FeCrAl ALLOY FOIL FOR CATALYTIC CONVERTERS AT MEDIUM HIGH TEMPERATURE AND A METHOD OF MAKING THE MATERIAL
    1.
    发明申请
    FeCrAl ALLOY FOIL FOR CATALYTIC CONVERTERS AT MEDIUM HIGH TEMPERATURE AND A METHOD OF MAKING THE MATERIAL 审中-公开
    用于中温高温催化转化器的FeCrAl合金箔及其制备方法

    公开(公告)号:US20070237690A1

    公开(公告)日:2007-10-11

    申请号:US11537148

    申请日:2006-09-29

    IPC分类号: B23K20/04 B01D53/34

    CPC分类号: B01J35/04 B01J37/08

    摘要: A FeCrAl alloy for catalytic converter substrates having excellent oxidation resistance and dimension stability at a medium high temperature, e.g. the temperature encountered by catalytic converter substrates in truck diesel engines, without necessary addition of extra Y, Hf, Zr, or rare earth elements beyond that inherently present in commercial stainless steel. A roll bonding and diffusion alloying annealing method is used for making such materials with the following two deviated paths. First, material in which layers of ferritic stainless steel and aluminum are solid state metallurgically bonded together forming a multilayer composite material. Such composite material is then further rolled to an intermediate foil gauge, cleaned, and then subjected to a thermal reaction to form a resulting uniform solid solution foil material followed by rolling to the final foil thickness. Alternatively, such composite material is further rolled to the final foil thickness, cleaned, and then subjected to a thermal in-situ reaction in the material after a honeycomb-like catalytic converter is made from the foil composite material. Both deviated approaches result in a uniform solid solution foil material.

    摘要翻译: 一种用于催化转化器基底的FeCrAl合金,其在中等高温下具有优异的抗氧化性和尺寸稳定性,例如, 催化转化器基板在卡车柴油发动机中遇到的温度,不需要额外添加额外的Y,Hf,Zr或稀土元素,超出商业不锈钢中固有的含量。 使用辊粘合和扩散合金化退火方法制造具有以下两个偏离路径的这种材料。 首先,铁素体不锈钢和铝层是固态冶金结合在一起形成多层复合材料的材料。 然后将这种复合材料进一步轧制到中间箔计量器上,进行清洗,然后进行热反应以形成均匀的固溶体箔材料,然后轧制至最终的箔厚度。 或者,将这种复合材料进一步轧制到最终的箔厚度,清洁,然后在由箔复合材料制成蜂窝状催化转化器之后在材料中进行热原位反应。 两种偏离的方法都产生均匀的固溶箔材料。

    FeCrAl alloy foil for catalytic converters at medium high temperature and a method of making the material
    2.
    发明申请
    FeCrAl alloy foil for catalytic converters at medium high temperature and a method of making the material 审中-公开
    用于中等温度催化转化器的FeCrAl合金箔及其制备方法

    公开(公告)号:US20050058581A1

    公开(公告)日:2005-03-17

    申请号:US10914457

    申请日:2004-08-09

    摘要: A FeCrAl alloy for catalytic converter substrates having excellent oxidation resistance and dimension stability at a medium high temperature, e.g. the temperature encountered by catalytic converter substrates in truck diesel engines, without necessary addition of extra Y, Hf, or rare earth elements beyond that inherently present in commercial stainless steel. A roll bonding and diffusion alloying annealing method is used for making such materials with the following two deviated paths. First, material in which layers of ferritic stainless steel and aluminum are solid state metallurgically bonded together forming a multilayer composite material. Such composite material is then further rolled to an intermediate foil gauge and then subjected to a thermal reaction to form a resulting uniform solid solution foil material followed by rolling to the final foil thickness. Alternatively, such composite material is further rolled to the final foil thickness and then subjected to a thermal in-situ reaction in the material after a honeycomb-like catalytic converter is made from the foil composite material. Both deviated approaches result in a uniform solid solution foil material.

    摘要翻译: 一种用于催化转化器基底的FeCrAl合金,其在中等高温下具有优异的抗氧化性和尺寸稳定性,例如, 催化转化器基板在卡车柴油发动机中遇到的温度,不需要额外的添加额外的Y,Hf或稀土元素超出商业不锈钢中固有的。 使用辊粘合和扩散合金化退火方法制造具有以下两个偏离路径的这种材料。 首先,铁素体不锈钢和铝层是固态冶金结合在一起形成多层复合材料的材料。 然后将这种复合材料进一步轧制成中间箔片,然后进行热反应以形成均匀的固溶体箔材料,然后轧制至最终的箔厚度。 或者,将这种复合材料进一步轧制到最终的箔厚度,然后在由箔复合材料制成蜂窝状催化转化器之后在材料中进行热原位反应。 两种偏离的方法都产生均匀的固溶箔材料。

    Self-brazing materials for elevated temperature applications
    3.
    发明授权
    Self-brazing materials for elevated temperature applications 有权
    用于高温应用的自钎焊材料

    公开(公告)号:US06783870B2

    公开(公告)日:2004-08-31

    申请号:US09976520

    申请日:2001-10-12

    IPC分类号: B32B1518

    摘要: This invention describes the roll bonding of Al and Ni-bearing Cu alloys to suitable substrates to produce self-brazing materials for the elevated temperature, aggressive environment application. The Al and Ni-bearing Cu alloy for the self-brazing layers can be obtained by cladding layers of elemental Ni and Al to Cu. The Al content in the self-brazing layers can be varied from 2 to 100%. The Ni content in the self-brazing Cu alloy can be varied from 10 to 100%. Additional alloying elements in the commercial Cu alloys such as Fe, Cr, Si, Mn, Sn and Zn are unavoidable. Trace elements in the commercial alloys such as Pb, Ag and As will also affect the brazing and shall be reduced.

    摘要翻译: 本发明描述了将Al和Ni承载的Cu合金与合适的基底进行辊接,以产生用于高温,侵蚀性环境应用的自钎焊材料。 用于自钎焊层的Al和Ni承载的Cu合金可以通过将元素Ni和Al包覆到Cu来获得。 自钎焊层中的Al含量可以在2至100%之间变化。 自钎焊Cu合金中的Ni含量可以从10%变化到100%。 市售的Cu合金如Fe,Cr,Si,Mn,Sn和Zn中的其它合金元素是不可避免的。 Pb,Ag,As等商品合金中的痕量元素也会影响钎焊,并减少。

    Method of making clad materials using lead alloys and composite strips made by such method
    4.
    发明授权
    Method of making clad materials using lead alloys and composite strips made by such method 失效
    采用这种方法制作的铅合金和复合带制造复合材料的方法

    公开(公告)号:US06475675B1

    公开(公告)日:2002-11-05

    申请号:US09568829

    申请日:2000-05-11

    IPC分类号: H01M464

    摘要: Lead alloy strip material (4, 6, 8) is roll bonded on one or both opposite face surfaces of a core strip material (2). The core material can be commercially pure titanium, austenitic stainless steel, low carbon steel, copper, aluminum, alloys thereof or other suitable metal that has sufficient ductility and that can provide desired attributes of stiffness and corrosion resistance to the composite. The lead alloy material is strengthened by the addition of less than approximately 1% of calcium or antimony and the core material is softened by fully annealing it prior to bonding. The several strips are reduced in thickness, preferably in approximately the same proportion, by at least 40% in the bonding pass to create a solid phase bond among the strips. The bonded composite is then rolled to final gauge and, for selected applications, is corrugated and cut to form panels (20, 22, 24) and etched to form pockets (8b) for pasting of active materials such as lead oxide for battery plates.

    摘要翻译: 铅芯合金条材料(4,6,8)在芯条材料(2)的一个或两个相对的表面上滚动粘结。 核心材料可以是商业上纯钛,奥氏体不锈钢,低碳钢,铜,铝,它们的合金或具有足够的延展性的其它合适的金属,并且可以提供对复合材料的刚性和耐腐蚀性所需的属性。 通过添加少于约1%的钙或锑来增强铅合金材料,并且通过在结合之前将其完全退火使芯材料软化。 在条带中,若干条的厚度,优选以大致相同的比例减少至少40%,以在条带之间产生固相结合。 然后将粘合的复合材料轧制成最终规格,并且对于所选择的应用,是波纹状的并且被切割以形成板(20,22,24)并被蚀刻以形成用于粘贴活性材料(例如电池板的氧化铅)的凹穴(8b)。

    Method for cleaning thin metal strip material
    5.
    发明授权
    Method for cleaning thin metal strip material 有权
    清洁薄金属条材料的方法

    公开(公告)号:US06379468B1

    公开(公告)日:2002-04-30

    申请号:US09669331

    申请日:2000-09-25

    IPC分类号: B08B304

    CPC分类号: B08B3/022 B08B1/02

    摘要: A method for cleaning thin gauge metal foil strip material using a plurality of wiper (12, 16, 20) and solvent application (14, 18) stages. The solvent used in the solvent application stages is an aliphatic petroleum type which is applied using low pressure to avoid atomization or separation of solvent components. The wipers of a first wiping station are made of a solid bar of polymer impregnated fiber material. The wipers of the second wiping station are spaced apart blades of urethane-based elastomer material.

    摘要翻译: 一种使用多个擦拭器(12,16,20)和溶剂施加(14,18)级清洁薄金属箔条带材料的方法。 在溶剂施加阶段中使用的溶剂是脂肪族石油类型,其使用低压来施加以避免雾化或分离溶剂组分。 第一擦拭站的擦拭器由固体聚合物浸渍的纤维材料制成。 第二擦拭站的擦拭器是间隔开的氨基甲酸酯类弹性体材料的叶片。

    Ti brazing strips or foils
    6.
    发明授权
    Ti brazing strips or foils 有权
    Ti钎焊条或箔

    公开(公告)号:US07776454B2

    公开(公告)日:2010-08-17

    申请号:US10743641

    申请日:2003-12-22

    IPC分类号: B32B9/00

    摘要: A method for producing titanium alloy brazing strips and the resulting brazing strips and/or foils. The method uses a cold-rolling process without heat treating to generate a titanium based multi-layer alloy strip or foil made up of discrete layers of titanium and an additional layer or layers of one or more metals, such as zirconium, nickel and/or copper, for example, or alloys thereof, with the layer of titanium roll bonded without heat treating to the layers of the additional metal(s). The resulting strip or foil can include, for example, Cu/Ti/Cu, Ni/Ti/Ni, Ni/Ti/Cu, Cu/Ni/Ti/Ni/Cu, Ni/Cu/Ti/Cu/Ni, Ni/Cu/Ni/Ti/Ni/Cu/Ni, Ni/Zr/Cu/Ti/Cu/Zr/Ni and Ni/Ti/Cu/Zr/Cu/Ti/Ni among other combinations. The resulting strip or foil can be used for brazing, creating an alloy of the weight percentage of the original materials.

    摘要翻译: 一种用于生产钛合金钎焊带和所得到的钎焊带和/或箔的方法。 该方法使用冷轧方法而不进行热处理,以生成由钛的不连续层和附加的一层或多层金属构成的钛基多层合金带或箔,例如锆,镍和/或 例如铜或其合金,钛层的粘合层不进行附加金属层的热处理。 所得到的带或箔可以包括例如Cu / Ti / Cu,Ni / Ti / Ni,Ni / Ti / Cu,Cu / Ni / Ti / Ni / Cu,Ni / Cu / Ti / Cu / Ni,Ni / Cu / Ni / Ti / Ni / Cu / Ni,Ni / Zr / Cu / Ti / Cu / Zr / Ni和Ni / Ti / Cu / Zr / Cu / Ti / Ni等组合。 所得到的条或箔可用于钎焊,形成原始材料重量百分比的合金。

    Method of producing Ti brazing strips or foils
    8.
    发明授权
    Method of producing Ti brazing strips or foils 有权
    生产Ti钎焊条或箔的方法

    公开(公告)号:US06722002B1

    公开(公告)日:2004-04-20

    申请号:US10320068

    申请日:2002-12-16

    IPC分类号: B21B122

    摘要: A method for producing titanium alloy brazing strips and the resulting brazing strips and/or foils. The method uses a cold-rolling process without annealing to generate a titanium based multi-layer alloy strip or foil made up of discrete layers of titanium and an additional layer or layers of one or more metals, such as nickel and/or copper, for example, or alloys thereof, with the layer of titanium roll bonded without annealing to the layers of the additional metal(s). The resulting strip or foil can include, for example, Cu/Ti/Cu, Ni/Ti/Ni, and Ni/Ti/Cu, and also, for example, Cu/Ni/Ti/Ni/Cu, and Ni/Cu/Ti/Cu/Ni, among other combinations. The resulting strip or foil can be used for brazing, creating an alloy of the weight percentage of the original materials.

    摘要翻译: 一种用于生产钛合金钎焊带和所得到的钎焊带和/或箔的方法。 该方法使用冷轧方法而不进行退火以产生由钛的离散层和一种或多种金属(例如镍和/或铜)的附加层或多层构成的钛基多层合金带或箔,用于 例如或其合金,其中钛辊粘合层,而不退火到附加金属的层。 所得到的带或箔可以包括例如Cu / Ti / Cu,Ni / Ti / Ni和Ni / Ti / Cu,并且还可以包括例如Cu / Ni / Ti / Ni / Cu和Ni / Cu / Ti / Cu / Ni等。 所得到的条或箔可用于钎焊,形成原始材料重量百分比的合金。

    IN-SITU DIFFUSION ALLOYING AND PRE-OXIDATION ANNEALING IN AIR OF FE-CR-AL ALLOY CATALYTIC CONVERTER MATERIAL
    9.
    发明申请
    IN-SITU DIFFUSION ALLOYING AND PRE-OXIDATION ANNEALING IN AIR OF FE-CR-AL ALLOY CATALYTIC CONVERTER MATERIAL 审中-公开
    FE-CR-AL合金催化转化材料空气中的原位扩散合金和预氧化退火

    公开(公告)号:US20090104090A1

    公开(公告)日:2009-04-23

    申请号:US12327535

    申请日:2008-12-03

    IPC分类号: B01D53/34 B21D51/16 B32B3/12

    摘要: A manufacturing method of metal substrate catalytic converter and the resulting product. In this method, a multiple layer aluminum and ferritic stainless steel composite material is first made by roll-bonding and then further processed to a final foil thickness. The composite foils are then fabricated to a honeycomb-like converter with air flow channels. The converter is then thermally treated at a high temperature during a necessary converter fabrication process. The monolithic FeCrAl alloy is then obtained in the converter by in-situ diffusion alloying with pre-oxide film on the surfaces. The resulted material has improved oxidation resistance and thermal dimension stability at a high temperature.

    摘要翻译: 金属基底催化转化器的制造方法及其所得产品。 在该方法中,多层铝和铁素体不锈钢复合材料首先通过辊压制成,然后进一步加工成最终的箔厚度。 然后将复合箔制成具有气流通道的蜂窝状转换器。 然后在必要的转换器制造过程中在高温下对转换器进行热处理。 然后通过在表面上与预氧化物膜原位扩散合金化在转炉中获得单片FeCrAl合金。 所得材料在高温下具有改善的抗氧化性和热尺寸稳定性。