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公开(公告)号：US11724250B2
公开(公告)日：2023-08-15
申请号：US16575800
申请日：2019-09-19
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Lubin Luo , Edward J. Blok , Alan A. Galuska , Anupriya Jain , Alexander V. Zabula , Yen-Hao Lin
CPC classification number: B01J31/2213 , C08G61/08 , B01J2231/14 , B01J2231/543 , B01J2531/50 , B01J2531/60 , C08G2261/418
Abstract: A supported catalyst system is based on a transition metal carbene including the moiety M1=CR*)2, wherein M1 is the transition metal and R* is hydrogen or a C1-C8 hydrocarbyl. The catalyst system can be supported on a metal oxide support such as silica or the catalyst can be self-supporting. Methods of making the catalyst system can involve precursors based on and/or reacted with aluminum alkyls, halides, and/or alkoxides. Methods of polymerizing cyclic olefins with the catalyst system can obtain polyalkenamers, cyclic olefin polymers, cyclic olefin copolymers, and other metathesis reaction products. The supported catalyst and/or monomer can be recovered and recycled to the polymerization reactor.
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公开(公告)号：US11142021B2
公开(公告)日：2021-10-12
申请号：US16773478
申请日：2020-01-27
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Edward J. Blok , Yong Yang , Jingwen Zhang , Ian C. Stewart , Shuji Luo , Andy H. Tsou
Abstract: A functionalized polyolefin and a tire tread composition comprising the functionalized polyolefin is described. The functionalized polyolefin comprises a vinyl/vinylidene-terminated polyolefin in which the vinyl/vinylidene terminus is functionalized with an alkoxysilane or an alkylsilane and optionally having ether, hydroxyl and/or amine functionality. The invention is also directed to the synthesis of vinyl/vinylidene-terminated polyolefins, functionalization at the vinyl/vinylidene terminus with an alkoxysilane or an alkylsilane and optionally having ether, hydroxyl and/or amine functionality.
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公开(公告)号：US20210238395A1
公开(公告)日：2021-08-05
申请号：US17059666
申请日：2020-11-30
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Edward J. Blok , Anthony J. Dias , Sunny Jacob , Ian C. Stewart , Yong Yang , Jingwen Zhang
Abstract: A tire tread composition is disclosed. The tire tread composition includes components, by weight of the composition, within the range from: 5 to 75 wt % of a diene elastomer; 0 to 40 wt % of processing oil; 20 to 80 wt % of filler; a curative agent; and 5 to 30 wt % of a propylene-ethylene-diene terpolymer containing from 2 wt % to 40 wt % of ethylene and/or C4-C20 α-olefins derived units, from 0.5 to 10 wt % of diene derived units, and having a heat of fusion, as determined by DSC, of from 0 J/g to 80 J/g.
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公开(公告)号：US20210017304A1
公开(公告)日：2021-01-21
申请号：US17040322
申请日：2019-03-29
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Paul Tu Quang Nguyen , David J. Freas , Tu N. Pham , Yuan-Ju Chen , Edward J. Blok , Anthony J. Dias
Abstract: Methods of post-polymerization modification of a polymer are provided herein. The present methods comprise the step of reacting a polymer with at least one nucleophile in a nucleophilic substitution reaction performed without a solvent to produce a functionalized polymer. The nucleophile can be selected from the group consisting of thioacetate, phenoxide, alkoxide, carboxylate, thiolate, thiocarboxylate, dithiocarboxylate, thiourea, thiocarbamate, dithiocarbamate, xanthate, thiocyanate. Nucleophilic substitution reaction can be performed in the presence of a phase transfer catalyst. Nucleophilic substitution reaction can also be performed via a two-step in-situ reactive mixing process with the initial formation of the polymer-amine ionomer (polymer-NR3+Br) which catalyzes the subsequent nucleophilic substitution with a second nucleophile to form a bi-functional polymer.
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公开(公告)号：US10882981B2
公开(公告)日：2021-01-05
申请号：US15507400
申请日：2015-08-31
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Edward J. Blok , Anthony J. Dias , Sunny Jacob , Ian C. Stewart , Yong Yang , Jingwen Zhang
Abstract: A tire tread composition is disclosed. The tire tread composition includes components, by weight of the composition, within the range from: 5 to 75 wt % of a diene elastomer; 0 to 40 wt % of processing oil; 20 to 80 wt % of filler; a curative agent; and 5 to 30 wt % of a propylene-ethylene-diene terpolymer containing from 2 wt % to 40 wt % of ethylene and/or C4-C20 α-olefins derived units, from 0.5 to 10 wt % of diene derived units, and having a heat of fusion, as determined by DSC, of from 0 J/g to 80 J/g.
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Patent Agency Ranking
公开(公告)号：US20170058057A1
公开(公告)日：2017-03-02
申请号：US15118639
申请日：2015-03-06
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor： Edward J. Blok , Ian C. Stewart , Anthony J. Dias , Yong Yang , Jingwen Zhang
CPC classification number: C08F8/42 , B60C1/0016 , C08C19/25 , C08F8/00 , C08K3/00 , C08L9/00 , C08L21/00 , C08L57/06 , C08L101/02
Abstract: This invention relates to a functionalized resin composition having the formula P-X-S-W where S is a spacer selected from at least one of C2-C40 straight chain and branched alkyl, C6-C40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, X is one or more reactive groups, and W is a silane.
Abstract translation: 本发明涉及具有式PXSW的官能化树脂组合物，其中S是选自C 2 -C 40直链和支链烷基，C 6 -C 40芳族化合物，丁二烯，异戊二烯及其组合中的至少一种的间隔基，P是聚合物骨架 选自二环戊二烯（DCPD）基聚合物，环戊二烯（CPD）基聚合物，DCPD-苯乙烯共聚物，C5均聚物和共聚物树脂中的至少一种，C5-苯乙烯共聚物树脂，萜烯均聚物或共聚物树脂，蒎烯均聚物或共聚物树脂 C9均聚物和共聚物树脂，C5 / C9共聚物树脂，α-甲基苯乙烯均聚物或共聚物树脂及其组合，X是一个或多个反应性基团，W是硅烷。
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公开(公告)号：US20170051085A1
公开(公告)日：2017-02-23
申请号：US15118701
申请日：2015-03-06
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Edward J. Blok , Ian C. Stewart , David T. Harris
CPC classification number: C08F8/42 , B60C1/0016 , C08F2810/30 , C08F2810/40 , C08K3/36 , C08K5/548 , C08L9/00 , C08L9/06 , C08L45/00 , C08L2205/025 , C08F132/08
Abstract: This invention relates to a functionalized resin composition having the formula P—S—X where S is a spacer selected from at least one of C2-C40 straight chain and branched alkyl, C6-C40 aromatics, butadiene, isoprene, and combinations thereof, P is a polymer backbone selected from at least one of dicyclopentadiene (DCPD)-based polymers, cyclopentadiene (CPD)-based polymers, DCPD-styrene copolymers, C5 homopolymers and copolymer resins, C5-styrene copolymer resins, terpene homopolymer or copolymer resins, pinene homopolymer or copolymer resins, C9 homopolymers and copolymer resins, C5/C9 copolymer resins, alpha-methylstyrene homopolymer or copolymer resins, and combinations thereof, and X is a silane.
Abstract translation: 本发明涉及具有式P-S-X的官能化树脂组合物，其中S是选自C 2 -C 40直链和支链烷基，C 6 -C 40芳烃，丁二烯，异戊二烯及其组合中的至少一种的间隔基，P 是选自二环戊二烯（DCPD）基聚合物，环戊二烯（CPD）基聚合物，DCPD-苯乙烯共聚物，C5均聚物和共聚物树脂中的至少一种，C5-苯乙烯共聚物树脂，萜烯均聚物或共聚物树脂，蒎烯 均聚物或共聚物树脂，C 9均聚物和共聚物树脂，C5 / C9共聚物树脂，α-甲基苯乙烯均聚物或共聚物树脂及其组合，X是硅烷。
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公开(公告)号：US20160152758A1
公开(公告)日：2016-06-02
申请号：US14902927
申请日：2014-07-15
Applicant: EXXONMOBIL CHEMICAL PATENTS INC.
Inventor： Edward J. Blok , Andy H. Tsou , Shuji Luo , Elizabeth L. Walker , Jingwen Zhang , Yong Yang
IPC: C08F299/00 , C08L9/06
CPC classification number: C08F299/00 , B60C1/0016 , C08C19/25 , C08C19/28 , C08C19/40 , C08F297/00 , C08F299/02 , C08G81/021 , C08L9/06 , C08L53/00
Abstract: A polyolefin-polybutadiene block-copolymer and a tire tread composition comprising the polyolefin-polybutadiene block-copolymer, the composition comprising, by weight of the composition, within the range from 15 to 60 wt % of a styrenic copolymer, processing oil, filler, a curative agent, and from 4 to 20 wt % of a polyolefin-polybutadiene block-copolymer, wherein the polyolefin-polybutadiene block-copolymer is a block copolymer having the general formula PO-XL-fPB; where “PO” is a polyolefin block having a weight average molecular weight within the range from 1000 to 150,000 g/mole, the “fPB” is a functionalized polar polybutadiene block having a weight average molecular weight within the range from 500 to 30,000 g/mole, and “XL” is a cross-linking moiety that covalently links the PO and fPB blocks; and wherein the maximum Energy Loss (Tangent Delta) of the immiscible polyolefin domain is a temperature within the range from −30° C. to 10° C.
Abstract translation: 包含聚烯烃 - 聚丁二烯嵌段共聚物的聚烯烃 - 聚丁二烯嵌段共聚物和轮胎胎面组合物，所述组合物按所述组合物的重量计在苯乙烯共聚物的15-60wt％范围内，加工油，填料， 固化剂和4〜20重量％的聚烯烃 - 聚丁二烯嵌段共聚物，其中聚烯烃 - 聚丁二烯嵌段共聚物是具有通式PO-XL-fPB的嵌段共聚物; 其中“PO”是重均分子量为1000〜150,000g / mol的聚烯烃嵌段，“fPB”为重均分子量在500〜30,000g / mol之间的官能化极性聚丁二烯嵌段， 摩尔，“XL”是共价连接PO和fPB嵌段的交联部分; 并且其中不混溶聚烯烃领域的最大能量损失（切线三角洲）是在-30℃至10℃的范围内的温度。
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公开(公告)号：US12146062B2
公开(公告)日：2024-11-19
申请号：US17043303
申请日：2019-04-09
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Edward J. Blok , Anthony J. Dias , Gabor Kiss
Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 70 to about 90 phr of polybutadiene having a cis-1,4 linkage content of at least 95%; about 5 to 20 phr of a processing oil; about 5 to about 20 of sunflower oil; about 50 to about 75 phr of a filler; a curative agent; an antioxidant; and about 5 to about 30 phr of a propylene-ethylene-diene terpolymer containing from about 0.2 wt % to about 20 wt % ethylidene norbornene and/or vinyl norbornene and about 10 wt % to about 30 wt % of ethylene and/or C4-C20 α-olefins derived units.
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10.发明授权公开(公告)号：US12006393B2
公开(公告)日：2024-06-11
申请号：US17040600
申请日：2019-03-29
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Paul Tu Quang Nguyen , Edward J. Blok , Ranjan Tripathy , Jason A. Mann , Anthony J. Dias
IPC: C08F8/34 , C08F8/04 , C08F210/10 , C08F212/08 , C08K3/04 , C08K3/06 , C08K3/36 , C08K5/00 , C08K5/31 , C08K5/378 , C08K5/40 , C08K5/435 , C08K5/47 , C08L45/00
CPC classification number: C08F8/34 , C08F8/04 , C08F210/10 , C08F212/08 , C08K3/04 , C08K3/06 , C08K3/36 , C08K5/0025 , C08K5/31 , C08K5/378 , C08K5/40 , C08K5/435 , C08K5/47 , C08L45/00 , C08K2201/019 , C08L2203/02 , C08L2203/30 , C08F210/10 , C08F212/21 , C08F210/10 , C08F212/30 , C08F210/10 , C08F212/21 , C08F212/12 , C08F210/10 , C08F212/30 , C08F212/12
Abstract: Provided herein are thioacetate isobutylene-based polymer compositions comprising thioalkylated functionalized polymer, and a sulfur donor and/or accelerator cure system. The thioalkylated functionalized polymer is produced via nucleophilic substitution reaction in solution. The present thioacetate functionalized isobutylene-based polymer compositions together with various accelerators and sulfur donors can form thermosets useful for pharmaceutical and tire applications without the use of zinc or a zinc oxide activator.
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