Abstract:
Provided are an acrylate derivative useful as a raw material of a polymer compound for resist compositions capable of giving resist patterns which are excellent in lithographic performance and have a good shape, an intermediate thereof (alcohol derivative) and production processes for them. To be specific, it is an acrylate derivative represented by a formula shown below: (wherein R1 represents a hydrogen atom, methyl or trifluoromethyl; R2, R3, R5, R7, R8, R9 and R10 each represent independently a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms or an alkoxy group having 1 to 6 carbon atoms; R4 and R6 each represent independently a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms or an alkoxy group having 1 to 6 carbon atoms, or both of R4 and R6 are combined to represent an alkylene group having 1 to 3 carbon atoms, —O— or —S—; and R11 represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or a cyclic hydrocarbon group having 3 to 10 carbon atoms).
Abstract translation:提供可用作抗蚀剂组合物的聚合物化合物的原料的丙烯酸酯衍生物,其能够提供平版印刷性能优异且形状良好的抗蚀剂图案,其中间体(醇衍生物)及其制备方法。 具体来说,它是由下式表示的丙烯酸酯衍生物:其中R1表示氢原子,甲基或三氟甲基; R2,R3,R5,R7,R8,R9和R10各自独立地表示氢原子,烷基 具有1至6个碳原子的基团,具有3至6个碳原子的环烷基或具有1至6个碳原子的烷氧基; R 4和R 6各自独立地表示氢原子,具有1至6个碳原子的烷基,环烷基 具有3至6个碳原子的烷基或具有1至6个碳原子的烷氧基,或者R 4和R 6都被结合以表示具有1至3个碳原子的亚烷基,-O-或-S-; R 11表示 氢原子,碳原子数1〜6的烷基或碳原子数3〜10的环状烃基)。
Abstract:
An oxygen absorbing composition of the present invention comprises a compound with a molecular weight of less than 10000 and an oxygen absorption accelerator. The compound includes two or more ring structures that are of at least one type, each of which has an ether bond. The oxygen absorbing composition further may contain a gas barrier resin. A laminate of the present invention comprises a layer formed of an oxygen absorbing composition of the present invention.
Abstract:
A process for producing cyclopropanecarbonitrile involves reacting cyclopropanecarbaldoxime with acetic anhydride to obtain a mixture containing acetic acid and cyclopropanecarbonitrile. The acetic acid can be removed from the mixture through azeotropic distillation of acetic acid with a solvent that forms with acetic acid an azeotropic mixture having an azeotropic point lower than the boiling point of the cyclopropanecarbonitrile.
Abstract:
The present invention provides an oxygen-absorbing resin composition containing a thermoplastic resin (A) having carbon-carbon double bonds substantially only in the main chain and a transition metal salt (B), and the oxygen absorption amount of 1 mol of carbon-carbon double bond of the thermoplastic resin (A) being 1.6 mols or more.
Abstract:
A method of industrially advantageously producing a cyclopropane monoacetal derivative represented by the formula (III) conveniently and also in a fewer steps by reacting a halogenated unsaturated carbonyl compound represented by the formula (II) with an alcoholate. wherein each symbol is as defined in the specification.
Abstract:
An oxygen absorption resin composition is provided that comprises a thermoplastic resin (A) having carbon-carbon double bonds substantially in its main chain and a transition metal salt (B). If necessary, the composition further comprises a gas barrier resin (C), a compatibilizer (D) and the like. The composition has excellent oxygen absorption properties, and when the composition is employed, generation of odorous substances derived from the decomposition of resins as a result of oxygen absorption can be suppressed.
Abstract:
Provided are an acrylate derivative useful as a raw material of a polymer compound for resist compositions capable of giving resist patterns which are excellent in lithographic performance and have a good shape, an intermediate thereof (alcohol derivative) and production processes for them. To be specific, it is an acrylate derivative represented by a formula shown below: (wherein R1 represents a hydrogen atom, methyl or trifluoromethyl; R2, R3, R5, R7, R8, R9 and R10 each represent independently a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms or an alkoxy group having 1 to 6 carbon atoms; R4 and R6 each represent independently a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms or an alkoxy group having 1 to 6 carbon atoms, or both of R4 and R6 are combined to represent an alkylene group having 1 to 3 carbon atoms, —O— or —S—; and R11 represents a hydrogen atom, an alkyl group having 1 to 6 carbon atoms or a cyclic hydrocarbon group having 3 to 10 carbon atoms).
Abstract translation:提供可用作抗蚀剂组合物的聚合物化合物的原料的丙烯酸酯衍生物,其能够提供平版印刷性能优异且形状良好的抗蚀剂图案,其中间体(醇衍生物)及其制备方法。 具体来说,它是由下式表示的丙烯酸酯衍生物:其中R1表示氢原子,甲基或三氟甲基; R2,R3,R5,R7,R8,R9和R10各自独立地表示氢原子,烷基 具有1至6个碳原子的基团,具有3至6个碳原子的环烷基或具有1至6个碳原子的烷氧基; R 4和R 6各自独立地表示氢原子,具有1至6个碳原子的烷基,环烷基 具有3至6个碳原子的烷基或具有1至6个碳原子的烷氧基,或者R 4和R 6都被结合以表示具有1至3个碳原子的亚烷基,-O-或-S-; R 11表示 氢原子,碳原子数1〜6的烷基或碳原子数3〜10的环状烃基)。
Abstract:
In optical resolution of an optically inactive (.+-.)-cis-4-aminocyclopent-2-en-1-carboxylic acid derivative into its (+)-derivative and (-)-derivative, the (.+-.)-cis-4-aminocyclopent-2-en-l-carboxylic acid derivative is allowed to react with an optically active cis-2-(arylalkylamino)cyclohexanemethanol or optically active .alpha.-alkylbenzylamine serving as an optically resolving agent, to form diastereomer salts corresponding to the (+)-cis-4-aminocyclopent-2-en-1-carboxylic acid derivative and the (-)-cis-4-aminocyclopent-2-en-1-carboxylic acid derivative.
Abstract:
An oxygen absorption resin composition is provided that comprises a thermoplastic resin (A) having carbon-carbon double bonds substantially in its main chain and a transition metal salt (B). If necessary, the composition further comprises a gas barrier resin (C), a compatibilizer (D) and the like. The composition has excellent oxygen absorption properties, and when the composition is employed, generation of odorous substances derived from the decomposition of resins as a result of oxygen absorption can be suppressed.
Abstract:
The present invention provides an oxygen-absorbing resin composition containing a thermoplastic resin (A) having carbon-carbon double bonds substantially only in the main chain and a transition metal salt (B), and the oxygen absorption amount of 1 mol of carbon-carbon double bond of the thermoplastic resin (A) being 1.6 mols or more.