公开(公告)号：US4728337A

公开(公告)日：1988-03-01

申请号：US925027

申请日：1986-10-30

申请人： Heinz Abel ,  Rosemarie Topfl ,  Franz Gunter

发明人： Heinz Abel ,  Rosemarie Topfl ,  Franz Gunter

IPC分类号： D06M13/02 ,  D06M13/322 ,  D06M13/332 ,  D06M13/405 ,  D06M13/46 ,  D06M13/463 ,  D06M13/467 ,  D06P1/52 ,  D06P1/645 ,  D06P1/647 ,  D06P1/649 ,  D06P1/66 ,  D06P3/16 ,  D06P5/06 ,  D06M15/37

CPC分类号： D06M13/405 ,  D06M13/332 ,  D06M13/467 ,  D06P1/5278 ,  D06P1/66 ,  D06P5/06 ,  Y10S8/917

摘要： An assistant combination for use as textile finishing agent, especially in a process for aftertreating wool dyeings, which comprises(1) a diquaternary ammonium salt of formula ##STR1## wherein Q is a divalent aliphatic hydrocarbon radical of 2 to 12 carbon atoms which may be interrupted in the chain by oxygen atoms and is unsubstituted or substituted by hydroxy.R.sub.1 and R.sub.2 are each independently of the other an aliphatic radical of 6 to 24 carbon atoms,R.sub.3 to R.sub.6 are independently of the other lower alkyl, hydroxy-lower alkyl or lower alkoxy-lower alkyl,X.sub.1 and X.sub.2 are each oxygen or --NH--,Z.sub.1 and Z.sub.2 are each independently of the other C.sub.2 -C.sub.6 alkylene, andY.sup..crclbar. is an anion of a strong inorganic or organic acid, and(2) (A) a mono- or polyquaternary ammonium salt which carries at least one hydrocarbon radical of not less than 7 carbon atoms attached to the nitrogen atom, or(B) a polymeric ammonium salt, or(C) a basic non-quaternized nitrogen-containing polycondensate.

摘要翻译： 用作织物整理剂的助剂组合物，特别是在羊毛染色后处理的方法中，其包括（1）式（1）的二季铵盐，其中Q是2至12个碳原子的二价脂族烃基 其可以在链中被氧原子中断，并且是未取代的或被羟基取代。 R 1和R 2各自独立地为6至24个碳原子的脂族基团，R 3至R 6独立于其它低级烷基，羟基 - 低级烷基或低级烷氧基 - 低级烷基，X 1和X 2各自为氧或-NH - ，Z 1和Z 2各自独立地为C 2 -C 6亚烷基，Y（ - ）是强无机或有机酸的阴离子，和（2）（A）单或多季铵盐，其携带至少一种 与氮原子连接的不少于7个碳原子的烃基，或（B）聚合铵盐，或（C）碱性非季铵化含氮缩聚物。

公开(公告)号：US5074888A

公开(公告)日：1991-12-24

申请号：US680626

申请日：1991-03-29

申请人： Rosemarie Topfl ,  Heinz Abel

发明人： Rosemarie Topfl ,  Heinz Abel

IPC分类号： C08G65/26 ,  C08G65/332 ,  C08L71/02 ,  D06M13/165 ,  D06P1/613

CPC分类号： C08G65/2609 ,  C08G65/3322 ,  C08L71/02 ,  D06M13/165 ,  D06P1/6131

摘要： A composition suitable for use as dyeing or textile auxiliary and which comprises a mixture of acid esters of adducts of ethylene oxide and propylene oxide with fatty alcohols having not less than 6 carbon atoms, at least one component of which composition is an acid ester of the formula ##STR1## wherein s is 3 to 10, p is 5 to 15,R is an aliphatic radical of not less than 6 carbon atoms; one of Z.sub.1 and Z.sub.2 is methyl and the other is hydrogen, andX is the acid radical of a low molecular aliphatic dicarboxylic acid, in particular maleic acid.This composition is used in particular as low foaming wetting agent and padding auxiliary for pretreating or dyeing cellulosic fibre materials.

公开(公告)号：US4767568A

公开(公告)日：1988-08-30

申请号：US876133

申请日：1986-06-19

申请人： Heinz Abel ,  Rosemarie Topfl

发明人： Heinz Abel ,  Rosemarie Topfl

IPC分类号： B01D19/04 ,  D06P1/613 ,  D06P1/649 ,  D06P1/651

CPC分类号： D06P1/65162 ,  B01D19/0404 ,  D06P1/613 ,  D06P1/6497 ,  D06P1/65125

摘要： The invention relates to foam inhibitors comprising(1) (A) a reaction product of a polyol, an anhydride of an aliphatic C.sub.2 -C.sub.10 dicarboxylic acid and an adduct of a polyalkylene glycol and a fatty acid, or (B) a reaction product of a polyol, an anhydride of an aliphatic C.sub.2 -C.sub.10 dicarboxylic acid, a higher aliphatic alcohol and a polyethylene glycol,(2) a dialkyl ester of an unsaturated dicarboxylic acid,(3) a mineral oil,(4) a nonionic emulsifier,(5) an anionic emulsifier, and(6) an alkylene diamide,to liquid formulations of such foam inhibitors, and to a process for defoaming aqueous systems with the aid thereof.

摘要翻译： 本发明涉及泡沫抑制剂，其包含（1）（A）多元醇，脂族C 2 -C 10二羧酸的酸酐和聚亚烷基二醇与脂肪酸的加合物的反应产物，或（B） 多元醇，脂肪族C 2 -C 10二羧酸的酸酐，高级脂肪醇和聚乙二醇，（2）不饱和二羧酸的二烷基酯，（3）矿物油，（4）非离子乳化剂，（5） 阴离子乳化剂和（6）亚烷基二酰胺，用于这种泡沫抑制剂的液体制剂，以及借助于该方法消除含水体系的方法。

公开(公告)号：US4559162A

公开(公告)日：1985-12-17

申请号：US353309

申请日：1982-03-01

申请人： Heinz Abel ,  Rosemarie Topfl

发明人： Heinz Abel ,  Rosemarie Topfl

IPC分类号： B01D19/04 ,  B01F17/54 ,  C02F1/20 ,  C08L83/00 ,  C09D133/06 ,  D06P1/52 ,  D06P1/613 ,  D06P1/651 ,  C09K3/00

CPC分类号： D06P1/651 ,  B01D19/0404 ,  C02F1/20 ,  C09D133/06 ,  D06P1/5257 ,  D06P1/613 ,  C08L83/00

摘要： Surfactant-containing compositions of(a) homopolymers of alkyl acrylates or methacrylates or copolymers of these alkyl esters with styrene or acrylic or methyacyrlic acid and(b) hydronaphthalenes, alkylbenzenes, alkanols, alkylene oxide adducts of polyhydric alcohols or maleates of aliphatic alcohols can be used as anti-foams and deaerating agents for aqeuous systems.As the surfactants, the compositions contain at least(d) an anionic surfactant and/or(e) a non-ionic surfactant.In addition to components (a) and (b), the surfactant-containing compositions can contain(c) hydrophobic silicone oils,(f) hydrophilic siloxanoxyalkylene copolymers and/or(g) hydrocarbon mixtures of paraffins and, if appropriate, naphthenes and aromatics.

摘要翻译： （a）丙烯酸烷基酯或甲基丙烯酸烷基酯的均聚物或这些烷基酯与苯乙烯或丙烯酸或甲基吡啶酸的共聚物和（b）氢化萘，烷基苯，链烷醇，多元醇的烯化氧加合物或脂族醇的马来酸酯的含有表面活性剂的组合物可以是 用作反泡沫和脱气剂用于苛性体系。 作为表面活性剂，组合物至少包含（d）阴离子表面活性剂和/或（e）非离子表面活性剂。 除了组分（a）和（b）之外，含表面活性剂的组合物可以含有（c）疏水性硅油，（f）亲水性硅氧烷氧化烯共聚物和/或（g）链烷烃的烃混合物，如果合适的话，可以含有环烷烃和芳烃 。

公开(公告)号：US3944385A

公开(公告)日：1976-03-16

申请号：US386139

申请日：1973-08-06

申请人： Hans Hostettler ,  Heinz Abel ,  Rosemarie Topfl

发明人： Hans Hostettler ,  Heinz Abel ,  Rosemarie Topfl

IPC分类号： D06M13/02 ,  D06M13/224 ,  D06M13/322 ,  D06M13/325 ,  D06M15/55 ,  D06M15/592 ,  D06M101/00 ,  D06M101/02 ,  D06M101/10 ,  D06M101/12 ,  D06M3/02

CPC分类号： D06M15/592

摘要： A process for rendering wool non-felting is provided, wherein the wool is treated with aqueous preparations containing a monopersulphine acid salt, an epoxide reaction product, a fatty amine ethylene oxide adduct and a softening agent. Very good non-felting effects without adverse influence on the handle are obtained.

摘要翻译： 提供了一种使羊毛不起毛的方法，其中羊毛用含有单过硫酸盐，环氧化物反应产物，脂肪胺环氧乙烷加合物和软化剂的含水制剂进行处理。 获得非常好的非毡化效果，而不会对手柄产生不利影响。

公开(公告)号：US4894183A

公开(公告)日：1990-01-16

申请号：US147093

申请日：1988-01-20

申请人： Rosemarie Topfl ,  Heinz Abel

发明人： Rosemarie Topfl ,  Heinz Abel

IPC分类号： C08G65/26 ,  C08G65/332 ,  C08L71/02 ,  D06M13/165 ,  D06P1/613

CPC分类号： C08G65/2609 ,  C08G65/3322 ,  C08L71/02 ,  D06M13/165 ,  D06P1/6131

摘要： A composition suitable for use as dyeing or textile auxiliary and which comprises a mixture of acid esters of adducts of ethylene oxide and propylene oxide with fatty alcohols having not less than 6 carbon atoms, at least one component of which composition is an acid ester of the formula ##STR1## wherein s is 3 to 10, p is 5 to 15, R is an aliphatic radical of not less than 6 carbon atoms; one of Z.sub.1 and Z.sub.2 is methyl and the other is hydrogen, and X is the acid radical of a low molecular aliphatic dicarboxylic acid, in particular maleic acid. This composition is used in particular as low foaming wetting agent and padding auxliary for pretreating or dyeing cellulosic fibre materials.

摘要翻译： 适合用作染色或纺织助剂的组合物，其包含环氧乙烷和环氧丙烷的加成酸的酸酯与不少于6个碳原子的脂肪醇的混合物，其组成为至少一种组分为 式（1）其中s为3至10，p为5至15，R为不少于6个碳原子的脂族基团; Z1和Z2之一是甲基，另一个是氢，X是低分子量脂族二羧酸，特别是马来酸的酸基。 该组合物特别用作低发泡润湿剂和用于预处理或染色纤维素纤维材料的填充辅助材料。

公开(公告)号：US4721512A

公开(公告)日：1988-01-26

申请号：US925058

申请日：1986-10-30

申请人： Rosemarie Topfl ,  Heinz Abel ,  Jorg Binz

发明人： Rosemarie Topfl ,  Heinz Abel ,  Jorg Binz

IPC分类号： D06P3/60 ,  D06P5/06 ,  D06P5/08 ,  D06M1/00

CPC分类号： D06P5/08 ,  D06P5/06

摘要： A process for aftertreating cellulosic fibre material using an aqueous liquor which comprises(A) a diquaternary ammonium salt of formula ##STR1## wherein Q is a divalent aliphatic hydrocarbon radical of 2 to 12 carbon atoms which may be interrupted in the chain by oxygen atoms and is unsubstituted or substituted by hydroxy groups,R.sub.1 and R.sub.2 are each independently of the other an aliphatic radical of 6 to 24 carbon atoms,R.sub.3 to R.sub.6 are each independently of the other lower alkyl, hydroxy-lower alkyl or lower alkoxy-lower alkyl,X.sub.1 and X.sub.2 are each oxygen or --NH--,Z.sub.1 and Z.sub.2 are each independently of the other C.sub.2 -C.sub.6 alkylene, andY.crclbar. is an anion of a strong inorganic or organic acid, and(B) a polybasic nitrogen-containing polycondensate.

摘要翻译： 一种使用含水液体后处理纤维素纤维材料的方法，该方法包括：（A）式（1）的二季铵盐，其中Q是2至12个碳原子的二价脂族烃基，其可以在链中被中断， 氧原子，未取代或被羟基取代，R 1和R 2各自独立地为6至24个碳原子的脂族基团，R 3至R 6各自独立地为低级烷基，羟基 - 低级烷基或低级烷氧基 - 低级烷基，X 1和X 2各自为氧或-NH-，Z 1和Z 2各自独立地为C 2 -C 6亚烷基，Y（ - ）为强无机或有机酸的阴离子，（B）多元氮 含缩聚物。

公开(公告)号：US4713482A

公开(公告)日：1987-12-15

申请号：US841420

申请日：1986-03-19

申请人： Rosemarie Topfl ,  Heinz Abel

发明人： Rosemarie Topfl ,  Heinz Abel

IPC分类号： C08G65/26 ,  C08G65/332 ,  D06P1/607 ,  C07C69/60 ,  C07C69/80

CPC分类号： C08G65/332 ,  C08G65/2624 ,  D06P1/6076

摘要： Acid half esters of the formula ##STR1## or quaternary ammonium compounds thereof, wherein R is an aliphatic radical of 12 to 24 carbon atoms, one of Y.sub.1 and Y.sub.2 is hydrogen and the other is phenyl, one of X.sub.1 and X.sub.2 is hydrogen and the other is methyl, one of Z.sub.1 and Z.sub.2 is hydrogen and the other is the maleic acid radical or the phthalic acid radical, m.sub.1 and m.sub.2 are 0 or 1, s.sub.1, s.sub.2, p.sub.1 and p.sub.2 are integers, with the sum of s.sub.1 +s.sub.2 being 25 to 50 and the sum of p.sub.1 +p.sub.2 is 4 to 15.These compounds are suitable for a wide range of utilities in textile application. In particular, they are used as assistants for dyeing wool-containing fibre materials with anionic dyes or mixtures of dyes.

摘要翻译： 式（1）的酸性半酯或其季铵化合物，其中R是12-24个碳原子的脂族基团，Y1和Y2之一是氢，另一个是苯基，X1和X2之一是 氢和另一个是甲基，Z1和Z2之一是氢，另一个是马来酸基或邻苯二甲酸基，m1和m2是0或1，s1，s2，p1和p2是整数，其总和 s1 + s2为25〜50，p1 + p2的和为4〜15。这些化合物适用于纺织应用中的广泛用途。 特别地，它们用作用阴离子染料或染料混合物染色含羊毛纤维材料的助剂。

公开(公告)号：US4906413A

公开(公告)日：1990-03-06

申请号：US270378

申请日：1988-11-10

申请人： Rosemarie Topfl ,  Heinz Abel ,  Jorg Binz

发明人： Rosemarie Topfl ,  Heinz Abel ,  Jorg Binz

IPC分类号： D06M13/46 ,  C07C219/06 ,  C07C233/36 ,  D06M13/02 ,  D06M13/322 ,  D06M13/332 ,  D06M13/405 ,  D06M13/467 ,  B01F17/18 ,  C07C93/04 ,  C07C103/54

CPC分类号： D06M13/405 ,  D06M13/332 ,  D06M13/467 ,  Y10T442/277

摘要： Diquaternary ammonium salts of the formula ##STR1## wherein A.sub.1 and A.sub.2 are each independently of the other C.sub.2 -C.sub.5 alkylene,Q.sub.1 and Q.sub.2 are each independently of the other --NH-- or --O--,R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each independently alkyl, hydroxyalkyl or alkoxyalkyl, each containing 1 to 4 carbon atoms in the alkyl moiety,Y.sub.1.sup.1.crclbar. is the anion of a strong acid,Z.sub.1 is C.sub.3 -C.sub.24 alkylene which is substituted by hydroxy and may be interrupted by oxygen atoms andn is 1 or 2.are suitable for use as textile finishing agents.

摘要翻译： 其中A 1和A 2各自独立地为C 2 -C 5亚烷基，Q 1和Q 2各自独立地为其它的-NH-或-O-，R 1，R 2，R 3 和R 4各自独立地为在烷基部分含有1至4个碳原子的烷基，羟基烷基或烷氧基烷基，Y 11（ - ）是强酸的阴离子，Z1是被羟基取代的C 3 -C 24亚烷基，并且可以被 氧原子，n为1或2.适用于纺织整理剂。

公开(公告)号：US4066392A

公开(公告)日：1978-01-03

申请号：US613649

申请日：1975-09-15

申请人： Heinz Abel ,  Rosemarie Topfl

发明人： Heinz Abel ,  Rosemarie Topfl

IPC分类号： D06M15/55 ,  D06M15/564 ,  D06M15/63 ,  D06M13/26 ,  D06M13/38 ,  D06M15/12 ,  D06M15/52

CPC分类号： D06M15/55 ,  D06M15/564 ,  D06M15/63 ,  Y10T442/2385

摘要： A process for modifying keratinous material is provided, which comprises treating said material with organic solutions or aqueous emulsions which contain1. polythiols with at least two thiol groups in the molecule and having a molecular weight of 400 to 20,000 and obtained fromA. polyalcoholsB. alkylene oxides and/or dicarboxylic acids andC.sub.1. carboxylic acids containing thio groups, or fromC.sub.2. epihalohydrins and alkali hydrogen sulphides, the polythiols containing ether and/or ester bonds, or fromA.sub.1. polycarboxylic acidsB.sub.1. alkylene oxides or dialcohols andC.sub.1. carboxylic acids containing thio groups,2. nitrogen-containing condensation products of epoxides, fatty amines, dicarboxylic acids, the equivalent ratios of epoxide groups to hydrogen bound to amino nitrogen to carboxylic acid groups being 1:(0.1-1):(1-0.55), and, optionally, of aliphatic diols and/or aminoplast precondensates which contain alkyl ether groups and/or of epihalohydrins and, optionally,3. stabilizers against the harmful action of light, and subsequently drying the treated material.The stabilizers are preferably monomeric phenols with at least one sterically hindered hydroxyl group. The finished goods withstand washing in machines showing good shrink-resist effects and retain their original dimension and shape.