公开(公告)号：US10364347B2

公开(公告)日：2019-07-30

申请号：US14006168

申请日：2012-03-22

申请人： Masao Tomioka ,  Manabu Kaneko ,  Miyuki Hagiwara

发明人： Masao Tomioka ,  Manabu Kaneko ,  Miyuki Hagiwara

IPC分类号： C08L63/04 ,  H05K5/00 ,  C08J5/24 ,  C08G59/32 ,  C08K5/21 ,  C08L63/00

摘要： To provide an epoxy-resin composition and prepreg for producing a fiber-reinforced composite material which exhibits excellent curability and has excellent flame retardance and heat resistance, as well as to provide fiber-reinforced composite materials produced using the prepreg and to provide housing for electronic/electrical devices. The epoxy resin composition contains component (A): a phosphorus compound; component (B): an epoxy resin which has at least three epoxy groups in the molecule, and which does not correspond to component (A) nor include component (A); component (C): an epoxy resin curing agent which does not have a urea structure in the molecule; and component (D): a dimethylurea compound represented by formula (a) (in formula (a), “R” is a hydrogen atom or an alkyl group having any number of 1 to 10 carbons).

公开(公告)号：US20140010979A1

公开(公告)日：2014-01-09

申请号：US14006168

申请日：2012-03-22

申请人： Masao Tomioka ,  Manabu Kaneko ,  Miyuki Hagiwara

发明人： Masao Tomioka ,  Manabu Kaneko ,  Miyuki Hagiwara

IPC分类号： C08L63/04 ,  H05K5/00

CPC分类号： C08L63/04 ,  C08G59/3272 ,  C08J5/24 ,  C08J2363/04 ,  C08K5/21 ,  C08L63/00 ,  C08L2205/02 ,  H05K5/0091 ,  Y10T428/1352 ,  Y10T428/249945

摘要： To provide an epoxy-resin composition and prepreg for producing a fiber-reinforced composite material which exhibits excellent curability and has excellent flame retardance and heat resistance, as well as to provide fiber-reinforced composite materials produced using the prepreg and to provide housing for electronic/electrical devices. The epoxy resin composition contains component (A): a phosphorus compound; component (B): an epoxy resin which has at least three epoxy groups in the molecule, and which does not correspond to component (A) nor include component (A); component (C): an epoxy resin curing agent which does not have a urea structure in the molecule; and component (D): a dimethylurea compound represented by formula (a) (in formula (a), “R” is a hydrogen atom or an alkyl group having any number of 1 to 10 carbons).

摘要翻译： 本发明提供一种环氧树脂组合物和预浸料，其用于生产具有优异的固化性和优异的阻燃性和耐热性的纤维增强复合材料，以及提供使用该预浸料制备的纤维增强复合材料并提供电子 /电气设备。 环氧树脂组合物含有成分（A）：磷化合物; 组分（B）：分子中具有至少三个环氧基但不对应于组分（A）的环氧树脂，也不包括组分（A）; 组分（C）：分子中不具有脲结构的环氧树脂固化剂; 组分（D）：式（a）表示的二甲基脲化合物（式（a）中的“R”表示氢原子或碳原子数1〜10的烷基）。

公开(公告)号：US4373046A

公开(公告)日：1983-02-08

申请号：US233134

申请日：1981-02-10

申请人： Miyuki Hagiwara ,  Yousuke Morita

发明人： Miyuki Hagiwara ,  Yousuke Morita

IPC分类号： C08L101/00 ,  C08K5/03 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L65/00 ,  C08L67/00 ,  C08L77/00 ,  C09K15/04 ,  C09K21/08 ,  C08L57/08

CPC分类号： C08K5/03

摘要： A flame-retardant and radiation-resistant polymer composition comprising a polymer and a halogenated acenaphthylene condensate having a structural unit of the formula (I) or (II): ##STR1## (wherein X is chlorine or bromine, n and n' are each an integer of 2 to 6, R is a substituent other than halogen, m and m' are each an integer of 0 to 4, n (or N')+m(or m').ltoreq.6, and when m or m' is 2 or more, each R may be the same or different) and a flame-retardant and radiation-resistant resin molded product prepared therefrom are herein disclosed.

摘要翻译： 包含具有式（I）或（II）结构单元的聚合物和卤代苊缩合物的阻燃和耐辐射聚合物组合物：其中X是氯 或溴，n和n'各自为2至6的整数，R为除卤素以外的取代基，m和m'各自为0至4的整数，n（或N'）+ m（或m'）为 当m或m'为2或更大时，每个R可以相同或不同），并且本文公开了由其制备的阻燃和耐辐射树脂模制产品。

公开(公告)号：US4134812A

公开(公告)日：1979-01-16

申请号：US860569

申请日：1977-12-14

申请人： Takashi Sasaki ,  Kunio Araki ,  Miyuki Hagiwara ,  Hayao Ishitani ,  Eisuke Saito ,  Kyoji Komatsu

发明人： Takashi Sasaki ,  Kunio Araki ,  Miyuki Hagiwara ,  Hayao Ishitani ,  Eisuke Saito ,  Kyoji Komatsu

IPC分类号： C08L23/00 ,  B29C35/08 ,  B29C71/04 ,  C08J7/00 ,  C08K5/01 ,  C08K5/10 ,  C08K5/13 ,  C08K5/134 ,  H01B3/44 ,  C08F8/00

CPC分类号： H01B3/441 ,  B29C71/04 ,  C08K5/01 ,  C08K5/10 ,  C08K5/1345 ,  B29C2035/0872 ,  B29K2023/00

摘要： A method of manufacturing shaped articles of cross-linked poly-.alpha.-olefin composition by irradiation of electron beam which comprises the steps of blending a poly-.alpha.-olefin with a compound miscible therewith which is expressed by the general formula:X--Ym(where X is a group free from acetylenic linkage, Y is a group containing acetylenic linkage and m is an integer of 1 or over) and tetrakis-[methylene-(3,5-di-t-butyl-4-hydroxy-hydrocinnamate)]-methane; molding the blended mass into a desired shape; and cross-linking said shaped articles by irradiation of electron beam.

摘要翻译： 通过电子束照射制造交联聚-α-烯烃组合物的成型制品的方法，该方法包括以下步骤：将聚-α-烯烃与可混合的化合物混合，所述化合物由下式表示：

公开(公告)号：US4753741A

公开(公告)日：1988-06-28

申请号：US49959

申请日：1987-05-15

申请人： Kazuo Arakawa ,  Tsuneo Sasuga ,  Miyuki Hagiwara ,  Naohiro Hayakawa ,  Kenzo Yoshida ,  Hiroshi Nakanishi ,  Mitsuo Hirohama ,  Tetsuya Yagi ,  Tamio Akada ,  Takao Soda

发明人： Kazuo Arakawa ,  Tsuneo Sasuga ,  Miyuki Hagiwara ,  Naohiro Hayakawa ,  Kenzo Yoshida ,  Hiroshi Nakanishi ,  Mitsuo Hirohama ,  Tetsuya Yagi ,  Tamio Akada ,  Takao Soda

IPC分类号： C10M169/00 ,  C10M169/02 ,  C10N30/00 ,  C10N40/00 ,  C10N50/10 ,  C10M103/00 ,  C10M113/10 ,  C10M125/30

CPC分类号： C10M169/02 ,  C10M169/00 ,  C10M2201/103 ,  C10M2201/1036 ,  C10M2207/021 ,  C10M2207/04 ,  C10M2207/0406 ,  C10M2207/08 ,  C10M2207/32 ,  C10M2209/00 ,  C10M2209/02 ,  C10M2209/10 ,  C10N2230/32 ,  C10N2270/00

摘要： A radiation-resistant grease that is stable under elevated temperatures is disclosed. The grease is prepared by mixing a bentonite-based thickening agent with a base oil composed of m-(m-phenoxyphenoxy)diphenyl, pentaphenyl ether, a monoalkyltriphenyl ether or a monoalkyltetraphenyl ether (provided that the alkyl group contains 6-20 carbon atoms). To the mixture is added, if necessary, a gelling aid composed of an aliphatic alcohol, an aliphatic ketone and/or an aliphatic carbonate ester.

摘要翻译： 公开了一种在高温下稳定的防辐射润滑脂。 通过将膨润土类增稠剂与由间 - （间 - 苯氧基苯氧基）二苯基，五苯基醚，单烷基三苯基醚或单烷基四苯基醚组成的基础油（条件是烷基含有6-20个碳原子）混合制备润滑脂， 。 如果需要，向混合物中加入由脂族醇，脂族酮和/或脂族碳酸酯组成的胶凝助剂。

公开(公告)号：US4393165A

公开(公告)日：1983-07-12

申请号：US406974

申请日：1982-08-09

申请人： Takashi Sasaki ,  Miyuki Hagiwara ,  Fumio Hosoi ,  Tohru Takagi

发明人： Takashi Sasaki ,  Miyuki Hagiwara ,  Fumio Hosoi ,  Tohru Takagi

IPC分类号： C08F2/00 ,  C08F2/54 ,  C08F283/00 ,  C08F291/00 ,  C08G59/00 ,  C08G59/40 ,  C08G81/00 ,  C08G81/02 ,  C08G63/76 ,  C08L67/00

CPC分类号： C08F283/00

摘要： A polymer composition is herein disclosed, which consists essentially of:(A) 90 to 50 wt % of a saturated polymer having in one molecule (1) at least two groups of at least one type selected from the group consisting of an epoxy group of the formula ##STR1## (R is hydrogen or methyl), an alcoholic or phenolic hydroxyl group and an alkoxymethyl-substituted acid amide group of the formula ##STR2## (R is an alkyl group of C.sub.1 to C.sub.4) and (2) a repeating unit made of a nonaromatic methylene group or methine group; and(B) 50 to 10 wt % of a nonfunctional radical polymerizable monomer mixture consisting of (a) a radical polymerizable monomer having in one molecule at least one functional group selected from the group consisting of a carboxyl group, an acid anhydride group, an alcoholic hydroxyl group, an alkoxymethyl-substituted acid amide group of the formula ##STR3## (R is an alkyl group of C.sub.1 to C.sub.4) and an amino group of the formula --NR.sub.1 R.sub.2 (R.sub.1 and R.sub.2 are each an alkyl group of C.sub.1 to C.sub.8) and an ethylenic double bond, and (b) a radical polymerizable monomer having one epoxy ring and one ethylenic double bond in one molecule.

摘要翻译： 本文公开了一种聚合物组合物，其基本上由以下组成：（A）90至50重量％的在一分子中具有至少两个选自以下组中的至少一种的饱和聚合物：（1）至少一种选自下组的环氧基： 式（IMA）（R是氢或甲基），醇或酚羟基和具有下式的烷氧基甲基取代的酰胺基（R是C1至C4的烷基）和（2）重复的 由非芳族亚甲基或次甲基组成的单元; 和（B）50〜10重量％的由以下组成的非功能性自由基聚合性单体混合物：（a）在1分子中具有至少一个选自羧基，酸酐基， 醇羟基，式IMAMA的烷氧基甲基取代的酰胺基（R为C1至C4的烷基）和式-NR1R2的氨基（R1和R2各自为C1至C8的烷基） ）和烯属双键，和（b）在一个分子中具有一个环氧环和一个烯属双键的自由基聚合单体。

公开(公告)号：US4332657A

公开(公告)日：1982-06-01

申请号：US94882

申请日：1979-11-16

申请人： Keizo Makuuchi ,  Akio Katakai ,  Miyuki Hagiwara ,  Tsutomu Yamamoto ,  Hiroyuki Nakayama ,  Tohru Takagi

发明人： Keizo Makuuchi ,  Akio Katakai ,  Miyuki Hagiwara ,  Tsutomu Yamamoto ,  Hiroyuki Nakayama ,  Tohru Takagi

IPC分类号： C08F220/56 ,  C08F2/46 ,  C08F2/54 ,  C09D125/08 ,  C09D133/02 ,  C09D133/06 ,  C09D133/26 ,  C08L33/08 ,  C08L33/10

CPC分类号： C09D133/26 ,  C08F2/46 ,  C09D125/08 ,  C09D133/066 ,  Y10S522/912 ,  Y10T428/26 ,  Y10T428/31699

摘要： An emulsion composition for use in baking paint prepared by emulsion polymerization with ionizing radiation of a monomer mixture comprising (1) at least one acrylamide selected from the group consisting of N-methylolacrylamide and N-alkoxymethylacrylamide, (2) a radical polymerizable ethylenic unsaturated monomer having a hydroxyl group, and (3) a radical polymerizable ethylenic unsaturated monomer other than (1) and (2) above.

摘要翻译： 一种用于通过使用单体混合物的电离辐射的乳液聚合制备的烘烤涂料中的乳液组合物，其包含（1）至少一种选自N-羟甲基丙烯酰胺和N-烷氧基甲基丙烯酰胺的丙烯酰胺，（2）可自由基聚合的烯属不饱和单体 具有羟基，（3）除上述（1）和（2）以外的自由基聚合性烯属不饱和单体。

公开(公告)号：US4289687A

公开(公告)日：1981-09-15

申请号：US114420

申请日：1980-01-22

申请人： Miyuki Hagiwara ,  Yosuke Morita

发明人： Miyuki Hagiwara ,  Yosuke Morita

IPC分类号： C08F291/00 ,  C08F255/02 ,  C08K5/03

CPC分类号： C08F291/00 ,  Y10T428/294

摘要： A fire-retardant and radiation resistant molded resin product is prepared by blending a resin with a halogenated acenaphthylene compound of the formula: ##STR1## wherein X is chlorine or bromine and R is alkyl, alkoxy or alkylester of 1 to 4 carbon atoms such that when m is 0, n is an integer of 2 to 8; when m is an integer of 1 to 4, n is an integer of 2 to 7 and n+m is .ltoreq.8 and when m is more than 2, R may be the same or different; and, after molding said blend, generating free radicals within said blend.

摘要翻译： 通过将树脂与下式的卤化苊化合物（其中X是氯或溴，R是具有1至4个碳原子的烷基，烷氧基或烷基酯）共混制备阻燃和耐辐射模制树脂产品，使得 当m为0时，n为2〜8的整数， 当m为1〜4的整数时，n为2〜7的整数，n + m为8，当m大于2时，R可以相同或不同， 并且在模制所述共混物之后，在所述共混物内产生自由基。

公开(公告)号：US4226687A

公开(公告)日：1980-10-07

申请号：US944782

申请日：1978-09-22

申请人： Takashi Sasaki ,  Miyuki Hagiwara ,  Kunio Araki ,  Hayao Ishitani ,  Eisuke Saito ,  Kyozi Komatsu

发明人： Takashi Sasaki ,  Miyuki Hagiwara ,  Kunio Araki ,  Hayao Ishitani ,  Eisuke Saito ,  Kyozi Komatsu

IPC分类号： B29C35/00 ,  B29C35/08 ,  B29C71/04 ,  C08F2/54 ,  C08J7/00 ,  G21K5/10 ,  H01B13/00 ,  H01B13/14 ,  C08F2/46 ,  C08F8/00

CPC分类号： G21K5/10 ,  B29C71/04 ,  H01B13/003 ,  B29C2035/0877 ,  B29K2021/00 ,  B29L2031/3462

摘要： A method of manufacturing an electric wire or cable having an improved rubber or plastic insulation layer which has the maximum wall thickness of beam penetration of 4mm or over and whose properties are improved by irradiation with an electron beam, wherein the wire or cable runs under the scanner of an electron beam accelerator while being rotated about the axis of the wire or cable at such a speed as causes the same portion of the wire or cable to be irradiated with the electron beam at least twice during a period of less than 10 seconds; and the electron beam accelerator directs on the insulation layer of the wire or cable an electron beam which is accelerated to an energy of 1 MeV or over and whose maximum penetration range in the said insulation layer is larger than its thickness.

摘要翻译： 一种制造具有改进的橡胶或塑料绝缘层的电线或电缆的方法，其具有4mm或更大的光束穿透的最大壁厚，并且通过用电子束照射改善其性能，其中电线或电缆在 电子束加速器的扫描仪，同时绕着电线或电缆的轴线旋转，以使电线或电缆的相同部分在少于10秒的时间内用电子束照射至少两次; 并且电子束加速器引导电线或电缆的绝缘层，电子束被加速至1MeV以上的能量，并且其绝缘层中的最大穿透范围大于其厚度。

公开(公告)号：US07972641B2

公开(公告)日：2011-07-05

申请号：US12220987

申请日：2008-07-30

申请人： Miyuki Hagiwara ,  Yasufumi Shibata

发明人： Miyuki Hagiwara ,  Yasufumi Shibata

IPC分类号： A23L1/20

CPC分类号： A23C11/103 ,  A23L11/07

摘要： Lipoxygenase-free soybean grains are mechanically pulverized into fine particles and then subjected to heat drying treatment with water vapor having a temperature in the range of 130 to 250° C. under atmospheric pressure to form lumps of soybean powder. The lumps are formed into granules having controlled sizes by placing the lumps in a space defined by two plates having a predetermined distance therebetween and having a plurality of parallel grooves formed in the surfaces. The plates are in a state of relative rotation. This method allows the production of soybean powder free from disagreeable odor and taste and the production of soybean milk from the soybean powder, with inexpensive equipment in a quick process.

摘要翻译： 将无脂氧合酶的大豆颗粒机械粉碎成细颗粒，然后在大气压下在130-250℃范围内的水蒸气进行加热干燥处理，形成大豆粉末块。 通过将块放置在由两个板之间具有预定距离限定的空间中并且在表面中形成有多个平行的凹槽，将块形成具有受控尺寸的颗粒。 板处于相对旋转的状态。 这种方法允许生产大豆粉从无味的气味和味道以及从大豆粉中生产的豆浆，并以快速的方法用廉价的设备。