公开(公告)号：US11732191B2

公开(公告)日：2023-08-22

申请号：US17486096

申请日：2021-09-27

申请人： FUJIFILM Corporation

发明人： Yuki Fukushima ,  Hiroshi Inada ,  Toshikazu Sumi ,  Shunya Katoh ,  Mitsuyoshi Ichihashi

IPC分类号： G02F1/1333 ,  C09K19/30 ,  C09K19/34 ,  G02B5/30 ,  C09K19/04

CPC分类号： C09K19/3068 ,  C09K19/3497 ,  G02B5/3016 ,  C09K2019/0448 ,  C09K2019/3075 ,  C09K2219/03

摘要： Provided is a compound which is capable of reducing a tilt angle of a liquid crystal molecule, and a polymerizable composition, a cured product, an optical film, a polarizing plate, and an image display device, each using the compound. The compound is represented, for example, by Formula (I), P-Sp-Z-G1-(X1-Cy1)n-(X2-A1)m-X3-A2.

公开(公告)号：US11453230B2

公开(公告)日：2022-09-27

申请号：US17033670

申请日：2020-09-25

申请人： FUJIFILM Corporation

发明人： Toshiyuki Makuta ,  Shigeaki Nimura ,  Hiroshi Inada ,  Rie Takasago ,  Tomohiro Mizuno

IPC分类号： B41M5/00 ,  B41J2/01 ,  C09D11/328 ,  C09D11/38 ,  B41J2/21

摘要： Provided is an image forming method including a step of imagewisely applying, onto a base material by an inkjet method, at least two inks containing a polymerizable liquid crystal compound, a chiral compound, and a polymerization initiator and having reflection wavelengths different from each other, such that the total application amount of the inks provides an image area ratio of 50% or more in an image forming region.

公开(公告)号：US10883048B2

公开(公告)日：2021-01-05

申请号：US15903314

申请日：2018-02-23

申请人： FUJIFILM Corporation

发明人： Hiroshi Inada ,  Shunya Katoh ,  Akihiro Anzai ,  Yuki Saiki

IPC分类号： C09K19/38 ,  C09K19/54 ,  C09K19/56 ,  C09K19/04 ,  C08F220/10 ,  C08F290/06 ,  C08G65/26 ,  C08L75/08 ,  C08L75/14 ,  C09K19/20 ,  C09K19/30

摘要： A polymerizable composition includes a polymerizable liquid crystal compound of Formula (I) and a urethane (meth)acrylate monomer including a urethane bond and three or more (meth)acryloyl groups: Q1-Sp1A-Lm-1A-Sp2-Q2  (I) In Formula (I), A represents a cyclic divalent group (at least one is a divalent saturated hydrocarbon ring group), L preferably represents —C(═O)O— or —OC(═O)—, m represents 3 to 12, Sp1 and Sp2 preferably are alkylene, and any one of Q1 and Q2 represents a polymerizable group. A film including a layer obtained by curing the polymerizable composition; and a film adjacently including a layer obtained by curing the polymerizable composition including a polymerizable liquid crystal compound represented by Formula (I) and a layer obtained by curing a composition including a urethane (meth)acrylate monomer and a manufacturing method thereof, are also disclosed. The polymerizable composition includes a polymerizable liquid crystal compound having low birefringence and provides a highly durable optical film.

公开(公告)号：US10858589B2

公开(公告)日：2020-12-08

申请号：US15898295

申请日：2018-02-16

申请人： FUJIFILM Corporation

发明人： Daisuke Hayashi ,  Hiroshi Inada ,  Shunya Katoh

IPC分类号： C09K19/38 ,  C07D241/04 ,  C07D295/205 ,  C09K19/34 ,  G02B5/30 ,  C08F222/10 ,  C08F22/20 ,  C09K19/58 ,  C09K19/04 ,  G02B1/08

摘要： A polymerizable liquid crystal compound represented by Formula (I): Q1—Sp1—[A—L]—A—Sp2—Q2  (I) A represents a divalent nitrogen-containing saturated cyclic group (that may have a substituent) formed by removing two hydrogen atoms from piperidine or piperazine, a phenylene group that may have a substituent, or a trans-1,4-cyclohexylene group that may have a substituent; L represents a linking group such as —C(═O)O— or —OC(═O)—; m represents 3 to 12; Sp1 and Sp2 represent an alkylene group having 1 to 20 carbon atoms; any one of Q1 and Q2 represents a polymerizable group; and Formula (I) has a nitrogen-containing saturated cyclic group and a phenylene group that are directly bonded to each other via —C(═O)O—. By using a polymerizable composition including the polymerizable liquid crystal compound, a film such as a retardation film can have low birefringence or a reflection film can have high selectivity in a reflection wavelength range.

公开(公告)号：US10338290B2

公开(公告)日：2019-07-02

申请号：US15253179

申请日：2016-08-31

申请人： FUJIFILM Corporation

发明人： Yasukazu Kuwayama ,  Hiroshi Inada ,  Aiko Yoshida ,  Yoshitaka Maeda ,  Yusuke Ino ,  Shuuji Kanayama ,  Nobutaka Fukagawa

IPC分类号： G02B5/30 ,  C09D7/63 ,  G02B1/14 ,  G02F1/1335 ,  C08K5/12 ,  C08K5/20 ,  C08K5/205 ,  C08K5/315 ,  C08K5/3417 ,  C08K5/3462 ,  C09D101/10 ,  C09D5/00 ,  C08L1/10 ,  C08L1/12

摘要： A cellulose ester film contains a compound having a structural unit denoted by —NR—(C═O)— in which R represents a hydrogen atom or a substituent, a surface having knoop hardness of greater than or equal to 210 N/mm2 is provided, and loss tangent tan δ at 25° C. is greater than or equal to 0.03.

公开(公告)号：US08922889B2

公开(公告)日：2014-12-30

申请号：US13675615

申请日：2012-11-13

申请人： Fujifilm Corporation

发明人： Nobutaka Fukagawa ,  Masaki Noro ,  Shuuji Kanayama ,  Hiroshi Inada

IPC分类号： G02B5/30 ,  C09K19/02 ,  B32B23/04 ,  C08L1/10

CPC分类号： C09K19/02 ,  B32B23/04 ,  C08L1/10 ,  G02B5/30 ,  G02B5/3025 ,  Y10T428/105 ,  Y10T428/31986

摘要： There is provided a cellulose acylate film, containing a hindered amin-based compound, wherein the hindered amine-based compound is contained in an amount of 0.001% by mass to 5% by mass based on cellulose acylate, a minimum value of Knoop hardness is 170 N/mm2 to 220 N/mm2, and the Knoop hardness is measured several times by a Knoop indenter, the Knoop indenter is rotated by a given angle in each measurement, and a rotation axis of the Knoop indenter is orthogonal to an upper surface of the cellulose acylate film.

摘要翻译： 提供了含有受阻胺基化合物的纤维素酰化物膜，其中受阻胺类化合物的含量相对于纤维素酰化物为0.001质量％至5质量％，诺普硬度的最小值为 170N / mm 2至220N / mm 2，并且通过Knoop压头测量Knoop硬度，在每次测量中将Knoop压头旋转给定角度，并且Knoop压头的旋转轴线正交于上表面 的纤维素酰化物膜。

公开(公告)号：US11287555B2

公开(公告)日：2022-03-29

申请号：US16709860

申请日：2019-12-10

申请人： FUJIFILM Corporation

发明人： Keisuke Kodama ,  Shunya Katoh ,  Hiroshi Inada

IPC分类号： C09K19/56 ,  G02B5/08 ,  G02B5/02 ,  G02B5/26

摘要： An object of the present invention is to provide a method for producing a reflective layer having an excellent diffuse reflectivity and a wide reflection wavelength range. Another object of the present invention is to provide a reflective layer having an excellent diffuse reflectivity and a wide reflection wavelength range.
The method for producing a reflective layer of the present invention includes: a step 1 of applying a composition selected from the group consisting of the following composition X and the following composition Y onto a substrate to form a composition layer; a step 2 of heating the composition layer to align a liquid crystal compound in the composition layer into a cholesteric liquid crystalline phase state; a step 3 of cooling or heating the composition layer in a cholesteric liquid crystalline phase state to reduce a helical pitch; and a step 4 of irradiating at least a partial region of the composition layer with light, between the step 1 and the step 2, between the step 2 and the step 3, or after the step 3, to photosensitize a chiral agent A or a chiral agent C in the composition layer. Composition X: a composition including a liquid crystal compound, a chiral agent A whose helical twisting power is changed upon light irradiation, and a chiral agent B whose helical twisting power is increased upon cooling or heating. Composition Y: a composition including a liquid crystal compound and a chiral agent C whose helical twisting power is changed upon light irradiation and whose helical twisting power is increased upon cooling or heating.

公开(公告)号：US10688701B2

公开(公告)日：2020-06-23

申请号：US16107045

申请日：2018-08-21

申请人： FUJIFILM Corporation

发明人： Yuki Saiki ,  Akihiro Anzai ,  Shunya Katoh ,  Hiroshi Inada ,  Kazuhiro Oki

IPC分类号： B32B27/18 ,  B32B27/26 ,  B32B27/08 ,  B32B27/30 ,  C08F20/00 ,  G02B5/00 ,  G02B5/30 ,  B29C45/16 ,  G02F1/13363 ,  C09D4/00 ,  C08F222/10 ,  B29K69/00 ,  B29K105/00 ,  B29K667/00 ,  B29L11/00

摘要： A transfer sheet includes a cured liquid crystal composition layer, a block layer including a (meth)acrylic polymer, and a thermoplastic welded layer in this order, the thermoplastic welded layer and the block layer are in direct contact with each other, and the thermoplastic welded layer includes a thermoplastic resin and an ultraviolet curable resin.

公开(公告)号：US09718933B2

公开(公告)日：2017-08-01

申请号：US14988171

申请日：2016-01-05

申请人： FUJIFILM Corporation

发明人： Masaki Noro ,  Hiroshi Inada ,  Yoshinori Kanazawa ,  Aiko Yoshida ,  Yasukazu Kuwayama

IPC分类号： G02B5/30 ,  C08J5/18 ,  C08K5/3462 ,  C08L1/10 ,  C08L1/12 ,  G02F1/1335 ,  G02B1/14 ,  G02B1/04

CPC分类号： C08J5/18 ,  C08J2301/10 ,  C08K5/3462 ,  C08L1/10 ,  C08L1/12 ,  G02B1/04 ,  G02B1/14 ,  G02B5/3033 ,  G02B5/305 ,  G02F1/133528 ,  Y10T428/105

摘要： The invention is an optical film at least containing cellulose acylate and a compound having a structure denoted by General Formula (I) described below, and a polarizing plate and a liquid crystal display device employing the optical film. R1 and R3 represent a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, or an aryl group, and R5a and R5b represent an alkyl group, an alkenyl group, a cycloalkyl group, a cycloalkenyl group, an aryl group, or a heterocyclic group. R1, R3, R5a, and R5b may have a substituent group.

公开(公告)号：US12091603B2

公开(公告)日：2024-09-17

申请号：US17697519

申请日：2022-03-17

申请人： FUJIFILM Corporation

发明人： Hiroshi Inada ,  Shunya Katoh ,  Yuki Nakamura ,  Yuko Suzuki

IPC分类号： C09K19/20 ,  C09K19/30 ,  C09K19/34 ,  G02B5/30

CPC分类号： C09K19/2007 ,  C09K19/3068 ,  C09K19/3405 ,  C09K19/3491 ,  C09K19/3497 ,  G02B5/3016 ,  G02B5/3025 ,  C09K2019/2035 ,  C09K2019/2078

摘要： A liquid crystal composition containing a liquid crystal compound and a non-liquid crystal compound, in which both of the liquid crystal compound and the non-liquid crystal compound are compounds having any of aromatic rings selected from the group consisting of groups represented by predetermined formulae, and a ratio of a molecular weight of the non-liquid crystal compound to a molecular weight of the liquid crystal compound is 1 or less.