摘要:
A ceramic honeycomb structural body is manufactured by molding silicon carbide raw powders into a honeycomb pillar shape and then firing it to form a sintered body. The silicon carbide raw powders are comprised of about 60 to about 80% by mass of particles of first particle group having one frequency peak in the particle size distribution and a particle size of 1.0 μm to about 100 μm, and about 20 to about 40% by mass of particles of a second particle group having a particle size of about 0.1 μm or more and less than 1.0 μm.
摘要:
A ceramic honeycomb structural body is manufactured by molding silicon carbide raw powders into a honeycomb pillar shape and then firing it to form a sintered body. The silicon carbide raw powders are comprised of about 60 to about 80% by mass of particles of first particle group having one frequency peak in the particle size distribution and a particle size of 1.0 μm to about 100 μm, and about 20 to about 40% by mass of particles of a second particle group having a particle size of about 0.1 μm or more and less than 1.0 μm.
摘要:
The invention provides a method for producing a porous body comprising: a starting material mixing step of mixing ceramic particles serving as an aggregate and a sintering aid which includes at least one element selected from the group consisting of rare earth elements, alkaline earth elements, Al and Si such that the amount of the sintering aid is about 1.0% by weight or less relative to the total amount of the ceramic particles and the sintering aid to form a puddle; and a molding and firing step of molding the puddle into a molded body and firing the molded body.
摘要:
The honeycomb structured body of the present invention is a honeycomb structured body in which a plurality of porous ceramic members are combined with one another through an adhesive layer, each of the porous ceramic members having a plurality of cells which are allowed to penetrate in a longitudinal direction with a wall portion therebetween and either one end of which is sealed, with a catalyst supporting layer being adhered to the wall portion, wherein an average pore diameter of the porous ceramic member is larger than an average particle diameter of particles constituting the catalyst supporting layer, and when a pore diameter distribution of the porous ceramic member and a particle diameter distribution of particles constituting the catalyst supporting layer are drawn with the pore diameter and the particle diameter being on the same axis, a pore volume in an overlapped area of both the distributions is about 10% or less to the entire pore volume of the porous ceramic member.
摘要:
A honeycomb structured body of the present invention is a honeycomb structured body in which a plurality of porous ceramic members are combined with one another through an adhesive layer, each of the porous ceramic members having a plurality of cells which are allowed to penetrate in a longitudinal direction with a wall portion therebetween and either one end of which is sealed, with a catalyst supporting layer being adhered to the wall portion, wherein, supposing that the rate of the pore volume of pores having a pore diameter of 10 μm or less to the entire pore volume of the porous ceramic member is X1 (%), the porosity is Y1 (%) and the weight of the catalyst supporting layer is Z1 (g/l), these X1, Y1 and Z1 are allowed to satisfy the following expressions (1) and (2): X1≦20−Z1/10 (1), and Y1≧35+7Z1/40 (2) (where about 20≦Z1≦about 150).
摘要:
A honeycomb structured body of the present invention is a honeycomb structured body in which a plurality of porous ceramic members are combined with one another through an adhesive layer, each of the porous ceramic members having a plurality of cells which are allowed to penetrate in a longitudinal direction with a wall portion therebetween and either one end of which is sealed, with a catalyst supporting layer being adhered to the wall portion, wherein, supposing that the rate of the pore volume of pores having a pore diameter of 10 μm or less to the entire pore volume of the porous ceramic member is X1 (%), the porosity is Y1 (%) and the weight of the catalyst supporting layer is Z1 (g/l), these X1, Y1 and Z1 are allowed to satisfy the following expressions (1) and (2): X1≦20−Z1/10 (1), and Y1≧35+7Z1/40 (2) (where about 20≦Z1≦about 150).
摘要:
The honeycomb structured body of the present invention is a honeycomb structured body in which a plurality of porous ceramic members are combined with one another through an adhesive layer, each of the porous ceramic members having a plurality of cells which are allowed to penetrate in a longitudinal direction with a wall portion therebetween and either one end of which is sealed, with a catalyst supporting layer being adhered to the wall portion, wherein an average pore diameter of the porous ceramic member is larger than an average particle diameter of particles constituting the catalyst supporting layer, and when a pore diameter distribution of the porous ceramic member and a particle diameter distribution of particles constituting the catalyst supporting layer are drawn with the pore diameter and the particle diameter being on the same axis, a pore volume in an overlapped area of both the distributions is about 10% or less to the entire pore volume of the porous ceramic member.
摘要:
A sintering aid for promoting sintering of ceramic particles and fine particles that are the same materials as ceramic particles and have smaller average particle diameter are mixed to obtain a puddle. The average particle diameter of ceramic particles is preferably about in a range of 5 to 100 μm; the average particle diameter of the fine particles is preferably about in a range of 0.1 to 1.0 μm, and the average particle diameter of the sintering aid is preferably about in a range of 0.1 to 10 μm. As the sintering aid, for example, alumina is used. This puddle is extrusion molded into a honeycomb shape and the molded object is fired at a firing temperature lower than a temperature for sintering without mixing a sintering aid. The thermal conductivity of the obtained honeycomb structure 10 shows about 60% or more of the thermal conductivity of a fired body fired without adding a sintering aid to ceramic particles and shows about 12 W/m·K or more at 20° C.
摘要:
It is to provide a honeycomb structural body having an excellent durability, which is large in the catching amount of particulates per unit volume and does not cause uneven accumulation of ash and occurrence of cracks or the like even in use for a long period of time, and there is proposed a honeycomb structural body obtained by assembling one or plural porous ceramic members in which two kinds of through-holes consisting of a group of large volume through-holes and a group of small volume through-holes are arranged side by side in the longitudinal direction through partitions and either one ends of these through-holes are plugged, wherein the ceramic member is made of silicon-ceramic composite material consisting of ceramic and silicon.