公开(公告)号：US08664141B2

公开(公告)日：2014-03-04

申请号：US13056142

申请日：2009-07-29

申请人： Masatoshi Fujisawa ,  Yasuyoshi Kato

发明人： Masatoshi Fujisawa ,  Yasuyoshi Kato

IPC分类号： C08F4/60 ,  B01J21/00 ,  B01J27/055 ,  B01D53/56 ,  C01B21/072 ,  C01B17/96

CPC分类号： B01J27/055 ,  B01D53/8628 ,  B01D2251/208 ,  B01D2255/104 ,  B01D2255/2092 ,  B01J37/0205

摘要： Provided is a silver-supported alumina catalyst for reducing nitrogen oxides using ethanol, which has the drawbacks of the conventional silver-supported alumina catalysts improved, has high performance, is not likely to deteriorate over time, and has excellent initial performance and durability.A catalyst for purifying nitrogen oxides, which purifies nitrogen oxides in exhaust gas using an alcohol as a reducing agent, and contains alumina, aluminum sulfate and silver as main components.

摘要翻译： 本发明提供一种使用乙醇还原氮氧化物的银负载氧化铝催化剂，其具有改进的常规银负载型氧化铝催化剂的缺点，具有高性能，不易随时间劣化，并且具有优异的初始性能和耐久性。 一种用于净化氮氧化物的催化剂，其使用醇作为还原剂净化废气中的氮氧化物，并且包含氧化铝，硫酸铝和银作为主要成分。

公开(公告)号：US07824635B2

公开(公告)日：2010-11-02

申请号：US10580720

申请日：2004-11-24

申请人： Yasuyoshi Kato ,  Eiji Miyamoto ,  Masatoshi Fujisawa ,  Naomi Imada ,  Hiroshi Ishizaka ,  Kazuki Kobayashi ,  Takeshi Hirota

发明人： Yasuyoshi Kato ,  Eiji Miyamoto ,  Masatoshi Fujisawa ,  Naomi Imada ,  Hiroshi Ishizaka ,  Kazuki Kobayashi ,  Takeshi Hirota

IPC分类号： B01D53/94 ,  B01D46/00 ,  B01D35/00 ,  B01J35/00 ,  F01N3/035

CPC分类号： B01J37/0225 ,  B01D39/12 ,  B01D53/9431 ,  B01J23/40 ,  F01N3/022 ,  F01N3/035 ,  F01N2330/02 ,  F01N2330/42 ,  Y10T442/109 ,  Y10T442/121

摘要： A particulate material removing filter for exhaust gas from a diesel engine is provided. The particulate material removing filter is formed by laminating metal laths having an oxidation catalyst layer containing a noble metal that oxidizes nitrogen oxide in exhaust gas into nitrogen dioxide. The metal laths are laminated to form a laminate in such a manner that the drawing direction of the metal lath processing differs by 90 degrees with each other.

摘要翻译： 提供了一种用于来自柴油发动机的废气的颗粒物质除去过滤器。 颗粒材料去除过滤器是通过层压具有氧化催化剂层的金属板条形成的，该氧化催化剂层含有将废气中的氮氧化物氧化成二氧化氮的贵金属。 金属板条被层压以形成层压体，使得金属板条加工的拉伸方向彼此相差90度。

公开(公告)号：US07005402B1

公开(公告)日：2006-02-28

申请号：US10415320

申请日：2000-10-26

申请人： Yasuyoshi Kato ,  Kouichi Yokoyama ,  Masatoshi Fujisawa

发明人： Yasuyoshi Kato ,  Kouichi Yokoyama ,  Masatoshi Fujisawa

IPC分类号： B01J27/24

CPC分类号： B01D53/8628 ,  B01D53/86 ,  B01D53/865 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01J21/063 ,  B01J21/12 ,  B01J23/002 ,  B01J23/22 ,  B01J23/28 ,  B01J27/24 ,  B01J37/0213 ,  B01J2523/00 ,  C01G39/006 ,  C01P2004/80 ,  C01P2006/12 ,  C01P2006/60 ,  C01P2006/80 ,  C01P2006/82 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/41

摘要： The invention is to provide (i) a catalyst which does not require an activation of catalyst components by means of a calcination which has become a hindrance in the way of obtaining a catalyst having a high activity through a conventional technology and in which catalyst the compositing of vanadium with molybdenum is contemplated more than enough; ii) a method for producing the catalyst; (iii) a catalyst having an activity, especially having an activity at low temperatures and a durability both greatly increased; (iv) a catalyst compound for purifying an exhaust gas, in which compound the ratio of vanadium atom to molybdenum atom (V/Mo) is 3/2 or close thereto and which compound is expressed by the rational formula (NH4)xMo2VxO(3x+6) wherein x is 2.8 to 3.2; and (v) a method for producing the catalyst compound through a step for reacting molybdenum oxide (MoO3) with ammonium metavanadate (NH4VO3) in the co-presence of water for a prescribed period of time.

摘要翻译： 本发明提供（i）催化剂，其通过煅烧不需要活化催化剂组分，该煅烧已经成为通过常规技术获得具有高活性的催化剂的障碍，并且其中催化剂的合成 的钒被认为是足够的; ii）催化剂的制造方法; （iii）具有活性的催化剂，特别是在低温下具有活性，耐久性大大增加; （iv）用于净化废气的催化剂化合物，其中钒原子与钼原子的比例（V / Mo）为3/2或接近其中，化合物由合理式（NH 4）表示 （3x + 6）其中x为2.8至3.2（x）x ; 和（v）通过使氧化钼（MoO 3 N 3）与偏钒酸铵（NH 3 VO 3）的反应的步骤制备催化剂化合物的方法 >）在水中共存一段规定的时间。

公开(公告)号：US06710013B1

公开(公告)日：2004-03-23

申请号：US09763779

申请日：2001-04-20

申请人： Yasuyoshi Kato ,  Kouichi Yokoyama ,  Eiji Miyamoto ,  Masatoshi Fujisawa

发明人： Yasuyoshi Kato ,  Kouichi Yokoyama ,  Eiji Miyamoto ,  Masatoshi Fujisawa

IPC分类号： B01J2300

CPC分类号： B01J21/063 ,  B01D53/8628 ,  B01D53/8631 ,  B01D53/8678 ,  B01D53/885 ,  B01D53/9413 ,  B01D53/9431 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2255/9207 ,  B01J19/32 ,  B01J23/22 ,  B01J23/24 ,  B01J35/02 ,  B01J35/04 ,  B01J2219/3221 ,  B01J2219/32213 ,  B01J2219/32237 ,  B01J2219/32262 ,  B01J2219/32286 ,  B01J2219/32408 ,  B01J2219/32425 ,  B01J2219/32441 ,  B01J2219/32466 ,  B01J2219/326 ,  F01N3/281 ,  F01N3/2814 ,  F01N3/2821 ,  F01N2330/02 ,  F01N2330/06 ,  F01N2330/12 ,  F01N2330/321 ,  F01N2330/323 ,  F01N2330/324 ,  F01N2330/38

摘要： Provided is a catalyst structure used for purifying an exhaust gas; to be disposed in an exhaust gas flow passage; preferable for obtaining a highly efficient and compact exhaust gas purifying apparatus; and produced by alternately stacking platelike catalysts 1, and gas dispersing members composed of netlike products 7 having many holes passing from the front surface to the back surface thereof, or linear, belt-shaped, or rodlike materials of a metal, ceramic, or glass to disturb the flow of an exhaust gas in a flow passage of the gas thereby to promote contact of the gas to be treated with the catalyst.

摘要翻译： 提供了用于净化废气的催化剂结构; 设置在排气流路中; 优选用于获得高效且紧凑的废气净化装置; 并且通过交替层叠的催化剂1和由具有从其前表面延伸到其后表面的许多孔的网状产品7或由金属，陶瓷或玻璃的直线形，带状或棒状材料组成的气体分散构件来产生干扰 气体的流路中的排气的流动，从而促进被处理气体与催化剂的接触。

公开(公告)号：US20130061753A1

公开(公告)日：2013-03-14

申请号：US13634416

申请日：2011-03-10

申请人： Masatoshi Fujisawa ,  Isato Morita ,  Yasuyoshi Kato

发明人： Masatoshi Fujisawa ,  Isato Morita ,  Yasuyoshi Kato

IPC分类号： B01D53/14

CPC分类号： B01D53/1493 ,  B01D53/1475 ,  B01D53/8621 ,  B01D2251/102 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01J21/063 ,  B01J23/22 ,  B01J23/28 ,  B01J35/04 ,  B01J37/0203 ,  B01J37/0215 ,  Y02A50/2342 ,  Y02C10/06

摘要： An object of the present invention is to provide a method and a device, which can suppress poisoning due to CO and efficiently remove a low concentration of amines contained in a gas discharged from a CO2 recovery device that uses various absorbing liquids of CO2 even at low temperature. A discharged gas treatment method for removing amines as absorbent contained in a gas discharged from a CO2 removal device, in which the CO2 removal device has used the amines, the method comprising alternatively performing the step of passing the discharged gas through a catalyst-packed bed which is packed with a catalyst composed of titanium oxide and an oxide of vanadium (V) or titanium oxide, an oxide of vanadium and an oxide of molybdenum (Mo) or tungsten (W), to adsorb and remove the amines contained in the discharged gas; and the step of passing heated air through the catalyst-packed bed wherein the amines are adsorbed thereon to heat the catalyst, and at the same time performing elimination and oxidative decomposition of the adsorbed amines.

摘要翻译： 本发明的目的是提供一种方法和装置，其可以抑制由于CO引起的中毒，并且有效地除去使用各种CO 2的吸收液体的CO 2回收装置排出的气体中所含的低浓度的胺， 温度。 一种排出气体处理方法，用于除去从CO 2除去装置排出的气体中含有的吸收剂作为吸收剂，其中CO 2除去装置已经使用了胺，该方法还包括使排气通过催化剂填充床 填充有由氧化钛和钒（V）或氧化钛的氧化物，钒的氧化物和钼（Mo）或钨（W）的氧化物组成的催化剂，以吸附和除去排出的胺 加油站; 以及使热空气通过催化剂填充床的步骤，其中胺吸附在其上以加热催化剂，同时进行吸附的胺的消除和氧化分解。

公开(公告)号：US06759565B1

公开(公告)日：2004-07-06

申请号：US10130155

申请日：2002-08-13

申请人： Yasuyoshi Kato ,  Masatoshi Fujisawa

发明人： Yasuyoshi Kato ,  Masatoshi Fujisawa

IPC分类号： A62D300

CPC分类号： B01J21/063 ,  B01D53/8625 ,  B01D53/8662 ,  B01D2257/2064 ,  B01D2257/404 ,  B01J23/22 ,  B01J23/28

摘要： The invention is to provide (1) a method for decomposing chlorine containing organic compounds (DXNs) contained in an exhaust gas in which method a high decomposition ratio of the DXNs can be obtained even at a low temperature and the effects by SOx can be repressed to a minimum and (2) a method for treating a used catalyst; the method for decomposing DXNs contained in an exhaust gas comprises contacting the DXNs contained in the exhaust gas with nitrogen dioxide (NO2) which is contained in the exhaust gas or added from the outside into the exhaust gas at 100 to 450° C. in the presence of a catalyst comprising a titanium oxideu, molybdenum oxide, and vanadium oxide, the contents of Ti, Mo, and V in which catalyst being in the range of 99 to 70/0.5 to 15/0.5 to 15 in terms of atomic ratio, respectively, to oxidatively decompose the DXNs with the nitrogen dioxide; and acocording to the method for treating a used catalyst, the DXNs adhered to the catalyst can be made innoxious by contacting the used catalyst with a gas containing NO2 to oxidatively decompose the DXN2 adhered to the catalyst, with the NO2.

摘要翻译： 本发明提供（1）在废气中分解含氯有机化合物（DXN）的方法，其中即使在低温下也能获得DXN的高分解率的方法，并且可以抑制SOx的影响 （2）用于处理使用的催化剂的方法;废气中包含的DXN的分解方法包括将废气中包含的DXN与废气中所含的二氧化氮（NO 2）接触或从 在含有氧化钛，氧化钼和氧化钒的催化剂的存在下，在100〜450℃下将废气的外部进入到废气中，其中催化剂的含量在99〜 70 / 0.5〜15 / 0.5〜15，分别用二氧化氮氧化分解DXN; 并且根据用于处理使用的催化剂的方法，通过使所使用的催化剂与含有NO 2的气体接触来使附着在催化剂上的DXN2与NO2一起氧化分解催化剂的DXN2，可以使附着在催化剂上的DXN变得无毒。

公开(公告)号：US20120213683A1

公开(公告)日：2012-08-23

申请号：US13388301

申请日：2010-08-02

申请人： Yasuyoshi Kato ,  Masatoshi Fujisawa

发明人： Yasuyoshi Kato ,  Masatoshi Fujisawa

IPC分类号： B01D53/62

CPC分类号： B01D53/1475 ,  B01D53/8621 ,  B01D53/90 ,  B01D2251/10 ,  B01D2252/204 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01D2257/30 ,  B01D2257/404 ,  B01D2257/504 ,  F23J2215/50 ,  F23J2219/40 ,  Y02C10/04 ,  Y02C10/06

摘要： Provided is a method capable of removing a low concentration of amines contained in an exhaust gas that is discharged from a CO2 recovery process, at low temperature with high efficiency.A method of treating an exhaust gas containing carbon dioxide, the method including absorbing and removing CO2 by bringing an exhaust gas containing carbon dioxide (CO2) and nitrogen oxides, into contact with a CO2 absorbent liquid containing amines, subsequently bringing the resultant into contact with a catalyst comprising titanium oxide and an oxide of vanadium (V), or from titanium oxide, an oxide of vanadium (V) and an oxide of molybdenum (Mo) or tungsten (W), at a temperature of 130° C. to 250° C., and thereby oxidizing and removing the amines.

摘要翻译： 提供了一种能够在低温高效率地从CO 2回收工序中排出的废气中除去低浓度的胺的方法。 一种处理含有二氧化碳的废气的方法，该方法包括通过使含有二氧化碳（CO 2）和氮氧化物的废气与含有胺的CO 2吸收剂液体接触来吸收和除去CO 2，随后将所得物与 在130℃至250℃的温度下，包含氧化钛和钒（V）的氧化物或氧化钛，钒（V）和钼（Mo）或钨（W）的氧化物的氧化物的催化剂 ℃，从而氧化和除去胺。

公开(公告)号：US06833117B1

公开(公告)日：2004-12-21

申请号：US09530844

申请日：2000-06-14

申请人： Yasuyoshi Kato ,  Yoshinori Nagai ,  Kouichi Yokoyama ,  Naomi Yoshida ,  Takashi Michimoto ,  Eiji Miyamoto ,  Masatoshi Fujisawa

发明人： Yasuyoshi Kato ,  Yoshinori Nagai ,  Kouichi Yokoyama ,  Naomi Yoshida ,  Takashi Michimoto ,  Eiji Miyamoto ,  Masatoshi Fujisawa

IPC分类号： B01D5000

CPC分类号： B01J21/063 ,  B01D53/8631 ,  B01D53/885 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20769 ,  B01D2255/20776 ,  B01J19/32 ,  B01J23/22 ,  B01J23/24 ,  B01J31/06 ,  B01J35/02 ,  B01J35/04 ,  B01J35/1033 ,  B01J37/0018 ,  B01J37/0219 ,  B01J37/0225 ,  B01J37/024 ,  B01J2219/3221 ,  B01J2219/32213 ,  B01J2219/32237 ,  B01J2219/32262 ,  B01J2219/32286 ,  B01J2219/32408 ,  B01J2219/32425 ,  B01J2219/32441 ,  B01J2219/32466 ,  B01J2219/326 ,  F01N3/281 ,  F01N3/2814 ,  F01N3/2821 ,  F01N2330/02 ,  F01N2330/06 ,  F01N2330/12 ,  F01N2330/321 ,  F01N2330/323 ,  F01N2330/324 ,  F01N2330/38

摘要： The catalyst structure of the present invention for purifying an exhaust gas is preferable for increasing the contact of an exhaust gas, to be treated, with a catalyst by disturbing the flow of the exhaust gas in a gas flow passage thereby obtain a highly efficient and compact apparatus for treating the exhaust gas. Such catalyst structure is produced by forming two or more catalyst elements each supporting a catalyst component on its surface and having flat plate portions and level-changing portions formed alternately therein with the angle formed between the flat plate portion and the level-changing portion being in a specific range, and then stacking the catalyst elements in a frame. A catalyst structure is also obtained by stacking a large number of the catalyst elements described above through metallic, ceramic, or glass netlike members interposed therebetween and each having a large number of perforated holes. The catalyst structure has such advantages that dust is hardly deposited between the catalyst elements, that a sufficiently high strength can be obtained even when the thickness of catalyst elements is reduced, and that the catalyst structure can be placed in an exhaust gas flue to use as an exhaust gas treating apparatus. When the exhaust gas treating apparatus is employed, an efficient exhaust gas treatment can be effected without damaging the catalyst elements while repressing the pressure loss.

摘要翻译： 用于净化废气的本发明的催化剂结构优选通过扰乱气体流路中的排气的流动来增加待处理废气与催化剂的接触，从而获得高效且致密的 废气处理装置。 这种催化剂结构通过在其表面上形成两个或更多个催化剂组分的催化剂组分来形成，并且具有平板部分和交替地形成的水平变化部分，其中平板部分和水平变化部分之间形成的角度在 特定范围，然后将催化剂元件堆叠在框架中。 催化剂结构也可以通过将上述多个催化剂元素堆叠通过介于其间的金属，陶瓷或玻璃网状构件并且各自具有大量穿孔而获得。 催化剂结构具有这样的优点，即在催化剂元件之间难以沉积灰尘，即使催化剂元素的厚度减小也能获得足够高的强度，并且催化剂结构可以放置在废气烟道中以用作 废气处理装置。 当采用废气处理装置时，可以在不损坏催化剂元件同时抑制压力损失的同时进行有效的废气处理。

公开(公告)号：US20110183839A1

公开(公告)日：2011-07-28

申请号：US13056142

申请日：2009-07-29

申请人： Masatoshi Fujisawa ,  Yasuyoshi Kato

发明人： Masatoshi Fujisawa ,  Yasuyoshi Kato

IPC分类号： B01J27/055 ,  B01J37/02 ,  B01J37/08

CPC分类号： B01J27/055 ,  B01D53/8628 ,  B01D2251/208 ,  B01D2255/104 ,  B01D2255/2092 ,  B01J37/0205

摘要： Provided is a silver-supported alumina catalyst for reducing nitrogen oxides using ethanol, which has the drawbacks of the conventional silver-supported alumina catalysts improved, has high performance, is not likely to deteriorate over time, and has excellent initial performance and durability.A catalyst for purifying nitrogen oxides, which purifies nitrogen oxides in exhaust gas using an alcohol as a reducing agent, and contains alumina, aluminum sulfate and silver as main components.

摘要翻译： 本发明提供一种使用乙醇还原氮氧化物的银负载氧化铝催化剂，其具有改进的常规银负载型氧化铝催化剂的缺点，具有高性能，不易随时间劣化，并且具有优异的初始性能和耐久性。 一种用于净化氮氧化物的催化剂，其使用醇作为还原剂净化废气中的氮氧化物，并且包含氧化铝，硫酸铝和银作为主要成分。