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    HYBRID POLYOLS
    4.
    发明申请
    HYBRID POLYOLS 审中-公开
    混合聚合物

    公开(公告)号：US20160108166A1

    公开(公告)日：2016-04-21

    申请号：US14893214

    申请日：2014-05-08

    Applicant: ROHM AND HAAS COMPANY ,  DOW GLOBAL TECHNOLOGIES LLC

    Inventor： Joseph J. Zupancic ,  William H. Heath ,  Jorge Jimenez ,  Amira A. Marine ,  Pavel L. Shutov ,  David E. Vietti

    IPC: C08G18/48 ,  C08G18/72

    CPC classification number: C08G18/4879 ,  C08G18/10 ,  C08G18/4261 ,  C08G18/4866 ,  C08G18/4887 ,  C08G18/72 ,  C09J175/04 ,  C08G18/7657 ,  C08G18/73

    Abstract: Provided is a two-component composition comprising one or more polyisocyanate and one or more hybrid polyol comprising reaction residues of (i). one initiator polyol having N hydroxyl groups, wherein N is 2 or greater, and wherein the number-average molecular weight of said initiator polyol is 900 or lower, (ii). one or more anhydride, and (iii). two or more alkylene oxides having the structure wherein said R3 is hydrogen or an alkyl group, wherein the mole ratio of said reaction residues of anhydride to said reaction residues of initiator polyol is N:1 or less; and wherein the mole ratio of said reaction residues (iii) to said reaction residues of initiator polyol is 20:1 or less wherein at least one said reaction residue of an anhydride is attached directly to one of said reaction residues of a higher-alkylene oxide.

    Abstract translation: 提供了包含一种或多种多异氰酸酯和一种或多种包含（i）的反应残基的杂化多元醇的双组分组合物。 一种具有N个羟基的引发剂多元醇，其中N为2或更大，并且其中所述引发剂多元醇的数均分子量为900或更低，（ii）。 一种或多种酸酐，和（ⅲ）。 两个或多个具有其中所述R 3为氢或烷基的结构的环氧烷烃，其中酸酐与引发剂多元醇的所述反应残余物的摩尔比为N：1或更小; 并且其中所述反应残余物（iii）与所述引发剂多元醇的所述反应残基的摩尔比为20:1或更低，其中至少一个所述酸酐的所述反应残基直接连接在所述高级环氧烷的所述反应残基之一 。

    Modified Ethylene-Based Films to Promote Isocyanate Chemical Reactions in Polyurethane Laminting Adhesives
    5.
    发明申请
    Modified Ethylene-Based Films to Promote Isocyanate Chemical Reactions in Polyurethane Laminting Adhesives 审中-公开
    改性乙烯基膜促进聚氨酯分散粘合剂中异氰酸酯化学反应

    公开(公告)号：US20150183193A1

    公开(公告)日：2015-07-02

    申请号：US14423871

    申请日：2013-08-28

    Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

    Inventor： Xuming Chen ,  Robert L. McGee ,  David E. Vietti ,  Kevin Miyake ,  Larry F. Brinkman

    IPC: B32B27/08 ,  B32B27/40 ,  B32B27/32

    CPC classification number: B32B27/08 ,  B32B15/08 ,  B32B15/085 ,  B32B15/09 ,  B32B15/20 ,  B32B27/10 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/40 ,  B32B2255/06 ,  B32B2255/26 ,  B32B2439/70 ,  B32B2439/80 ,  B32B2553/00 ,  Y10T428/31587

    Abstract: In the construction of a multilayer film in which an ethylene-based polymer layer is joined to one another layer by a polyurethane (PU) adhesive, the rate of cure and the degree of cure of the PU adhesive are accelerated by incorporating into the ethylene-based polymer layer a functional compound with active hydrogens, e.g., a polyol, and/or a cure catalyst, e.g., an amine, zinc or tin-based compound. The catalyst and reactive functionality may be present on the same molecule (e.g. alkoxylated amine or zinc ricinoleate). The catalyst and isocyanate reactive compound will migrate into the PU adhesive over time and accelerate the rate and promote the degree of PU adhesive cure, and the functional compound will promote the migration of the cure catalyst into the PU adhesive. In turn, this accelerated cure inhibits the migration of residual, monomeric amines from the PU adhesive into and through the ethylene-based polymer.

    Abstract translation: 在通过聚氨酯（PU）粘合剂将乙烯类聚合物层与另一层接合的多层膜的构造中，PU粘合剂的固化速度和固化程度通过加入到乙烯 - 基于聚合物层的是具有活性氢的官能化合物，例如多元醇和/或固化催化剂，例如胺，锌或锡基化合物。 催化剂和反应性官能团可以存在于相同的分子上（例如烷氧基化胺或蓖麻醇酸锌）。 催化剂和异氰酸酯反应性化合物随时间迁移到PU粘合剂中，加速速率并促进PU粘合剂固化程度，功能化合物将促进固化催化剂迁移到PU粘合剂中。 反过来，这种加速的固化抑制残留的单体胺从PU粘合剂迁移到乙烯基聚合物中并通过乙烯基聚合物。

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