Treatment of Lewis base polymers to improve antistatic, hygroscopic and
dye receptive properties
    1.
    发明授权
    Treatment of Lewis base polymers to improve antistatic, hygroscopic and dye receptive properties 失效
    路易斯碱聚合物的处理以改善抗静电,吸湿性和染料接受性

    公开(公告)号:US4806125A

    公开(公告)日:1989-02-21

    申请号:US100547

    申请日:1987-09-24

    Inventor: Michael E. Dyer

    CPC classification number: C08G69/48

    Abstract: A method is provided for treating and modifying solid, high molecular weight Lewis base polymers, particularly shaped structures such as fibers, filaments or knitted fabrics, to form branched polymer with improved electrical conductivity, water absorbency and dye receptivity while retaining the essential structural shape. The method comprises heating the polymer in the presence of an aqueous treating solution containing an ethylenically unsaturated monomer which does not readily polymerize under the conditions of treatment and a catalyst which is a source of hydrogen ions or protons. The treatment is carried out at a temperature and for a sufficient time so as to effect essentially single molecule addition of the monomer pendent to the polymer chain with substantially no graft polymerization of the monomer to the polymer. A particularly preferred embodiment of the method is the treatment of nylon 6,6 knitted fabric with an aqueous solution of acrylamide and hydrochloric acid for about one hour at 95.degree. C. to 100.degree. C.

    Abstract translation: 提供了一种用于处理和改性固体,高分子量路易斯碱聚合物,特别是成形结构如纤维,长丝或针织物的方法,以形成具有改善的导电性,吸水性和染料接收性同时保持基本结构形状的支链聚合物。 该方法包括在含有处理条件下不容易聚合的烯键式不饱和单体的含水处理溶液和作为氢离子或质子源的催化剂存在下加热聚合物。 该处理在一个温度和足够的时间进行,以基本上单独地向聚合物链添加单体,基本上没有单体接枝聚合到聚合物上。 该方法的一个特别优选的实施方案是用丙烯酰胺和盐酸水溶液在95℃至100℃下处理尼龙6,6针织物约1小时。

    Process for aftertreating dyed cellulosic material
    2.
    发明授权
    Process for aftertreating dyed cellulosic material 失效
    后处理染色纤维素材料的方法

    公开(公告)号:US4721512A

    公开(公告)日:1988-01-26

    申请号:US925058

    申请日:1986-10-30

    CPC classification number: D06P5/08 D06P5/06

    Abstract: A process for aftertreating cellulosic fibre material using an aqueous liquor which comprises(A) a diquaternary ammonium salt of formula ##STR1## wherein Q is a divalent aliphatic hydrocarbon radical of 2 to 12 carbon atoms which may be interrupted in the chain by oxygen atoms and is unsubstituted or substituted by hydroxy groups,R.sub.1 and R.sub.2 are each independently of the other an aliphatic radical of 6 to 24 carbon atoms,R.sub.3 to R.sub.6 are each independently of the other lower alkyl, hydroxy-lower alkyl or lower alkoxy-lower alkyl,X.sub.1 and X.sub.2 are each oxygen or --NH--,Z.sub.1 and Z.sub.2 are each independently of the other C.sub.2 -C.sub.6 alkylene, andY.crclbar. is an anion of a strong inorganic or organic acid, and(B) a polybasic nitrogen-containing polycondensate.

    Abstract translation: 一种使用含水液体后处理纤维素纤维材料的方法,该方法包括:(A)式(1)的二季铵盐,其中Q是2至12个碳原子的二价脂族烃基,其可以在链中被中断, 氧原子,未取代或被羟基取代,R 1和R 2各自独立地为6至24个碳原子的脂族基团,R 3至R 6各自独立地为低级烷基,羟基 - 低级烷基或低级烷氧基 - 低级烷基,X 1和X 2各自为氧或-NH-,Z 1和Z 2各自独立地为C 2 -C 6亚烷基,Y( - )为强无机或有机酸的阴离子,(B)多元氮 含缩聚物。

    Process for forming cushion articles
    3.
    发明授权
    Process for forming cushion articles 失效
    冲压件制成工艺

    公开(公告)号:US4559094A

    公开(公告)日:1985-12-17

    申请号:US655917

    申请日:1984-10-02

    Abstract: A process for forming cloth-covered cushion articles. A mold is provided having the shape of the desired cushion article. In one form, a cloth covering is drawn into the mold. Foamable material is poured into the mold and cured to form the cushion article. The covered, cured article is removed from the mold and heated to at least the heat-fixable fiber set temperature of the cloth, as the cured foam acts as a male mold to hold the cloth in contour during heat setting. In another form, the foam is poured directly into the mold and cured. The cloth covering then is placed over the cured cushion and set.

    Abstract translation: 一种形成布覆盖的坐垫制品的方法。 提供具有所需缓冲物品形状的模具。 在一种形式中,将布覆盖物拉入模具中。 将可发泡材料倒入模具中并固化以形成衬垫制品。 将被覆盖的固化物从模具中取出并加热至至少布的热固定纤维集合温度,因为固化的泡沫体作为阳模而在热定型期间将布保持在轮廓中。 在另一种形式中,将泡沫直接倒入模具中并固化。 然后将覆盖物覆盖在固化垫上并固化。

    Diester composition and textile processing compositions therefrom
    4.
    发明授权
    Diester composition and textile processing compositions therefrom 失效
    二酯组合物和纺织品加工组合物

    公开(公告)号:US4426297A

    公开(公告)日:1984-01-17

    申请号:US376748

    申请日:1982-05-10

    Inventor: Robert B. Wilson

    CPC classification number: D06M13/192 Y10T428/2969

    Abstract: A cycloaliphatic diester of the formula ##STR1## wherein R is straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 --, HO(C.sub.3 H.sub.6 O).sub.n C.sub.6 H.sub.3 --, HO(CH.sub.2 CH.sub.2 O).sub.p (C.sub.3 H.sub.6 O).sub.q C.sub.3 H.sub.6 --, or HO(C.sub.3 H.sub.6 O).sub.p (C.sub.2 H.sub.4 O).sub.q C.sub.2 H.sub.4 -- or phosphated polyoxyalkylene, wherein n is 2-22 and the sum of p+q is n, in combination with a high boiling aromatic ester, is useful in fiber treating and textile processing compositions.

    Abstract translation: 其中R是4-20个碳原子的直链或支链烷基,式HO(CH2CH2O)nCH2CH2-,HO(C3H6O)nC6H3-,HO(CH2CH2O)p(C3H6O)的聚氧化烯的式脂肪酸二酯, qC3H6-或HO(C3H6O)p(C2H4O)qC2H4-或磷酸化聚氧化烯,其中n为2-22,p + q的和为高沸点芳香酯,可用于纤维处理和纺织品 处理组合物。

    Diester composition and textile processing compositions therefrom
    5.
    发明授权
    Diester composition and textile processing compositions therefrom 失效
    二酯组合物和纺织品加工组合物

    公开(公告)号:US4394126A

    公开(公告)日:1983-07-19

    申请号:US305028

    申请日:1981-09-24

    Inventor: Robert B. Wilson

    Abstract: A cycloaliphatic diester of the formula ##STR1## wherein R is substituted or unsubstituted straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 --, HO(C.sub.3 H.sub.6 O).sub.n C.sub.3 H.sub.6 --, HO(CH.sub.2 CH.sub.2 O).sub.p (C.sub.3 H.sub.6 O).sub.q C.sub.3 H.sub.6 --, or HO(C.sub.3 H.sub.6 O).sub.p (C.sub.2 H.sub.4 O).sub.q C.sub.2 H.sub.4 -- or phosphated polyoxyalkylene, wherein n is 2-22 and the sum of p+q is n, in combination with a high boiling aromatic ester, is useful in fiber treating and textile processing compositions. Corresponding cycloaliphatic diesters wherein R is Ar'COO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 --, Ar'COO(C.sub.3 H.sub.6 O).sub.n C.sub.3 H.sub.6 --, Ar'COO(C.sub.2 H.sub.4 O).sub.p (C.sub.3 H.sub.6 O).sub.q C.sub.3 H.sub.6 --, or Ar'COO(C.sub.3 H.sub.6 O).sub.p --(C.sub.2 H.sub.4 O).sub.q C.sub.2 H.sub.4 -- and Ar' is substituted or unsubstituted monocyclic aryl can be used as the sole additive.

    Abstract translation: 其中R是取代或未取代的4-20个碳原子的直链或支链烷基,式HO(CH2CH2O)nCH2CH2-,HO(C3H6O)nC3H6-,HO(CH2CH2O)p的聚氧化烯 (C 3 H 6 O)qC 3 H 6 - 或HO(C 3 H 6 O)p(C 2 H 4 O)qC 2 H 4 - 或磷酸化聚氧化烯,其中n为2-22,p + q的和为高沸点芳族酯,可用于纤维 处理和纺织加工组合物。 对应的脂环族二酯,其中R是Ar'COO(CH 2 CH 2 O)n CH 2 CH 2 - ,Ar'COO(C 3 H 6 O)n C 3 H 6 - ,Ar'COO(C 2 H 4 O)p(C 3 H 6 O)qC 3 H 6 - 或Ar'COO(C 3 H 6 O)p-(C 2 H 4 O)qC 2 H 4 - 和Ar'是取代或未取代的单环芳基可以用作唯一的添加剂。

    Process for manufacturing flame-retardant yarn
    6.
    发明授权
    Process for manufacturing flame-retardant yarn 失效
    制造阻燃纱线的工艺

    公开(公告)号:US4244692A

    公开(公告)日:1981-01-13

    申请号:US927616

    申请日:1978-07-24

    CPC classification number: D06M11/60 D06M13/285

    Abstract: A system for ammoniating and curing flame-retardant impregnated single textile yarns by steps including impregnating the yarn with THPOH, drying the impregnated yarn, and ammoniating the THPOH-impregnated yarn by passing a single end of the yarn through a small tube leading into an ammoniation chamber wherein there is located a spool and means for rotating said spool for winding the ammoniated yarn onto the spool, the small tube being reciprocatable to traverse the length of the spool for uniformly winding the yarn on the spool.

    Abstract translation: 一种通过以下步骤对阻燃浸渍的单一纺织纱线进行氨化和固化的系统,其中包括用THPOH浸渍纱线,干燥浸渍纱线,并通过使纱线的单端通过导管进入氨化的小管来使THPOH浸渍的纱线氨化 其中设置有卷轴和用于使所述卷轴旋转的装置,用于将氨化纱线卷绕到卷轴上,小管可往复运动以穿过卷轴的长度,以将纱线均匀地卷绕在卷轴上。

    Process for manufacture of amidophosphates
    7.
    发明授权
    Process for manufacture of amidophosphates 失效
    酰胺磷酸盐的制备方法

    公开(公告)号:US4094929A

    公开(公告)日:1978-06-13

    申请号:US684988

    申请日:1976-05-10

    CPC classification number: D06M13/453 Y10S428/921

    Abstract: Reaction products containing at least two amidophosphate radicals are disclosed. They have been produced from(1) an amidophosphate of the formula ##STR1## wherein R.sub.1 is lower alkyl or both R.sub.1 's together are lower alkylene,(2) formaldehyde,(3) optionally an aliphatic diol with 2 to 6 carbon atoms,(4) optionally a lower alkanol.If a diol according to (3) has been used, R.sub.1 in the amidophosphate according to (1) can also be lower alkenyl or halogenoalkyl.The disclosed reaction products are suitable for flameproofing organic fibre materials, especially cellulosic textiles.

    Abstract translation: 公开了含有至少两个酰氨基磷酸酯基团的反应产物。 它们是由(1)式(1)的氨基磷酸酯制得的,其中R 1是低级烷基,或者两个R 1一起是低级亚烷基,(2)甲醛,(3)选择性地具有2至6碳原子的脂族二醇,(4 )选择一个较低的碱性醇。

    Textile finishing process
    8.
    发明授权
    Textile finishing process 失效
    纺织整理工艺

    公开(公告)号:US4052158A

    公开(公告)日:1977-10-04

    申请号:US722854

    申请日:1976-09-10

    Applicant: Edward D. Weil

    Inventor: Edward D. Weil

    Abstract: A process for producinga wash-durable finish on a textile is provided which comprises applying to the textile an effective amount of:A. at least one free-radical polymerizable monomer having a functional group capable of undergoing an acid catalyzed condensation reaction withB. at least one co-reactant having a reactive methylol, hydroxy, alkoxy or amino group capable of undergoing acid-catalyzed condensation with a reactive group on said free radical polymerizable monomer;C. at least one free radical generating catalyst and at least one acid catalyst, or at least one catalyst having both free radical generating and acidic characteristics, andD. subjecting said textile to curing conditions to conjointly effect free radical polymerization and acid-catalyzed condensation reactions.

    Process for binding pigments to textiles
    10.
    发明授权
    Process for binding pigments to textiles 失效
    将染料与纺织品混合的方法

    公开(公告)号:US3661632A

    公开(公告)日:1972-05-09

    申请号:US3661632D

    申请日:1968-06-17

    CPC classification number: D06M15/21 Y10T442/2779

    Abstract: WHEREIN R is a lower alkyl radical having from 1 to about 3 carbon atoms, hydroxymethyl radical or the radical -CH2-OOC-R1 and R1 is an alkyl radical having from 1 to about 25 carbon atoms, the weight ratio of acrylic monomer to oxazoline in said copolymer being in the range of from about 75:25 to about 95:5, and drying the textile.

    A process for binding pigment to textiles, for example, cotton fabrics, by applying to the textile a liquid application medium having dispersed therein a pigment and a copolymer of an acrylic monomer of the formula WHEREIN R is hydrogen or methyl and R1 is hydrogen or an alkyl radical having from 1 up to about 6 carbon atoms and an oxazoline of the formula

    Abstract translation: 通过向织物施加其中分散有颜料的液体应用介质和式WHEREIN R是丙烯酸单体的氢或甲基和R 1的共聚物,将颜料结合到纺织品,例如棉织物上的方法是氢或 具有1至约6个碳原子的烷基和式WHEREIN的恶唑啉是具有1至约3个碳原子的低级烷基,羟甲基或基团-CH 2 -OOC-R 1和R 1是烷基 具有1至约25个碳原子,所述共聚物中丙烯酸单体与恶唑啉的重量比在约75:25至约95:5的范围内,并干燥纺织品。

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