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公开(公告)号：US4328343A
公开(公告)日：1982-05-04
申请号：US54926
申请日：1979-07-05
IPC分类号： C07D217/02 , C07D217/14 , C07D217/16 , C07D217/22 , C07D221/04 , C07D455/04 , C07D471/04 , C07D495/04
CPC分类号： C07D221/04 , C07D217/02 , C07D217/14 , C07D217/16 , C07D217/22 , C07D455/04 , C07D471/04 , C07D495/04
摘要： A method of synthesizing fused ring pyridines (annulated) by co-oligomerization of .alpha.,.omega.-diynes with about molar equivalents of nitriles using a Co.sup.+1 catalyst preferably cyclopentadienyl cobalt dicarbonyl. Additionally, new compounds of tricyclic quinolizine-4-ones were produced where excess cyanoacetic ester starting materials were utilized (about 2:1 equivalent nitriles:diyne). The results with the catalyst employed indicated a stepwise mechanism in which cobalt(I) catalyst first forms a metallocycle intermediate derived from the bisacetylene. This cobalt(III) intermediate reacts preferentially with nitriles to give the product annulated pyridines in good yield. Generally, preferred conditions indicated roughly molar equivalents of reactants with no substantial excess of either reactant for the bicyclic compounds. Preferred conditions include a moderate temperature (solvent reflux temperature) and a preferred solvent such as BTX-type solvent (xylene) or an alkane (N-octane) under an inert blanket (nitrogen) for a multi-day period.
摘要翻译： 通过使用Co + 1催化剂，优选环戊二烯基二羰基钴将α，ω-二炔与约摩尔当量的腈共价低聚合成稠环吡啶（环化）的方法。 另外，生产出三价喹诺酮-4-酮的新化合物，其中使用过量的氰基乙酸酯原料（约2:1当量腈：二炔）。 所用催化剂的结果表明，其中钴（I）催化剂首先形成衍生自双乙炔的金属环中间体的逐步机理。 这种钴（III）中间体优先与腈反应，以良好的产率给出产物环状的吡啶。 通常，优选的条件表示大致摩尔当量的双环化合物的反应物基本上不超过任何一种反应物。 优选的条件包括中等温度（溶剂回流温度）和优选的溶剂如BTX型溶剂（二甲苯）或烷烃（N-辛烷）在惰性气氛下（氮气）下进行多天。
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2.发明授权Systems and methods for solar energy storage, transportation, and conversion utilizing photochemically active organometallic isomeric compounds and solid-state catalysts 有权使用光化学活性的有机金属异构体化合物和固态催化剂的太阳能储存，运输和转化的系统和方法公开(公告)号：US08950392B2
公开(公告)日：2015-02-10
申请号：US13002645
申请日：2009-07-13
CPC分类号： H01L31/0586 , C09K5/16 , F28D20/003 , F28D2020/0026 , H01G9/20 , H01M14/005 , H02S40/38 , Y02E10/50 , Y10S204/90
摘要： A system for converting solar energy to chemical energy, and, subsequently, to thermal energy includes a light-harvesting station, a storage station, and a thermal energy release station. The system may include additional stations for converting the released thermal energy to other energy forms, e.g., to electrical energy and mechanical work. At the light-harvesting station, a photochemically active first organometallic compound, e.g., a fulvalenyl diruthenium complex, is exposed to light and is photochemically converted to a second, higher-energy organometallic compound, which is then transported to a storage station. At the storage station, the high-energy organometallic compound is stored for a desired time and/or is transported to a desired location for thermal energy release. At the thermal energy release station, the high-energy organometallic compound is catalytically converted back to the photochemically active organometallic compound by an exothermic process, while the released thermal energy is captured for subsequent use.
摘要翻译： 用于将太阳能转化为化学能的系统，以及随后的热能系统包括光收集站，存储站和热能释放站。 该系统可以包括用于将释放的热能转换成其他能量形式的附加站，例如电能和机械作业。 在光收集站，光化学活性的第一有机金属化合物，例如富瓦烯基二钌配合物暴露于光，并被光化学转化为第二较高能量的有机金属化合物，然后将其运送到储存站。 在储存站，高能量有机金属化合物被储存一段所需的时间和/或被运送到期望的位置以释放热能。 在热能释放站，高能有机金属化合物通过放热过程被催化转化回光化学活性的有机金属化合物，同时释放的热能被捕获用于随后的使用。
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公开(公告)号：US4183864A
公开(公告)日：1980-01-15
申请号：US879492
申请日：1978-02-21
CPC分类号： C07J51/00 , C07C45/511 , C07C49/647 , C07F7/1856 , C07J11/00
摘要： Steroid compounds obtained by co-oligomerization of a side chain functionalized 1,5-hexadiyne with bis(trimethylsilyl)acetylene catalyzed by cyclopentadiene cobalt dicarbonyl, CpCO(CO).sub.2, via intermediate benzocyclobutene formation followed by intramolecular cycloaddition to the sterospecific formation of the steroid nucleus. This constitutes a short steroid synthesis, five steps from commercially available acyclic precursor 1,5-hexadiyne and three steps from 2-methyl-cyclopent-2-enone.
摘要翻译： 通过双链官能化1,5-己二炔与双（三甲基甲硅烷基）乙炔的双链官能化化合物获得的类固醇化合物通过环戊二烯钴二羰基，CpCO（CO）2催化，通过中间体苯并环丁烯形成，然后分子内环加成到类固醇的固相特异性形成 核。 这构成短的类固醇合成，从商业上可得到的无环前体1,5-己二炔5步，从2-甲基 - 环戊-2-烯酮三步。
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4.发明申请公开(公告)号：US20110277747A1
公开(公告)日：2011-11-17
申请号：US13002645
申请日：2009-07-13
CPC分类号： H01L31/0586 , C09K5/16 , F28D20/003 , F28D2020/0026 , H01G9/20 , H01M14/005 , H02S40/38 , Y02E10/50 , Y10S204/90
摘要： A system for converting solar energy to chemical energy, and, subsequently, to thermal energy includes a light-harvesting station, a storage station, and a thermal energy release station. The system may include additional stations for converting the released thermal energy to other energy forms, e.g., to electrical energy and mechanical work. At the light-harvesting station, a photochemically active first organometallic compound, e.g., a fulvalenyl diruthenium complex, is exposed to light and is photochemically converted to a second, higher-energy organometallic compound, which is then transported to a storage station. At the storage station, the high-energy organometallic compound is stored for a desired time and/or is transported to a desired location for thermal energy release. At the thermal energy release station, the high-energy organometallic compound is catalytically converted back to the photochemically active organometallic compound by an exothermic process, while the released thermal energy is captured for subsequent use.
摘要翻译： 用于将太阳能转化为化学能的系统，以及随后的热能系统包括光收集站，存储站和热能释放站。 该系统可以包括用于将释放的热能转换成其他能量形式的附加站，例如电能和机械作业。 在光收集站，光化学活性的第一有机金属化合物，例如富瓦烯基二钌配合物暴露于光，并被光化学转化为第二较高能量的有机金属化合物，然后将其运送到储存站。 在储存站，高能量有机金属化合物被储存一段所需的时间和/或被运送到期望的位置以释放热能。 在热能释放站，高能有机金属化合物通过放热过程被催化转化回光化学活性的有机金属化合物，同时释放的热能被捕获用于随后的使用。
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5.发明授权公开(公告)号：US07261871B2
公开(公告)日：2007-08-28
申请号：US10261366
申请日：2002-09-30
CPC分类号： B82Y30/00 , D01F9/127 , Y10S977/742 , Y10S977/843
摘要： A simple method for the production or synthesis of carbon nanotubes as free-standing films or nanotube mats by the thermal decomposition of transition metal complexed alkynes with aryl, alkyl, alkenyl, or alkynyl substituents. In particular, transition metal (e.g. Co, Ni, Fe, Mo) complexes of diarylacetylenes, e.g. diphenylacetylene, and solid mixtures of these complexes with suitable, additional carbon sources are heated in a vessel. More specifically, the heating of the transition metal complex is completed at a temperature between 400-800° C. and more particularly 550-700° C. for between 0.1 to 24 hours and more particularly 0.5-3 hours in a sealed vessel under a partial pressure of argon or helium.
摘要翻译： 通过过渡金属络合的炔与芳基，烷基，烯基或炔基取代基的热分解，生产或合成碳纳米管作为自立膜或纳米管垫的简单方法。 特别地，二芳基乙炔的过渡金属（例如Co，Ni，Fe，Mo）络合物，例如， 二苯基乙炔和这些络合物与合适的另外的碳源的固体混合物在容器中加热。 更具体地说，过渡金属络合物的加热在400-800℃，更特别是550-700℃的温度下在密封容器中在0.1至24小时之间完成，更特别地在0.5-3小时内完成 氩气或氦气的分压。
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