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1.发明申请公开(公告)号：US20130190471A1
公开(公告)日：2013-07-25
申请号：US13806055
申请日：2011-06-23
摘要： Provided are: an impact-resistant polyamide composition which exhibits improved toughness and improved impact strength and which can be easily polymerized in-situ in a molding stage; and a novel process for the production of the same. The novel process comprises initiating the anionic polymerization of ε-caprolactam in the presence of (A) an anionic polymerization catalyst, (B) an anionic polymerization activator, (C) 2.0 to 30% by weight (relative to the ε-caprolactam) of an N,N-disubstituted vinylbenzylamine, and (D) a radical polymerization initiator, and subjecting the resulting system to reaction under conditions comprising a reaction temperature of the reaction system of 120 to 180° C. and a reaction time of 10 seconds to 120 minutes. Since radical polymerization in the process is conducted without hindering the anionic polymerization, an alloyed polyamide composed of both polycaprolactam and poly (N,N-disubstituted vinylbenzylamine) can be obtained.
摘要翻译： 提供：耐冲击聚酰胺组合物，其显示出改进的韧性和改善的冲击强度，并且可以容易地在模塑阶段中原位聚合; 和一种新的生产方法。 该新方法包括在（A）阴离子聚合催化剂存在下引发ε-己内酰胺的阴离子聚合，（B）阴离子聚合活化剂，（C）2.0-30重量％（相对于ε-己内酰胺） N，N-二取代的乙烯基苄胺和（D）自由基聚合引发剂，并将所得体系在包括反应体系的反应温度为120至180℃，反应时间为10秒至120℃的条件下反应 分钟。 由于在不阻碍阴离子聚合的情况下进行自由基聚合，所以可以得到由聚己内酰胺和聚（N，N-二取代乙烯基苄基胺）组成的合金化聚酰胺。
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2.发明申请Method for producing fiber-reinforced thermoplastics plastic and fiber-reinforced thermoplastic prastic 审中-公开纤维增强热塑性塑料和纤维增强热塑性塑料的生产方法公开(公告)号：US20070010611A1
公开(公告)日：2007-01-11
申请号：US10540540
申请日：2003-12-26
申请人： Norio Hirayama , Hirofumi Nishida
发明人： Norio Hirayama , Hirofumi Nishida
IPC分类号： C08K3/40
CPC分类号： B29C43/003 , C08J5/043
摘要： A method of manufacturing a fiber-reinforced thermoplastics, comprising a mixing step for mixing an uncured thermosetting resin with reinforcing fibers to obtain a mixture, and a reaction step for forming the thermoplastics by causing a polymerization reaction of the thermosetting resin in the mixture so that the thermosetting resin polymerizes.
摘要翻译： 一种制造纤维增强热塑性塑料的方法，包括将未固化的热固性树脂与增强纤维混合以获得混合物的混合步骤，以及通过使热固性树脂在混合物中的聚合反应形成热塑性塑料的反应步骤，使得 热固性树脂聚合。
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公开(公告)号：US20080139758A1
公开(公告)日：2008-06-12
申请号：US11661208
申请日：2005-08-24
申请人： Hirofumi Nishida
发明人： Hirofumi Nishida
CPC分类号： C08G59/4007 , C08G59/40 , C08G59/4207 , C08G59/68 , C08G59/685 , C08G65/105 , C08G65/2648 , C08L63/00
摘要： A polymerizable epoxy compound composition containing an anionic polymerization initiator which can be easily produced, can attain a high polymerization rate and a high degree of polymerization, and can realize an epoxy polymer having properties unobtainable so far, an improvement in cured polymer properties, etc.; and a method of polymerizing an epoxy compound. The composition is an anionically polymerizable composition comprising a monofunctional epoxy compound or a di- or more functional epoxy resin and a polymerization initiator, the polymerization initiator comprising the potassium or sodium salt of a monocarboxylic acid monomer. The method, which is for producing a polymer of epoxy compounds, comprises polymerizing a monofunctional epoxy compound or a di- or more functional epoxy resin by anionic polymerization with the aid of the potassium or sodium salt of a monocarboxylic acid monomer.
摘要翻译： 可以容易地制造含有阴离子聚合引发剂的可聚合环氧化合物组合物可以获得高聚合速率和高聚合度，并且可以实现迄今为止无法获得的性能，聚合物固化性能的改善等的环氧聚合物。 ; 和环氧化合物的聚合方法。 该组合物是包含单官能环氧化合物或二官能或更多功能的环氧树脂和聚合引发剂的阴离子可聚合组合物，聚合引发剂包含单羧酸单体的钾盐或钠盐。 用于生产环氧化合物的聚合物的方法包括通过阴离子聚合在一元羧酸单体的钾盐或钠盐的作用下聚合单官能环氧化合物或二官能以上的环氧树脂。
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公开(公告)号：US5278113A
公开(公告)日：1994-01-11
申请号：US845079
申请日：1992-03-03
申请人： Yukiyoshi Ono , Kunio Kimura , Hidenobu Wakita , Yasue Yamade , Hirofumi Nishida
发明人： Yukiyoshi Ono , Kunio Kimura , Hidenobu Wakita , Yasue Yamade , Hirofumi Nishida
IPC分类号： B01D53/86 , B01J29/068 , B01J37/02 , B01J29/06
CPC分类号： B01J29/068 , B01D53/86 , B01J37/0244 , B01J37/0246
摘要： A catalytic body contains a base material and, formed on the surface thereof, a catalytic coating layer containing activated alumina, zeolite, a platinum group metal and an inorganic binder.By alternately repeating the step of adsorption of odor components with zeolite and alumina under non-heating condition and the step of heat-regeneration of the zeolite and alumina and catalytic decomposition of odor components under heating condition, offensive odors can be continuously removed over a long period and without excessively raising the temperature in the surroundings of the catalytic body.
摘要翻译： 催化体含有基材，并在其表面上形成含有活性氧化铝，沸石，铂族金属和无机粘合剂的催化剂涂层。 通过在非加热条件下交替重复用沸石和氧化铝吸附气味组分的步骤，沸石和氧化铝的热再生步骤以及加热条件下气味组分的催化分解，可以长时间连续除去令人反感的气味 并且不会过度升高催化体周围的温度。
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公开(公告)号：US20080139698A1
公开(公告)日：2008-06-12
申请号：US11666600
申请日：2005-10-25
申请人： Hirofumi Nishida , Norio Hirayama
发明人： Hirofumi Nishida , Norio Hirayama
IPC分类号： C08K9/00
CPC分类号： C08G59/32 , C08G59/38 , C08G59/42 , C08G59/681 , C08G59/685 , C08K7/14 , C08L63/00 , Y10T428/24994 , Y10T428/31511
摘要： A high heat-resistant composite material which comprises a polymerizable composition comprising a bi-functional epoxy compound, a tri- or more-functional epoxy compound and a polymerization initiator, wherein the polymerization initiator comprises a sodium salt or potassium salt of mono- or poly-functional carboxylic acid, and a reinforcing fiber such as a carbon fiber or a glass fiber; and a vehicle member or a construction member comprising the above heat-resistant composite material. Said composite material comprises an epoxy polymer having high heat-resistant physical properties over those of a conventional epoxy polymer as a matrix, and exhibits an extremely high retention factor of storage modulus at high temperature.
摘要翻译： 一种高耐热复合材料，其包含可聚合组合物，其包含双功能环氧化合物，三官能或更多官能的环氧化合物和聚合引发剂，其中所述聚合引发剂包括单或多价的钠盐或钾盐 官能羧酸，以及增强纤维如碳纤维或玻璃纤维; 以及包括上述耐热复合材料的车辆构件或构造构件。 所述复合材料包含与作为基质的常规环氧聚合物相比具有高耐热物理性能的环氧聚合物，并且在高温下表现出非常高的储能模量保留因子。
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公开(公告)号：US5551170A
公开(公告)日：1996-09-03
申请号：US225903
申请日：1994-04-11
申请人： Hideaki Sakatani , Hirofumi Nishida , Yoji Uetani , Yoichi Kuroki , Keiko Hata , Tatsuo Fujita , Tatsuo Kikawa , Seichi Ueno , Yukio Hayashida
发明人： Hideaki Sakatani , Hirofumi Nishida , Yoji Uetani , Yoichi Kuroki , Keiko Hata , Tatsuo Fujita , Tatsuo Kikawa , Seichi Ueno , Yukio Hayashida
CPC分类号： B02C17/002 , B09B3/00 , F26B11/14 , F26B25/22
摘要： Refuse 21 in a refuse container 2 is heated by a heater 16, and the steam generated from the refuse 21 is condensed by a condenser 8. The ambient temperature near the refuse container 2 is detected by a first temperature detector 6, and the output of the heater 16 is controlled by the output of the first temperature detector 6 so that the temperature near the refuse container 2 may be a specific temperature, and the temperature of the steam flowing out from the refuse container 2 into the condenser 8 is detected by a second temperature detector 7 at the condenser 8. When the temperature change of the second temperature detector 7 exceeds a specific value, the drying process is terminated, so that the drying end time can be detected accurately without allowing to scorch.
摘要翻译： 垃圾箱2中的垃圾21被加热器16加热，并且由垃圾21产生的蒸汽被冷凝器8冷凝。垃圾容器2附近的环境温度由第一温度检测器6检测， 加热器16由第一温度检测器6的输出控制，使得垃圾容器2附近的温度可以是特定的温度，并且从垃圾容器2流出到冷凝器8的蒸汽的温度由 第二温度检测器7在冷凝器8处。当第二温度检测器7的温度变化超过特定值时，干燥过程终止，从而可以准确地检测干燥结束时间，而不会使焦烧。
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7.发明授权公开(公告)号：US09006381B2
公开(公告)日：2015-04-14
申请号：US13806055
申请日：2011-06-23
摘要： Provided are: an impact-resistant polyamide composition which exhibits improved toughness and improved impact strength and which can be easily polymerized in-situ in a molding stage; and a novel process for the production of the same. The novel process comprises initiating the anionic polymerization of ε-caprolactam in the presence of (A) an anionic polymerization catalyst, (B) an anionic polymerization activator, (C) 2.0 to 30% by weight (relative to the ε-caprolactam) of an N,N-disubstituted vinylbenzylamine, and (D) a radical polymerization initiator, and subjecting the resulting system to reaction under conditions comprising a reaction temperature of the reaction system of 120 to 180° C. and a reaction time of 10 seconds to 120 minutes. Since radical polymerization in the process is conducted without hindering the anionic polymerization, an alloyed polyamide composed of both polycaprolactam and poly (N,N-disubstituted vinylbenzylamine) can be obtained.
摘要翻译： 提供：耐冲击聚酰胺组合物，其显示出改进的韧性和改善的冲击强度，并且可以容易地在模塑阶段中原位聚合; 和一种新的生产方法。 该新方法包括在（A）阴离子聚合催化剂，（B）阴离子聚合活化剂，（C）2.0-30重量％（相对于ε-己内酰胺） ）的N，N-二取代的乙烯基苄基胺和（D）自由基聚合引发剂，并将所得体系在包括反应体系的反应温度为120-180℃并且反应时间为10秒的条件下反应 至120分钟。 由于在不阻碍阴离子聚合的情况下进行自由基聚合，所以可以得到由聚己内酰胺和聚（N，N-二取代乙烯基苄基胺）组成的合金化聚酰胺。
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公开(公告)号：US08530053B2
公开(公告)日：2013-09-10
申请号：US11666600
申请日：2005-10-25
申请人： Hirofumi Nishida , Norio Hirayama
发明人： Hirofumi Nishida , Norio Hirayama
IPC分类号： B32B27/26 , B32B27/04 , B32B27/38 , C08G59/22 , C08G59/32 , C08G59/38 , C08G59/68 , C08L63/00
CPC分类号： C08G59/32 , C08G59/38 , C08G59/42 , C08G59/681 , C08G59/685 , C08K7/14 , C08L63/00 , Y10T428/24994 , Y10T428/31511
摘要： A high heat-resistant composite material which comprises a polymerizable composition comprising a bi-functional epoxy compound, a tri- or more-functional epoxy compound and a polymerization initiator, wherein the polymerization initiator comprises a sodium salt or potassium salt of mono- or poly-functional carboxylic acid, and a reinforcing fiber such as a carbon fiber or a glass fiber; and a vehicle member or a construction member comprising the above heat-resistant composite material. Said composite material comprises an epoxy polymer having high heat-resistant physical properties over those of a conventional epoxy polymer as a matrix, and exhibits an extremely high retention factor of storage modulus at high temperature.
摘要翻译： 一种高耐热复合材料，其包含可聚合组合物，其包含双功能环氧化合物，三官能或更多官能的环氧化合物和聚合引发剂，其中所述聚合引发剂包括单或多价的钠盐或钾盐 官能羧酸，以及增强纤维如碳纤维或玻璃纤维; 以及包括上述耐热复合材料的车辆构件或构造构件。 所述复合材料包含与作为基质的常规环氧聚合物相比具有高耐热物理性能的环氧聚合物，并且在高温下表现出非常高的储能模量保留因子。
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公开(公告)号：US5482685A
公开(公告)日：1996-01-09
申请号：US225808
申请日：1994-04-11
申请人： Tatsuo Fujita , Syuzo Tokumitsu , Hirofumi Nishida , Tadashi Suzuki , Yukiyoshi Ono , Tetsuo Terashima , Takeshi Tomizawa , Jiro Suzuki , Syuji Asada , Yukiyoshi Nishikori
发明人： Tatsuo Fujita , Syuzo Tokumitsu , Hirofumi Nishida , Tadashi Suzuki , Yukiyoshi Ono , Tetsuo Terashima , Takeshi Tomizawa , Jiro Suzuki , Syuji Asada , Yukiyoshi Nishikori
CPC分类号： F24F3/16 , B01D53/885 , F24F2003/1628
摘要： A catalyst 1 is provided in a gas passage 4 for communicating between a gas flow-in unit 12 and a gas flow-out unit 13, and the catalyst 1 is heated by a heater 2, and a temperature sensor 3 for detecting the temperature of the heater 2 is provided inside the heater 2. By feeding power to the heater 2, the wall temperature of the heater 2 is raised to heat the catalyst 1, and then malodorous gas containing odor substances is passed in from the gas flow-in unit 12. The malodorous gas passes through the catalyst 1 in the gas passage 4 to be oxidized to be harmless and odorless, and is discharged from the gas flow-out unit 13.
摘要翻译： 催化剂1设置在用于气体流入单元12和气体流出单元13之间连通的气体通道4中，催化剂1被加热器2加热，温度传感器3用于检测温度 加热器2设置在加热器2的内部。通过向加热器2供电，升温加热器2的壁温度以加热催化剂1，然后从气体流入单元中通入含气味物质的恶臭气体 恶臭气体通过气体通道4中的催化剂1，被氧化成无害和无臭，并从气体流出单元13排出。
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公开(公告)号：US08809470B2
公开(公告)日：2014-08-19
申请号：US11661208
申请日：2005-08-24
申请人： Hirofumi Nishida
发明人： Hirofumi Nishida
CPC分类号： C08G59/4007 , C08G59/40 , C08G59/4207 , C08G59/68 , C08G59/685 , C08G65/105 , C08G65/2648 , C08L63/00
摘要： A polymerizable epoxy compound composition containing an anionic polymerization initiator which can be easily produced, can attain a high polymerization rate and a high degree of polymerization, and can realize an epoxy polymer having properties unobtainable so far, an improvement in cured polymer properties, etc.; and a method of polymerizing an epoxy compound. The composition is an anionically polymerizable composition comprising a monofunctional epoxy compound or a di- or more functional epoxy resin and a polymerization initiator, the polymerization initiator comprising the potassium or sodium salt of a monocarboxylic acid monomer. The method, which is for producing a polymer of epoxy compounds, comprises polymerizing a monofunctional epoxy compound or a di- or more functional epoxy resin by anionic polymerization with the aid of the potassium or sodium salt of a monocarboxylic acid monomer.
摘要翻译： 可以容易地制造含有阴离子聚合引发剂的可聚合环氧化合物组合物可以获得高聚合速率和高聚合度，并且可以实现迄今为止无法获得的性能，聚合物固化性能的改善等的环氧聚合物。 ; 和环氧化合物的聚合方法。 该组合物是包含单官能环氧化合物或二官能或更多功能的环氧树脂和聚合引发剂的阴离子可聚合组合物，聚合引发剂包含单羧酸单体的钾盐或钠盐。 用于生产环氧化合物的聚合物的方法包括通过阴离子聚合在一元羧酸单体的钾盐或钠盐的作用下聚合单官能环氧化合物或二官能以上的环氧树脂。
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