公开(公告)号：US20150148452A1

公开(公告)日：2015-05-28

申请号：US14404942

申请日：2013-02-15

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Hyun-Aee Chun ,  Su-Jin Park ,  Sook-Yeon Park ,  Yun-Ju Kim ,  Sang-Yong Tak ,  Sung-Hwan Park ,  Kyung-Nam Kang

IPC: C08K5/549 ,  C08K3/22 ,  C07D301/00 ,  C07F7/18 ,  C07C41/06 ,  C07C37/48 ,  C08K3/28 ,  C08K3/36

CPC classification number: C08K5/549 ,  C07C37/48 ,  C07C41/06 ,  C07D301/00 ,  C07D303/12 ,  C07D303/30 ,  C07D407/12 ,  C07F7/1804 ,  C07F7/1876 ,  C08K3/22 ,  C08K3/28 ,  C08K3/36 ,  C08K2003/2241 ,  C08K2003/2244

Abstract: There is provided a composition including an alkoxysilylated epoxy compound, a composition of which exhibits good heat resistance properties, low CTE and high glass transition temperature or Tg-less and not requiring a separate coupling agent, and inorganic particles, a cured product formed of the composition, and a use of the cured product. An epoxy composition including an alkoxysilylated epoxy compound and inorganic particles, an epoxy composition including an epoxy compound, inorganic particles and a curing agent, a cured product of the composition, and a use of the composition are provided. Since chemical bonds may be formed between the alkoxysilyl group and the inorganic particles and between the alkoxysilyl groups, a composition of the composition including the alkoxysilylated epoxy compound and the inorganic particles exhibits improved heat resistance properties, decreased CTE, and increased glass transition temperature or Tg less.

Abstract translation: 提供了包含烷氧基甲硅烷基化环氧化合物的组合物，其具有良好的耐热性，低CTE和高玻璃化转变温度或Tg-Tg并且不需要单独的偶联剂的组合物，以及无机颗粒，由 组合物和使用固化产物。 提供了包含烷氧基甲硅烷基化环氧化合物和无机颗粒的环氧组合物，包含环氧化合物，无机颗粒和固化剂的环氧组合物，组合物的固化产物和组合物的用途。 由于可以在烷氧基甲硅烷基和无机颗粒之间以及烷氧基甲硅烷基之间形成化学键，所以包含烷氧基硅烷基化环氧化合物和无机颗粒的组合物的组合物表现出改进的耐热性，降低的CTE和增加的玻璃化转变温度或Tg 减。

公开(公告)号：US09902803B2

公开(公告)日：2018-02-27

申请号：US14384669

申请日：2013-03-14

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Hyun-Aee Chun ,  Yun-Ju Kim ,  Su-Jin Park ,  Sook-Yeon Park ,  Sung-Hwan Park ,  Sang-Yong Tak

IPC: C08G59/32 ,  C08G59/04 ,  C08G59/30 ,  C09D163/00 ,  C08K7/14 ,  C08K3/36 ,  C07F7/18 ,  C07D303/36 ,  C08L63/00

CPC classification number: C08G59/3281 ,  C07D303/36 ,  C07F7/1804 ,  C07F7/1876 ,  C08G59/04 ,  C08G59/306 ,  C08K3/36 ,  C08K7/14 ,  C08L63/00 ,  C09D163/00

Abstract: The present invention relates to an alkoxysilylated epoxy compound, a composite of which exhibits good heat resistance properties, low CTE and high glass transition temperature and not requiring a coupling agent, a composition including the same, a cured product formed of the composition, a use of the cured product, and a method of preparing the epoxy compound having alkoxysilyl group. An epoxy compound having an epoxy group and an alkoxysilyl group, a composition including the epoxy compound, a curing agent, a filler and/or a reaction catalyst, a cured product of the composition, and a use of the composition including an electronic part are provided. In a composite and/or cured product, the epoxy composition forms chemical bonds and exhibits improved heat resistance properties, decreased CTE, and increased glass transition temperature or Tg less. The cured product exhibits good flame retardant property by the introduction of the alkoxysilyl group.

公开(公告)号：US09150686B2

公开(公告)日：2015-10-06

申请号：US14190043

申请日：2014-02-25

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Hyun-Aee Chun ,  Sang-Yong Tak ,  Su-Jin Park ,  Yun-Ju Kim ,  Sung-Hwan Park

IPC: B32B27/38 ,  B32B27/04 ,  C08G59/14 ,  C08G59/30 ,  C08L63/00 ,  H05K1/03 ,  C07D303/02 ,  C08K7/14 ,  C07F7/18 ,  C07D407/12 ,  C07D303/12 ,  C08J5/24

CPC classification number: C08G59/306 ,  C07D303/12 ,  C07D407/12 ,  C07F7/1804 ,  C07F7/1876 ,  C08J5/24 ,  C08J2363/00 ,  C08K3/36 ,  C08K7/14 ,  C08L63/00

Abstract: Disclosed are an epoxy compound having an alkoxysilyl group, a composite of which exhibits good heat resistant properties and/or a cured product of which exhibits good flame retardant properties, a method of preparing the same, a composition comprising the same, and a cured product and a use of the composition. An alkoxysilylated epoxy compound comprising at least one of Chemical Formula S1 substituent and at least two epoxy groups in a core, a method of preparing the epoxy compound by an allylation, a claisen rearrangement, an epoxidation and an alkoxysilylation, an epoxy composition comprising the epoxy compound, and a cured product and a use of the composition are provided. The composite of the disclosed exhibits improved chemical bonding, good heat resistant properties, a low CTE, a high glass transition temperature or Tg-less. The cured product of the composition exhibits good flame retardant properties.

Abstract translation: 公开了具有烷氧基甲硅烷基的环氧化合物，其具有良好的耐热性的复合材料和/或其具有良好阻燃性能的固化产物，其制备方法，包含该组合物的组合物和固化产物 和使用该组合物。 烷氧基硅烷基化环氧化合物，其包含核心中的化学式S1取代基和至少两个环氧基中的至少一个，通过烯丙基化制备环氧化合物的方法，克莱森重排，环氧化和烷氧基硅烷基化，包含环氧树脂 化合物，以及固化产物和组合物的用途。 所公开的复合材料显示出改善的化学键合，良好的耐热性能，低CTE，高玻璃化转变温度或Tg。 该组合物的固化产物具有良好的阻燃性能。

公开(公告)号：US20140308527A1

公开(公告)日：2014-10-16

申请号：US14355557

申请日：2012-11-01

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Hyun-Aee Chun ,  Sang-Yong Tak ,  Su-Jin Park ,  Yun-Ju Kim ,  Sung-Hwan Park ,  Sook-Yeon Park

IPC: C08G59/30 ,  B32B15/092 ,  C08K3/36 ,  C08K7/14 ,  C07F7/18 ,  C08L63/00

CPC classification number: C08G59/306 ,  B32B15/092 ,  C07D251/32 ,  C07D405/14 ,  C07F7/0812 ,  C07F7/10 ,  C07F7/1804 ,  C08K3/36 ,  C08K7/14 ,  C08L63/00 ,  Y10T428/31529

Abstract: Disclosed are an alkoxysilylated isocyanurate epoxy compound, a composite of which exhibiting low CTE and high glass transition temperature or Tg-less and/or a cured product of which exhibiting good flame retardant property, a method of preparing the same, a composition including the same, a cured product formed of the composition, and a use of the composition. An isocyanurate epoxy compound having an alkoxysilyl group and an epoxy group in a core; a method of manufacturing the epoxy compound by the epoxidation and alkoxysilylation of a starting material; an epoxy composition including the epoxy compound; and a cured product and a use thereof, are provided. A composite of the epoxy composition has improved bonding efficiency between alkoxysilyl group and filler and between alkoxysilyl groups, and has good heat resistance, low CTE, and high glass transition temperature or Tg-less. A cured product formed of the epoxy composition has good flame retardant property.

Abstract translation: 公开了烷氧基甲硅烷基化的异氰脲酸酯环氧化合物，其具有低CTE和高玻璃化转变温度或Tg-Tg的复合材料和/或其具有良好阻燃性能的固化产物，其制备方法，包含其的组合物 ，由该组合物形成的固化产物，以及该组合物的用途。 在核心中具有烷氧基甲硅烷基和环氧基的异氰脲酸酯环氧化合物; 通过原料的环氧化和烷氧基甲硅烷基化制造环氧化合物的方法; 包含环氧化合物的环氧组合物; 和固化产物及其用途。 环氧组合物的复合物提高了烷氧基甲硅烷基与填料之间以及烷氧基甲硅烷基之间的粘合效率，并具有良好的耐热性，低CTE，高玻璃化转变温度或Tg。 由环氧组合物形成的固化产物具有良好的阻燃性能。

公开(公告)号：US10428176B2

公开(公告)日：2019-10-01

申请号：US15534451

申请日：2014-12-09

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Hyun-Aee Chun ,  Sung-Hwan Park ,  Yun-Ju Kim ,  Su-Jin Park ,  Sook-Yeon Park ,  Sang-Yong Tak

IPC: C08G59/40 ,  C08L63/00 ,  C07F7/18 ,  C08K7/14 ,  C08K3/36 ,  C08G59/20

Abstract: The present invention relates to: a thermosetting alkoxysilyl compound (hereinafter, referred to as “alkoxysilyl compound”) having two or more alkoxysilyl groups showing excellent heat-resistance characteristics in a composite; a composition and a cured product comprising the same; a use thereof; and a method for preparing an alkoxysilyl compound. The composition of an alkoxysilyl compound, comprising a novel alkoxysilyl compound according to the present invention shows, in a composite, improved heat-resistance characteristics, i.e., an effect of decreasing the CTE of the composition of an alkoxysilyl compound and not showing a glass transition temperature (hereinafter, referred to as “Tg-less”). Further, the cured product comprising an alkoxysilyl compound according to the present invention shows excellent flame retardant properties due to the alkoxysilyl groups.

公开(公告)号：US09732182B2

公开(公告)日：2017-08-15

申请号：US14834387

申请日：2015-08-24

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Hyun-Aee Chun ,  Sung-Hwan Park ,  Yun-Ju Kim ,  Su-Jin Park ,  Sook-Yeon Park ,  Sang-Yong Tak

IPC: C08G59/06 ,  C08G59/02 ,  C07F7/18 ,  C09J163/00 ,  C07D303/12 ,  C07D303/36 ,  C07D405/06 ,  C08L63/00 ,  C09D163/00 ,  C08G59/30

CPC classification number: C08G59/02 ,  C07D303/12 ,  C07D303/36 ,  C07D405/06 ,  C07F7/1804 ,  C08G59/06 ,  C08G59/306 ,  C08L63/00 ,  C09D163/00 ,  C09J163/00 ,  Y10T428/239

Abstract: Provided are alkoxysilylated epoxy compounds, a composite of which exhibits good heat resistance properties, low CTE and increased glass transition temperature, and a cured product thereof exhibits good flame retardancy without requiring separate coupling agent, a method for preparing the same and a composition and a cured product including the same. An alkoxysilylated epoxy compound including an epoxy group and at least one alkoxysilyl group of an S1 substituent selected from Formulae S11 to S15 or an S2 substituent selected from Formulae S21 to S25; a method for preparing the same by epoxy ring-opening reaction of starting material and alkoxysilylation, an epoxy composition including the epoxy compound, and a cured product and a use of the composition, are provided. Since chemical bonds may be formed between alkoxysilyl group and filler and between alkoxysilyl groups, chemical bonding efficiency of the composite may be improved.

公开(公告)号：US09725590B2

公开(公告)日：2017-08-08

申请号：US14427990

申请日：2013-09-17

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Hyun-Aee Chun ,  Yun-Ju Kim ,  Su-Jin Park ,  Sang-Yong Tak ,  Sung-Hwan Park ,  Kyung-Nam Kang ,  Sook-Yeon Park

IPC: C07F7/08 ,  C07F7/10 ,  C07F7/18 ,  C08L63/00 ,  C09J163/00 ,  C08G59/20 ,  C08G59/30 ,  C08K5/50 ,  C08K7/14 ,  C08G59/32 ,  H01L33/52 ,  H05K1/03

CPC classification number: C08L63/00 ,  C07F7/1804 ,  C08G59/306 ,  C08G59/3281 ,  C08K5/50 ,  C08K7/14

Abstract: Provided are an alkoxysilylated epoxy compound, a composite of which exhibits good heat resistance properties, particularly low CTE and increased glass transition temperature, and a cured product thereof exhibits good flame retardancy and composition of which does not require additional silane coupling agent, a method for preparing the same and a composition and a cured product including the same. An alkoxysilylated epoxy compound including at least one alkoxysilyl group and at least two epoxy groups, a method for preparing the same by epoxide ring-opening reaction of starting material and alkoxysilylation, an epoxy composition including the epoxy compound, and a cured product and a use of the composition are provided. Since chemical bonds may be formed between alkoxysilyl group and filler and between alkoxysilyl groups, chemical bonding efficiency of the composite may be improved. Thus, the composite exhibits good heat resistance properties and the cured product exhibits good flame retardancy.

公开(公告)号：US20150203626A1

公开(公告)日：2015-07-23

申请号：US14413226

申请日：2013-07-05

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Hyun-Aee Chun ,  Yun-Ju Kim ,  Sang-Yong Tak ,  Su-Jin Park ,  Sung-Hwan Park

IPC: C08G59/14 ,  C08K3/36 ,  C08K7/14 ,  C08L63/04

CPC classification number: C08G59/1494 ,  C07D303/04 ,  C07F7/1804 ,  C08G59/08 ,  C08G59/1433 ,  C08K3/36 ,  C08K7/14 ,  C08L63/04 ,  C08L2205/02

Abstract: A novolac epoxy compound having an alkoxysilyl group of which composite has low CTE and increase of glass transition temperature, and requiring no coupling agent, a production method thereof, an epoxy composition including the same and a cured article thereof, are provided. A novolac epoxy compound having an alkoxysilyl group of Formulae I-1 to I-4, a production method of the novolac epoxy compound having an alkoxysilyl group by the epoxidation, alkenylation and alkoxysilylation of a novolac epoxy compound, a production method of the novolac epoxy compound having an alkoxysilyl group by the epoxidation and alkoxysilylation of a novolac epoxy compound, an epoxy composition including the novolac epoxy compound having an alkoxysilyl group, and a cured article, are provided. The cured article, i.e., the composite of the epoxy composition has improved chemical bonding efficiency due to alkoxysilyl groups. Low CTE and high glass transition temperature are exhibited

Abstract translation: 提供了具有低CTE，玻璃化转变温度低，不需要偶联剂的烷氧基甲硅烷基酚醛清漆型环氧化合物，其制造方法，含有它们的环氧组合物及其固化物。 具有式I-1〜I-4的烷氧基甲硅烷基的酚醛清漆型环氧化合物，环氧化作用的具有烷氧基甲硅烷基的酚醛清漆型环氧化合物的制造方法，酚醛清漆型环氧化合物的烯基化和烷氧基化， 提供了通过酚醛环氧化合物的环氧化和烷氧基化作用的具有烷氧基甲硅烷基的化合物，包含具有烷氧基甲硅烷基的酚醛环氧化合物的环氧组合物和固化物。 固化物，即环氧组合物的复合物由于烷氧基甲硅烷基而提高了化学键合效率。 展现了低CTE和高玻璃化转变温度

公开(公告)号：US09896535B2

公开(公告)日：2018-02-20

申请号：US14805339

申请日：2015-07-21

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Hyun-Aee Chun ,  Sang-Yong Tak ,  Su-Jin Park ,  Yun-Ju Kim ,  Sung-Hwan Park

IPC: C08L63/00 ,  C08G59/02 ,  C08G59/30 ,  C08K7/14 ,  C07F7/18 ,  C07D407/12 ,  C07D303/12 ,  C08J5/24 ,  C08K3/36

CPC classification number: C08G59/306 ,  C07D303/12 ,  C07D407/12 ,  C07F7/1804 ,  C07F7/1876 ,  C08J5/24 ,  C08J2363/00 ,  C08K3/36 ,  C08K7/14 ,  C08L63/00

Abstract: Disclosed are an epoxy compound having an alkoxysilyl group, a composite of which exhibits good heat resistant properties and/or a cured product of which exhibits good flame retardant properties, a method of preparing the same, a composition comprising the same, and a cured product and a use of the composition. An alkoxysilylated epoxy compound comprising at least one of Chemical Formula S1 substituent and at least two epoxy groups in a core, a method of preparing the epoxy compound by an allylation, a claisen rearrangement, an epoxidation and an alkoxysilylation, an epoxy composition comprising the epoxy compound, and a cured product and a use of the composition are provided. The composite of the disclosed exhibits improved chemical bonding, good heat resistant properties, a low CTE, a high glass transition temperature or Tg-less. The cured product of the composition exhibits good flame retardant properties.

公开(公告)号：US09670309B2

公开(公告)日：2017-06-06

申请号：US14413226

申请日：2013-07-05

Applicant: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

Inventor： Hyun-Aee Chun ,  Yun-Ju Kim ,  Sang-Yong Tak ,  Su-Jin Park ,  Sung-Hwan Park

IPC: C08G59/20 ,  C08G59/14 ,  C08G77/00 ,  C08L63/04 ,  C08L83/00 ,  C08K7/00 ,  C08K7/04 ,  C07D303/04 ,  C07F7/18 ,  C08K3/36 ,  C08K7/14 ,  C08G59/08

CPC classification number: C08G59/1494 ,  C07D303/04 ,  C07F7/1804 ,  C08G59/08 ,  C08G59/1433 ,  C08K3/36 ,  C08K7/14 ,  C08L63/04 ,  C08L2205/02

Abstract: A novolac epoxy compound having an alkoxysilyl group of which composite has low CTE and increase of glass transition temperature, and requiring no coupling agent, a production method thereof, an epoxy composition including the same and a cured article thereof, are provided. A novolac epoxy compound having an alkoxysilyl group of Formulae I-1 to I-4, a production method of the novolac epoxy compound having an alkoxysilyl group by the epoxidation, alkenylation and alkoxysilylation of a novolac epoxy compound, a production method of the novolac epoxy compound having an alkoxysilyl group by the epoxidation and alkoxysilylation of a novolac epoxy compound, an epoxy composition including the novolac epoxy compound having an alkoxysilyl group, and a cured article, are provided. The cured article, i.e., the composite of the epoxy composition has improved chemical bonding efficiency due to alkoxysilyl groups. Low CTE and high glass transition temperature are exhibited.