公开(公告)号：US20230029797A1

公开(公告)日：2023-02-02

申请号：US17783024

申请日：2020-12-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Paul T. Q. Nguyen ,  Anthony J. Dias ,  Jason A. Mann ,  Ranjan Tripathy

IPC: C08K3/04 ,  C08K3/36 ,  C08K5/548

Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 5 to about 30 phr of polybutadiene having a cis-1,4 linkage content of at least 95%; about 60 to 100 phr of a styrene/butadiene copolymer; an antioxidant; a curative agent; about 1 to about 20 phr carbon black; about 50 to 80 phr silica, a silane coupling agent and about 5 to about 30 phr of a polymer is selected from the group consisting of ethylene-propylene-diene terpolymer, butyl rubber, poly(isobutylene-co-para-methylstyrene) and poly(isobutylene-co-para-methylstyrene-co-isoprene) terpolymer. The polymer based on ethylene-propylene-diene terpolymer, butyl rubber, poly(isobutylene-co-para-methylstyrene) and poly(isobutylene-co-para-methylstyrene-co-isoprene) terpolymer may be functionalized.

公开(公告)号：US20230016289A1

公开(公告)日：2023-01-19

申请号：US17783041

申请日：2020-12-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Paul T. Q. Nguyen ,  Edward J. Blok ,  Anthony J. Dias ,  Ranjan Tripathy ,  Jason A. Mann

IPC: B60C1/00 ,  C08L7/00 ,  C08L9/06

Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 20 to about 40 phr of a polybutadiene having a cis-1,4 linkage content of at least 95%; about 40 to about 70 phr styrene/ butadiene copolymer; about 5 to about 30 phr natural rubber or polyisoprene; a curative agent; an antioxidant; about 1 to about 20 phr carbon black; about 1 to about 30 phr plasticizing oil; about 40 to about 80 phr silica; about 1 to about 15 phr silane coupling agent and about 5 to about 30 phr of a polymer selected from the group consisting of an ethylene-propylene-diene terpolymer, butyl rubber, poly(isobutylene-co-para-methylstyrene) and poly(isobutylene-co-para-methylstyrene-co-isoprene) terpolymer.

公开(公告)号：US20220112364A1

公开(公告)日：2022-04-14

申请号：US17435929

申请日：2020-03-23

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Krishnan Anantha Narayana Iyer ,  Antonios K. Doufas ,  Anthony J. Dias

IPC: C08L23/12

Abstract: In an embodiment, a thermoplastic vulcanizate (TPV) composition includes a rubber, a thermoplastic polyolefin, and a polyhedral oligomeric silsesquioxane, wherein: a concentration of the rubber is from 10 wt % to 80 wt % based on a combined weight of the rubber and the thermoplastic polyolefin; a concentration of the thermoplastic polyolefin is from 20 wt % to 90 wt % based on the combined weight of the rubber and the thermoplastic polyolefin; and a concentration of the polyhedral oligomeric silsesquioxane is from 0.1 wt % to 20 wt % based on the total weight of the TPV composition. In another embodiment, a process for preparing a dynamically vulcanized thermoplastic vulcanizate composition includes melt processing under shear conditions at least one thermoplastic resin, at least one rubber, at least one curing agent, and at least one polyhedral oligomeric silsesquioxane; and forming a dynamically vulcanized thermoplastic vulcanizate composition. In another embodiment, a pipe is provided.

公开(公告)号：US20210340361A1

公开(公告)日：2021-11-04

申请号：US17278575

申请日：2019-09-10

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Krishnan Anantha Narayana Iyer ,  Antonios K. Doufas ,  Krassimir I. Doynov ,  Anthony J. Dias

IPC: C08L23/06 ,  B32B1/08 ,  B32B15/18 ,  B32B25/14 ,  B32B15/06 ,  F16L11/10

Abstract: Embodiments of the present disclosure generally relate to crosslinked TPE or TPV compositions, flexible pipes containing crosslinked TPE or TPV compositions, and methods for forming crosslinked elastomer polymer compositions and flexible pipes. In an embodiment, a flexible pipe includes a plurality of layers, where at least one layer includes a composition including: at least one polar elastomer, and a polymer having a crystallinity of about 20% or greater. In an embodiment, a pipe includes an inner sheath, an outer sheath, a first armor layer, and a second armor layer, where at least one of the inner sheath and the outer sheath comprises a crosslinked TPE or TPV composition that is the reaction product of an elastomer having a polarity of about 90° or less, a polymer having a crystallinity of about 20% or greater, and a crosslinking agent.

公开(公告)号：US20210017369A1

公开(公告)日：2021-01-21

申请号：US17043254

申请日：2019-04-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Anthony J. Dias ,  Paul T.Q. Nguyen ,  Erick E, Wurzinger ,  Andy H. Tsou

IPC: C08L23/16 ,  C08L23/32 ,  C08F136/06 ,  C08F136/08 ,  C08L9/06 ,  C08L7/00 ,  C08L57/02 ,  C08K3/04 ,  C08K3/36 ,  C08K3/06 ,  C08K5/18 ,  C08K5/548 ,  B60C1/00

Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 30 to about 50 phr of polybutadiene having a cis-1,4 linkage content of at least 95%; about 40 to about 60 phr of styrene/butadiene copolymer; about 0 to about 20 phr of natural rubber or polyisoprene; about 0 to about 30 phr of a processing oil; about 10 to about 30 phr of a hydrocarbon resin; about 50 to about 75 phr of a filler; a curative agent; an antioxidant; a silane coupling agent; and about 5 to about 30 phr of a propylene-ethylene-diene terpolymer containing from about 2 wt % to about 30 wt % of ethylene and/or C4-C20 α-olefins derived units.

公开(公告)号：US12146062B2

公开(公告)日：2024-11-19

申请号：US17043303

申请日：2019-04-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Anthony J. Dias ,  Gabor Kiss

IPC: C08L9/06 ,  B60C1/00 ,  C08L23/16 ,  C08L91/00 ,  C08K3/04 ,  C08K3/36

Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 70 to about 90 phr of polybutadiene having a cis-1,4 linkage content of at least 95%; about 5 to 20 phr of a processing oil; about 5 to about 20 of sunflower oil; about 50 to about 75 phr of a filler; a curative agent; an antioxidant; and about 5 to about 30 phr of a propylene-ethylene-diene terpolymer containing from about 0.2 wt % to about 20 wt % ethylidene norbornene and/or vinyl norbornene and about 10 wt % to about 30 wt % of ethylene and/or C4-C20 α-olefins derived units.

公开(公告)号：US12006393B2

公开(公告)日：2024-06-11

申请号：US17040600

申请日：2019-03-29

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Paul Tu Quang Nguyen ,  Edward J. Blok ,  Ranjan Tripathy ,  Jason A. Mann ,  Anthony J. Dias

IPC: C08F8/34 ,  C08F8/04 ,  C08F210/10 ,  C08F212/08 ,  C08K3/04 ,  C08K3/06 ,  C08K3/36 ,  C08K5/00 ,  C08K5/31 ,  C08K5/378 ,  C08K5/40 ,  C08K5/435 ,  C08K5/47 ,  C08L45/00

CPC classification number: C08F8/34 ,  C08F8/04 ,  C08F210/10 ,  C08F212/08 ,  C08K3/04 ,  C08K3/06 ,  C08K3/36 ,  C08K5/0025 ,  C08K5/31 ,  C08K5/378 ,  C08K5/40 ,  C08K5/435 ,  C08K5/47 ,  C08L45/00 ,  C08K2201/019 ,  C08L2203/02 ,  C08L2203/30 ,  C08F210/10 ,  C08F212/21 ,  C08F210/10 ,  C08F212/30 ,  C08F210/10 ,  C08F212/21 ,  C08F212/12 ,  C08F210/10 ,  C08F212/30 ,  C08F212/12

Abstract: Provided herein are thioacetate isobutylene-based polymer compositions comprising thioalkylated functionalized polymer, and a sulfur donor and/or accelerator cure system. The thioalkylated functionalized polymer is produced via nucleophilic substitution reaction in solution. The present thioacetate functionalized isobutylene-based polymer compositions together with various accelerators and sulfur donors can form thermosets useful for pharmaceutical and tire applications without the use of zinc or a zinc oxide activator.

公开(公告)号：US20230043808A1

公开(公告)日：2023-02-09

申请号：US17783036

申请日：2020-12-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Paul T.Q. Nguyen ,  Anthony J. Dias ,  Ranjan Tripathy ,  Jason A. Mann

IPC: B60C1/00 ,  C08L7/00 ,  C08L9/06

Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 5 to about 40 phr of styrene/butadiene copolymer; about 60 to about 100 phr of natural mbber or polyisoprene; a curative agent; an antioxidant; about 1 to about 20 phr carbon black; about 5 to about 40 phr plasticizing agent; about 40 to about 80 phr silica; about 1 to about 20 phr silane coupling agent and about 5 to about 30 phr of a polymer selected from the group consisting of ethyl-ene-propylene-diene terpolymer, butyl mbber, poly(isobutylene-co-para-methylstyrene) and poly(isobutylene-co-para-methylstyrene-co-isoprene) terpolymer. The polymer based on ethylene-propylene-diene terpolymer, butyl mbber, poly(isobutylene-co-para-methylstyrene) and poly(isobutylene-co-para-methylstyrene-co-isoprene) terpolymer may be functionalized.

公开(公告)号：US20230022627A1

公开(公告)日：2023-01-26

申请号：US17783020

申请日：2020-12-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Paul T. Q. Nguyen ,  Edward J. Blok ,  Anthony J. Dias ,  Jason A. Mann ,  Ranjan Tripathy

IPC: C08L9/06

Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 5 to about 30 phr of polybutadiene having a cis-1,4 linkage content of at least 95%; about 60 to 100 phr of a styrene/butadiene copolymer; an antioxidant; about 1 to about 20 phr carbon black; about 100-140 phr silica; a silane coupling agent and about 5 to about 40 phr of a polymer selected from the group consisting of ethylene-propylene-diene terpolymer, butyl rubber, poly(isobutylene-co-para-methylstyrene) and poly (isobutylene-co-para-methylstyrene-co-isoprene) terpolymer. The polymer based on ethylene-propylene-diene terpolymer, butyl rubber, poly(isobutylene-co-para-methylstyrene) and poly (isobutylene-co-para-methylstyrene-co-isoprene) terpolymer may be functionalized.

公开(公告)号：US20210230403A1

公开(公告)日：2021-07-29

申请号：US17056216

申请日：2019-05-23

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Anthony J. Dias ,  Jason A. Mann ,  Andy H. Tsou ,  Paul T. Q. Nguyen ,  Gabor Kiss ,  Abdul M. Jangda

IPC: C08L9/06 ,  C08L23/16 ,  B60C1/00 ,  B60C11/00

Abstract: Elastomeric compositions comprising propylene-ethylene-diene terpolymer based polyolefin additives useful in tire tread compositions. The elastomeric compositions comprise 100 phr (parts by weight per hundred parts of total elastomer) diene elastomers; about 0 to about 80 phr of processing oil; 0 to about 80 phr of a hydrocarbon resin; about 60 to about 140 phr of filler; a curative agent; and about 5 to about 30 phr of a silane functionalized propylene-ethylene-diene terpolymer. The silane functionalized propylene-ethylene-diene terpolymer comprises from about 2 wt. % to about 40 wt. % of ethylene and/or C4-C20 α-olefins derived units, from 0.5 to 10 wt % of diene derived units, and a silane coupling agent. The present elastomeric compositions are useful as tire tread compositions for improved tire performance.