the catalytic activity can be enhanced. The catalyst elements exhibits their catalytic abilities effectively without entailing significant pressure loss in the gas flow.

摘要翻译： PCT No.PCT / JP95 / 02323 Sec。 371日期：1996年5月21日 102（e）日期1996年5月21日PCT提交1995年5月14日PCT公布。 公开号WO96 / 14920 PCT 日期1996年5月23日催化剂单元通过交替堆叠通过切割涂覆有催化材料的催化剂载体板形成的矩形催化剂元件（1），并且具有倾斜45°的肋（2）至其每一个的特定侧边缘（1a） ，并且在一种情况下翻转的那些，催化剂单元设置在气体通道中，其中催化剂元件（1）的肋（2）以大于0°并且小于90°的角度倾斜 气流（6）。 当包含涂有脱硝催化剂的催化剂元件（1）的催化剂单元被放置在气体通道中时，催化剂元件（1）的肋（2）阻挡气流（6）并在下游侧产生湍流 以促进废气中所含的氨和NOx与催化剂的接触。 当气流（6）被扰乱时，覆盖催化剂元件（1）表面的层状膜的厚度减小，使得氨和NOx容易扩散并且可以提高催化活性。 催化剂元素显示出其催化能力，而不会在气流中产生明显的压力损失。

公开(公告)号：US5409681A

公开(公告)日：1995-04-25

申请号：US980182

申请日：1992-11-23

申请人： Yasuyoshi Kato ,  Kunihiko Konishi ,  Fumito Nakajima ,  Ikuhisa Hamada ,  Isato Morita

发明人： Yasuyoshi Kato ,  Kunihiko Konishi ,  Fumito Nakajima ,  Ikuhisa Hamada ,  Isato Morita

IPC分类号： B01D53/94 ,  B01J23/40 ,  B01J23/652 ,  B01J37/02 ,  B01J8/00 ,  B01J21/04

CPC分类号： B01J37/0201 ,  B01D53/9418 ,  B01J23/40 ,  B01J23/652 ,  B01D2251/2062 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/1025 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776

摘要： A catalyst for purifying an exhaust gas includes a first component having activity for reducing nitrogen oxides with ammonia and a second component having at least one of activity for forming nitrogen oxide from ammonia and activity for forming carbon dioxide from carbon monoxide. The first component is a composition containing an oxide of at least one member selected from titanium, vanadium, tungsten and molybdenum and the second component is a composition containing a salt of a noble metal selected from platinum, palladium and rhodium or any one of these noble metals supported on a porous material selected from zeolites, alumina and silica. The invention further provides a method for purifying an exhaust gas containing NOx, CO and leak NH.sub.3 using the catalyst.

摘要翻译： 用于净化废气的催化剂包括具有用氨还原氮氧化物的活性的第一成分和具有从氨形成氮氧化物的活性中的至少一种和从一氧化碳形成二氧化碳的活性中的至少一种的第二成分。 第一组分是含有选自钛，钒，钨和钼中的至少一种的氧化物的组合物，第二组分是含有选自铂，钯和铑的贵金属的盐或这些贵金属中的任何一种的组合物 负载在选自沸石，氧化铝和二氧化硅的多孔材料上的金属。 本发明还提供一种使用催化剂净化含有NOx，CO和泄漏NH 3的废气的方法。

公开(公告)号：US08202482B2

公开(公告)日：2012-06-19

申请号：US12373817

申请日：2006-07-26

申请人： Yoshinori Nagai ,  Toshio Katsube ,  Isato Morita ,  Hirofumi Kikkawa ,  Yasuyoshi Kato

发明人： Yoshinori Nagai ,  Toshio Katsube ,  Isato Morita ,  Hirofumi Kikkawa ,  Yasuyoshi Kato

IPC分类号： B01D46/02

CPC分类号： B01D53/75 ,  B01D46/0027 ,  B01D46/02 ,  B01D53/501 ,  B01D53/8625 ,  B01D53/8665 ,  B01D2257/2045 ,  B01D2257/602 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/06 ,  B01J37/0036 ,  B01J37/0063 ,  B01J37/0215

摘要： An apparatus for removing of traces of toxic substances from exhaust gas, comprising, disposed in sequence from the upstream side in a flow channel of exhaust gas emitted from combustion equipment, a denitration unit including a denitration catalyst layer capable of removing nitrogen oxides from the exhaust gas and capable of oxidizing metallic mercury; an air preheater adapted for heat exchange between air for combustion in the combustion equipment and the exhaust gas; a dust removal unit having a bag filter containing a catalyst for metallic mercury oxidation; and a desulfurization unit for removing sulfur oxide from the exhaust gas. The bag filter may be disposed in advance of the desulfurization unit. Thus, there can be provided an apparatus for removing of traces of toxic substances from exhaust gas that is stable over a prolonged period of time and is highly reliable; and provided a method of operating the same.

摘要翻译： 一种用于从废气中除去有毒物质痕迹的装置，包括从燃烧设备排出的排气流动通道中的上游侧依次设置的脱硝单元，该脱硝单元包括能够从排气中除去氮氧化物的脱硝催化剂层 气体和能够氧化金属汞; 空气预热器，其适于在燃烧设备中的燃烧空气和废气之间进行热交换; 除尘单元，其具有包含用于金属汞氧化的催化剂的袋式过滤器; 以及用于从废气中除去硫氧化物的脱硫单元。 袋式过滤器可以在脱硫单元之前设置。 因此，可以提供一种用于从长时间内稳定的排气中除去痕量有毒物质并且高可靠性的装置; 并提供了一种操作该方法的方法。

公开(公告)号：US20100000410A1

公开(公告)日：2010-01-07

申请号：US12373817

申请日：2006-07-26

申请人： Yoshinori Nagai ,  Toshio Katsube ,  Isato Morita ,  Hirofumi Kikkawa ,  Yasuyoshi Kato

发明人： Yoshinori Nagai ,  Toshio Katsube ,  Isato Morita ,  Hirofumi Kikkawa ,  Yasuyoshi Kato

IPC分类号： B01D46/10 ,  B01D59/50

CPC分类号： B01D53/75 ,  B01D46/0027 ,  B01D46/02 ,  B01D53/501 ,  B01D53/8625 ,  B01D53/8665 ,  B01D2257/2045 ,  B01D2257/602 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J35/06 ,  B01J37/0036 ,  B01J37/0063 ,  B01J37/0215

摘要： An apparatus for removing of traces of toxic substances from exhaust gas, comprising, disposed in sequence from the upstream side in a flow channel of exhaust gas emitted from combustion equipment, a denitration unit including a denitration catalyst layer capable of removing nitrogen oxides from the exhaust gas and capable of oxidizing metallic mercury; an air preheater adapted for heat exchange between air for combustion in the combustion equipment and the exhaust gas; a dust removal unit having a bag filter containing a catalyst for metallic mercury oxidation; and a desulfurization unit for removing sulfur oxide from the exhaust gas. The bag filter may be disposed in advance of the desulfurization unit. Thus, there can be provided an apparatus for removing of traces of toxic substances from exhaust gas that is stable over a prolonged period of time and is highly reliable; and provided a method of operating the same.

摘要翻译： 一种用于从废气中除去有毒物质痕迹的装置，包括从燃烧设备排出的排气流动通道中的上游侧依次设置的脱硝单元，该脱硝单元包括能够从排气中除去氮氧化物的脱硝催化剂层 气体和能够氧化金属汞; 空气预热器，其适于在燃烧设备中的燃烧空气和废气之间进行热交换; 除尘单元，其具有包含用于金属汞氧化的催化剂的袋式过滤器; 以及用于从废气中除去硫氧化物的脱硫单元。 袋式过滤器可以在脱硫单元之前设置。 因此，可以提供一种用于从长时间内稳定的排气中除去痕量有毒物质并且高可靠性的装置; 并提供了一种操作该方法的方法。

公开(公告)号：US06759565B1

公开(公告)日：2004-07-06

申请号：US10130155

申请日：2002-08-13

申请人： Yasuyoshi Kato ,  Masatoshi Fujisawa

发明人： Yasuyoshi Kato ,  Masatoshi Fujisawa

IPC分类号： A62D300

CPC分类号： B01J21/063 ,  B01D53/8625 ,  B01D53/8662 ,  B01D2257/2064 ,  B01D2257/404 ,  B01J23/22 ,  B01J23/28

摘要： The invention is to provide (1) a method for decomposing chlorine containing organic compounds (DXNs) contained in an exhaust gas in which method a high decomposition ratio of the DXNs can be obtained even at a low temperature and the effects by SOx can be repressed to a minimum and (2) a method for treating a used catalyst; the method for decomposing DXNs contained in an exhaust gas comprises contacting the DXNs contained in the exhaust gas with nitrogen dioxide (NO2) which is contained in the exhaust gas or added from the outside into the exhaust gas at 100 to 450° C. in the presence of a catalyst comprising a titanium oxideu, molybdenum oxide, and vanadium oxide, the contents of Ti, Mo, and V in which catalyst being in the range of 99 to 70/0.5 to 15/0.5 to 15 in terms of atomic ratio, respectively, to oxidatively decompose the DXNs with the nitrogen dioxide; and acocording to the method for treating a used catalyst, the DXNs adhered to the catalyst can be made innoxious by contacting the used catalyst with a gas containing NO2 to oxidatively decompose the DXN2 adhered to the catalyst, with the NO2.

摘要翻译： 本发明提供（1）在废气中分解含氯有机化合物（DXN）的方法，其中即使在低温下也能获得DXN的高分解率的方法，并且可以抑制SOx的影响 （2）用于处理使用的催化剂的方法;废气中包含的DXN的分解方法包括将废气中包含的DXN与废气中所含的二氧化氮（NO 2）接触或从 在含有氧化钛，氧化钼和氧化钒的催化剂的存在下，在100〜450℃下将废气的外部进入到废气中，其中催化剂的含量在99〜 70 / 0.5〜15 / 0.5〜15，分别用二氧化氮氧化分解DXN; 并且根据用于处理使用的催化剂的方法，通过使所使用的催化剂与含有NO 2的气体接触来使附着在催化剂上的DXN2与NO2一起氧化分解催化剂的DXN2，可以使附着在催化剂上的DXN变得无毒。

公开(公告)号：US20110183839A1

公开(公告)日：2011-07-28

申请号：US13056142

申请日：2009-07-29

申请人： Masatoshi Fujisawa ,  Yasuyoshi Kato

发明人： Masatoshi Fujisawa ,  Yasuyoshi Kato

IPC分类号： B01J27/055 ,  B01J37/02 ,  B01J37/08

CPC分类号： B01J27/055 ,  B01D53/8628 ,  B01D2251/208 ,  B01D2255/104 ,  B01D2255/2092 ,  B01J37/0205

摘要： Provided is a silver-supported alumina catalyst for reducing nitrogen oxides using ethanol, which has the drawbacks of the conventional silver-supported alumina catalysts improved, has high performance, is not likely to deteriorate over time, and has excellent initial performance and durability.A catalyst for purifying nitrogen oxides, which purifies nitrogen oxides in exhaust gas using an alcohol as a reducing agent, and contains alumina, aluminum sulfate and silver as main components.

摘要翻译： 本发明提供一种使用乙醇还原氮氧化物的银负载氧化铝催化剂，其具有改进的常规银负载型氧化铝催化剂的缺点，具有高性能，不易随时间劣化，并且具有优异的初始性能和耐久性。 一种用于净化氮氧化物的催化剂，其使用醇作为还原剂净化废气中的氮氧化物，并且包含氧化铝，硫酸铝和银作为主要成分。

公开(公告)号：US06710013B1

公开(公告)日：2004-03-23

申请号：US09763779

申请日：2001-04-20

申请人： Yasuyoshi Kato ,  Kouichi Yokoyama ,  Eiji Miyamoto ,  Masatoshi Fujisawa

发明人： Yasuyoshi Kato ,  Kouichi Yokoyama ,  Eiji Miyamoto ,  Masatoshi Fujisawa

IPC分类号： B01J2300

CPC分类号： B01J21/063 ,  B01D53/8628 ,  B01D53/8631 ,  B01D53/8678 ,  B01D53/885 ,  B01D53/9413 ,  B01D53/9431 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/9207 ,  B01J19/32 ,  B01J23/22 ,  B01J23/24 ,  B01J35/02 ,  B01J35/04 ,  B01J2219/3221 ,  B01J2219/32213 ,  B01J2219/32237 ,  B01J2219/32262 ,  B01J2219/32286 ,  B01J2219/32408 ,  B01J2219/32425 ,  B01J2219/32441 ,  B01J2219/32466 ,  B01J2219/326 ,  F01N3/281 ,  F01N3/2814 ,  F01N3/2821 ,  F01N2330/02 ,  F01N2330/06 ,  F01N2330/12 ,  F01N2330/321 ,  F01N2330/323 ,  F01N2330/324 ,  F01N2330/38

摘要： Provided is a catalyst structure used for purifying an exhaust gas; to be disposed in an exhaust gas flow passage; preferable for obtaining a highly efficient and compact exhaust gas purifying apparatus; and produced by alternately stacking platelike catalysts 1, and gas dispersing members composed of netlike products 7 having many holes passing from the front surface to the back surface thereof, or linear, belt-shaped, or rodlike materials of a metal, ceramic, or glass to disturb the flow of an exhaust gas in a flow passage of the gas thereby to promote contact of the gas to be treated with the catalyst.

摘要翻译： 提供了用于净化废气的催化剂结构; 设置在排气流路中; 优选用于获得高效且紧凑的废气净化装置; 并且通过交替层叠的催化剂1和由具有从其前表面延伸到其后表面的许多孔的网状产品7或由金属，陶瓷或玻璃的直线形，带状或棒状材料组成的气体分散构件来产生干扰 气体的流路中的排气的流动，从而促进被处理气体与催化剂的接触。

公开(公告)号：US20120213683A1

公开(公告)日：2012-08-23

申请号：US13388301

申请日：2010-08-02

申请人： Yasuyoshi Kato ,  Masatoshi Fujisawa

发明人： Yasuyoshi Kato ,  Masatoshi Fujisawa

IPC分类号： B01D53/62

CPC分类号： B01D53/1475 ,  B01D53/8621 ,  B01D53/90 ,  B01D2251/10 ,  B01D2252/204 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2257/30 ,  B01D2257/404 ,  B01D2257/504 ,  F23J2215/50 ,  F23J2219/40 ,  Y02C10/04 ,  Y02C10/06

摘要： Provided is a method capable of removing a low concentration of amines contained in an exhaust gas that is discharged from a CO2 recovery process, at low temperature with high efficiency.A method of treating an exhaust gas containing carbon dioxide, the method including absorbing and removing CO2 by bringing an exhaust gas containing carbon dioxide (CO2) and nitrogen oxides, into contact with a CO2 absorbent liquid containing amines, subsequently bringing the resultant into contact with a catalyst comprising titanium oxide and an oxide of vanadium (V), or from titanium oxide, an oxide of vanadium (V) and an oxide of molybdenum (Mo) or tungsten (W), at a temperature of 130° C. to 250° C., and thereby oxidizing and removing the amines.

摘要翻译： 提供了一种能够在低温高效率地从CO 2回收工序中排出的废气中除去低浓度的胺的方法。 一种处理含有二氧化碳的废气的方法，该方法包括通过使含有二氧化碳（CO 2）和氮氧化物的废气与含有胺的CO 2吸收剂液体接触来吸收和除去CO 2，随后将所得物与 在130℃至250℃的温度下，包含氧化钛和钒（V）的氧化物或氧化钛，钒（V）和钼（Mo）或钨（W）的氧化物的氧化物的催化剂 ℃，从而氧化和除去胺。